Viscosity of concentrated sucrose and trehalose aqueous solutions including the supercooled regime

The viscosity of aqueous solutions of sucrose and trehalose is analyzed over a wide range of concentrations and temperatures covering the normal liquid and supercooled liquid regions, close to the glass transition temperature. These sugar solutions are fragile systems whose viscosity exhibits temper...

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Autor principal: Longinotti, M.P
Otros Autores: Corti, H.R
Formato: Capítulo de libro
Lenguaje:Inglés
Publicado: 2008
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100 1 |a Longinotti, M.P. 
245 1 0 |a Viscosity of concentrated sucrose and trehalose aqueous solutions including the supercooled regime 
260 |c 2008 
270 1 0 |m Corti, H. R.; Departamento de Física de la Materia Condensada, Comisión Nacional de Energía Atómica, Av. General Paz 1499 (1650), San Martín, Buenos Aires, Argentina; email: hrcorti@cnea.gov.ar 
506 |2 openaire  |e Política editorial 
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520 3 |a The viscosity of aqueous solutions of sucrose and trehalose is analyzed over a wide range of concentrations and temperatures covering the normal liquid and supercooled liquid regions, close to the glass transition temperature. These sugar solutions are fragile systems whose viscosity exhibits temperature dependence with a large departure from Arrhenius behavior. A description of the temperature and concentration dependences of the solution viscosity is given in terms of a scaled Arrhenius representation, which adopts the reduced temperature Tg T as the state variable. A comparison with results obtained from other theoretical or semiempirical equations is also presented. © 2008 American Institute of Physics.  |l eng 
593 |a Unidad de Actividad Química, Comisión Nacional de Energía Atómica, Av. General Paz 1499 (1650), San Martín, Buenos Aires, Argentina 
593 |a Departamento de Física de la Materia Condensada, Comisión Nacional de Energía Atómica, Av. General Paz 1499 (1650), San Martín, Buenos Aires, Argentina 
593 |a Instituto de Química Física de Los Materiales, Medio Ambiente y Energía, Facultad de Ciencias Exactas y Naturales, Universidad de Buenos Aires, Pabellón II, Ciudad Universitaria (1428), Buenos Aires, Argentina 
690 1 0 |a AQUEOUS SOLUTIONS 
690 1 0 |a FRAGILITY 
690 1 0 |a SUCROSE 
690 1 0 |a SUPERCOOLED 
690 1 0 |a TREHALOSE 
690 1 0 |a VISCOSITY 
700 1 |a Corti, H.R. 
773 0 |d 2008  |g v. 37  |h pp. 1503-1515  |k n. 3  |p J. Phys. Chem. Ref. Data  |x 00472689  |t Journal of Physical and Chemical Reference Data 
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856 4 0 |u https://doi.org/10.1063/1.2932114  |y DOI 
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