Structure and thermal reactivity of Zn(II) salts of isocinchomeronic acid (2,5-pyridinedicarboxylic acid)

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The synthesis, an improved refined crystal and molecular structure re-determination, and the thermal decomposition behavior of two Zn(II) derivatives of isocinchomeronic acid (2,5-pyridinedicarboxylic acid or H 22,5-pydc) are presented. [Zn(2,5-pydc)(H2O) 3Zn(2,5-pydc)(H2O)2]2 (1) crystallizes in th...

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Autor principal: Sileo, E.E
Otros Autores: Piro, Oscar Enrique, Rigotti, Graciela Ester, Blesa, M.A, De Araujo, A.S, Castellano, Eduardo Ernesto
Formato: Capítulo de libro
Lenguaje:Inglés
Publicado: Springer New York 2008
Acceso en línea:Registro en Scopus
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100 1 |a Sileo, E.E. 
245 1 0 |a Structure and thermal reactivity of Zn(II) salts of isocinchomeronic acid (2,5-pyridinedicarboxylic acid) 
260 |b Springer New York  |c 2008 
270 1 0 |m Sileo, E. E.; Departamento de Química Inorgánica, Analítica Y Química Física, Facultad de Ciencias Exactas Y Naturales, Pab. II, C1428EHA Buenos Aires, Argentina; email: sileo@qi.fcen.uba.ar 
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506 |2 openaire  |e Política editorial 
520 3 |a The synthesis, an improved refined crystal and molecular structure re-determination, and the thermal decomposition behavior of two Zn(II) derivatives of isocinchomeronic acid (2,5-pyridinedicarboxylic acid or H 22,5-pydc) are presented. [Zn(2,5-pydc)(H2O) 3Zn(2,5-pydc)(H2O)2]2 (1) crystallizes in the triclinic P-1 space group with a = 7.106(2), b = 11.450(2), c = 11.869(1) Å, α = 107.29(1), β = 104.08(1), γ = 90.32(2)°, and Z = 2. [Zn(2,5-pydc)(H2O)2] ·H2O (2) is orthorhombic (P21212 1 space group), with a = 7.342(1), b = 9.430(1), c = 13.834(2) Å, and Z = 4. The structures were refined to agreement R 1-factors of 0.0315 (1) and 0.0336 (2). Complex (1) is arranged as molecular Zn4(2,5-pydc)4(H2O)10 tetramers, the cages of which define channels that remain unblocked by anions. Compound (2) is polymeric with Zn(2,5-pydc)(H2O)2 and Zn(2,5-pydc)(H2O)3 units linked through bridging ligands. Both compounds were synthesized under mild conditions in aqueous media, without need to resort to hydrothermal media. Changing the pH from 4.51 to 5.75 suffices to direct the chemical processes toward the orthorhombic compound rather than to the triclinic one. © 2008 Springer Science+Business Media, LLC.  |l eng 
593 |a Departamento de Química Inorgánica, Analítica Y Química Física, Facultad de Ciencias Exactas Y Naturales, Pab. II, C1428EHA Buenos Aires, Argentina 
593 |a Departamento de Física, Facultad de Ciencias Exactas, Instituto IFLP (CONICET), C.C. 67, (1900), La Plata, Argentina 
593 |a Gerencia de Química, Comisión Nacional de Energía Atómica, CONICET, Av. Gral. Paz 1499, San Martín 1650, Argentina 
593 |a Instituto de Física de São Carlos, Universidade de São Paulo, C.P. 369, Sao Carlos, SP 13560, Brazil 
690 1 0 |a 2,5-PYRIDINEDICARBOXYLATE 
690 1 0 |a ISOCINCHOMERONATE 
690 1 0 |a STRUCTURE 
690 1 0 |a THERMAL PROPERTIES 
690 1 0 |a ZINC 
700 1 |a Piro, Oscar Enrique 
700 1 |a Rigotti, Graciela Ester 
700 1 |a Blesa, M.A. 
700 1 |a De Araujo, A.S. 
700 1 |a Castellano, Eduardo Ernesto 
773 0 |d Springer New York, 2008  |g v. 19  |h pp. 651-657  |k n. 4  |p Struct Chem  |x 10400400  |t Structural Chemistry 
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856 4 0 |u https://doi.org/10.1007/s11224-008-9341-8  |y DOI 
856 4 0 |u https://hdl.handle.net/20.500.12110/paper_10400400_v19_n4_p651_Sileo  |y Handle 
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