Reaction pathways of 2,2,2-trifluoroethylamine and n-butylamine with [Ru(bpy)2(NO)Cl]2+

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The reaction of [Ru(bpy)2(NO)Cl]2+ with 2,2,2-trifluoroethylamine produced [Ru(bpy)2(NO)Cl]+ by electron transfer and a number of organic compounds formed via nucleophilic substitution of the intermediate 2,2,2-trifluoroethyldiazonium ion (free or coordinated). Density functional theory computed res...

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Detalles Bibliográficos
Autor principal: Di Salvo, F.
Otros Autores: Crespo, A., Estrin, D.A, Doctorovich, F.
Formato: Capítulo de libro
Lenguaje:Inglés
Publicado: 2002
Acceso en línea:Registro en Scopus
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Biblioteca Central Dr. Luis F. Leloir (FCEN) de Universidad de Buenos Aires
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100 1 |a Di Salvo, F. 
245 1 0 |a Reaction pathways of 2,2,2-trifluoroethylamine and n-butylamine with [Ru(bpy)2(NO)Cl]2+ 
260 |c 2002 
506 |2 openaire  |e Política editorial 
504 |a Doctorovich, F., Escola, N., Trápani, C., Estrin, D.A., Turjanski, A.G., González Lebrero, M.C., (2000) Organometallics, 19, p. 3810 
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504 |a The 13C NMR signal corresponding to the CF3 unit was not observed due to the C-F splitting 
520 3 |a The reaction of [Ru(bpy)2(NO)Cl]2+ with 2,2,2-trifluoroethylamine produced [Ru(bpy)2(NO)Cl]+ by electron transfer and a number of organic compounds formed via nucleophilic substitution of the intermediate 2,2,2-trifluoroethyldiazonium ion (free or coordinated). Density functional theory computed results suggest that stabilization of the trifluoroethyldiazonium ion by complexation is much larger than the one corresponding to the butyl ion, in agreement with the fact that no rearrangement products derived from CF3CH2+ were observed. © 2002 Elsevier Science Ltd. All rights reserved.  |l eng 
536 |a Detalles de la financiación: Universidad de Buenos Aires, TX-042 
536 |a Detalles de la financiación: Agencia Nacional de Promoción Científica y Tecnológica, 06-00000-01704 
536 |a Detalles de la financiación: This work was supported by University of Buenos Aires (project TX-042), VW Stiftung and ANPCYT (project # 06-00000-01704). We thank the Cambridge Crystallographic Data Center for having provided us the Cambridge Structural Database Version 5.18. F. D. and D. A. E. are members of the scientific staff of CONICET. F. D. S. and A. C. are UBA fellows. 
593 |a Departamento de Quı́mica Inorgánica, Analı́tica y Quı́mica Fı́sica/INQUIMAE, Facultad de Ciencias Exactas y Naturales, Universidad de Buenos Aires, CEHA Buenos Aires, Ciudad Universitaria, Pabellón II, piso 3 (1428), Argentina 
690 1 0 |a 2,2,2-TRIFLUOROETHYLAMINE 
690 1 0 |a COMPLEX 
690 1 0 |a DENSITY FUNCTIONAL THEORY 
690 1 0 |a ELECTRON TRANSFER 
690 1 0 |a N-BUTYLAMINE 
690 1 0 |a NITROSYL 
690 1 0 |a RUTHENIUM 
690 1 0 |a 2,2,2 TRIFLUOROETHYLAMINE 
690 1 0 |a BUTYLAMINE 
690 1 0 |a ETHYLAMINE 
690 1 0 |a RUTHENIUM COMPLEX 
690 1 0 |a UNCLASSIFIED DRUG 
690 1 0 |a ARTICLE 
690 1 0 |a CALCULATION 
690 1 0 |a CHEMICAL REACTION 
690 1 0 |a COMPLEX FORMATION 
690 1 0 |a ELECTRON TRANSPORT 
690 1 0 |a MOLECULAR STABILITY 
690 1 0 |a PRIORITY JOURNAL 
690 1 0 |a REACTION ANALYSIS 
690 1 0 |a SOLVATION 
690 1 0 |a THEORY 
700 1 |a Crespo, A. 
700 1 |a Estrin, D.A. 
700 1 |a Doctorovich, F. 
773 0 |d 2002  |g v. 58  |h pp. 4237-4244  |k n. 21  |p Tetrahedron  |x 00404020  |w (AR-BaUEN)CENRE-45  |t Tetrahedron 
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