Enzyme-catalyzed preparation of novel fatty acid derivatives of pyridoxine with surfactant activity
A series of novel fatty acid derivatives of pyridoxine, one of the three members of the vitamin B6 group, has been prepared. These products were obtained using an enzymatic approach. Several lipases catalyzed esterification and transesterification reactions of pyridoxine with carboxylic acid or alky...
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| Formato: | Capítulo de libro |
| Lenguaje: | Inglés |
| Publicado: |
2002
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| Acceso en línea: | Registro en Scopus DOI Handle Registro en la Biblioteca Digital |
| Aporte de: | Registro referencial: Solicitar el recurso aquí |
| LEADER | 06492caa a22010337a 4500 | ||
|---|---|---|---|
| 001 | PAPER-5334 | ||
| 003 | AR-BaUEN | ||
| 005 | 20230518203458.0 | ||
| 008 | 190411s2002 xx ||||fo|||| 00| 0 eng|d | ||
| 024 | 7 | |2 scopus |a 2-s2.0-0036097353 | |
| 040 | |a Scopus |b spa |c AR-BaUEN |d AR-BaUEN | ||
| 030 | |a BOBOE | ||
| 100 | 1 | |a Baldessari, A. | |
| 245 | 1 | 0 | |a Enzyme-catalyzed preparation of novel fatty acid derivatives of pyridoxine with surfactant activity |
| 260 | |c 2002 | ||
| 270 | 1 | 0 | |m Baldessari, A.; Departamento de Quimica Organica, Fac. de Ciencias Exactas y Naturales, Universidad de Buenos Aires, 1428 Buenos Aires, Argentina; email: alib@qo.fcen.uba.ar |
| 506 | |2 openaire |e Política editorial | ||
| 504 | |a Angerer, P., Von Schacky, C., ω-3 Polyunsaturated fatty acids and the cardiovascular system (2000) Curr. Opin. Lipidol., 11, pp. 57-63 | ||
| 504 | |a Baldessari, A., Mangone, C.P., (2000) Patent Pending, INPI, AR 00 01 04147 | ||
| 504 | |a Baldessari, A., Mangone, C.P., Gros, E.G., Lipase-catalyzed acylation and deacylation reactions of pyridoxine, member of vitamin B6 group (1998) Helv. Chim. Acta, 81, pp. 2407-2413 | ||
| 504 | |a Becher, P., (1966) Emulsions: Theory and Practice, , (Marcel Dekker, New York) | ||
| 504 | |a Bowen, W.H., Food components and caries (1994) Adv. Dent. Res., 8, pp. 215-220 | ||
| 504 | |a Brown, L., Johnston, A., Sukling, C.J., Halling, P.J., Valivety, R.H., Pyridoxal derivatives as probes for water concentration in non-aqueous solvents (1993) J. Chem. Soc. Perkin Trans., 1, pp. 2777-2780 | ||
| 504 | |a (1997) Physical Properties! Pro™, Computational Chemistry Program, , revision (1997) (Fairfield, California) | ||
| 504 | |a Driskell, J.A., Vitamin B6 requirements of humans (1994) Nutr. Res., 14, pp. 293-324 | ||
| 504 | |a Faber, K., (2000) Biotransformations in Organic Chemistry, A Textbook, 4th Ed, , (Springer, Berlin) | ||
| 504 | |a Griffin, W.C., Classification of surface-active agents by HLB (1949) J. Soc. Cosmet. Chem., 1, pp. 311-316 | ||
| 504 | |a Korytnyk, W., Paul, B., Acyl migration and selective esterification in pyridoxol (1967) J. Org. Chem., 32, pp. 3791-3796 | ||
| 504 | |a Simopoulos, A.P., New products from the agri-food industry: The return of ω-3 fatty acids into the food supply (1999) Lipids, 34 (SUPPL.), pp. S297-S301 | ||
| 504 | |a Snider, B., Dietman, D.F., Pyridoxine therapy for acne flare (1974) Arch. Dermatol., 110, pp. 130-131 | ||
| 504 | |a Wong, C.H., Whitesides, G.M., Enzymes in synthetic organic chemistry (1994) Tetrahedron Organic Chemistry Series, 12. , In: Baldwin, J.E. and Magnus, P.D., eds; (Elsevier Science, Oxford) | ||
| 504 | |a Wyatt, K.M., Efficacy of vitamin B6 in the treatment of premenstrual syndrome: Systematic review (1999) Br. Med. J., 318, pp. 1375-1381 | ||
| 520 | 3 | |a A series of novel fatty acid derivatives of pyridoxine, one of the three members of the vitamin B6 group, has been prepared. These products were obtained using an enzymatic approach. Several lipases catalyzed esterification and transesterification reactions of pyridoxine with carboxylic acid or alkyl carboxylates showed a remarkable regioselective behavior; only monoacyl derivatives were obtained. The surfactant activity, composition and clean enzymatic methodology applied in the preparation of these products make them useful as ingredients in cosmetic and pharmaceutical formulations or food additives. |l eng | |
| 536 | |a Detalles de la financiación: Consejo Nacional de Investigaciones Científicas y Técnicas | ||
| 536 | |a Detalles de la financiación: Our thanks to UMYMFOR and LANAIS-EMAR for the CG analysis and spectra. We are indebted to CONICET for partial financial support. | ||
| 593 | |a Departamento de Quimica Organica, Fac. de Ciencias Exactas y Naturales, Universidad de Buenos Aires, 1428 Buenos Aires, Argentina | ||
| 690 | 1 | 0 | |a ENZYME-CATALYZED |
| 690 | 1 | 0 | |a FATTY ACIDS |
| 690 | 1 | 0 | |a PYRIDOXINE |
| 690 | 1 | 0 | |a SURFACTANTS |
| 690 | 1 | 0 | |a BIOSYNTHESIS |
| 690 | 1 | 0 | |a CARBOXYLIC ACIDS |
| 690 | 1 | 0 | |a DERIVATIVES |
| 690 | 1 | 0 | |a DRUG PRODUCTS |
| 690 | 1 | 0 | |a ENZYMES |
| 690 | 1 | 0 | |a ESTERIFICATION |
| 690 | 1 | 0 | |a FATTY ACIDS |
| 690 | 1 | 0 | |a FOOD ADDITIVES |
| 690 | 1 | 0 | |a SURFACE ACTIVE AGENTS |
| 690 | 1 | 0 | |a VITAMINS |
| 690 | 1 | 0 | |a REGIOSELECTIVE |
| 690 | 1 | 0 | |a NITROGEN COMPOUNDS |
| 690 | 1 | 0 | |a (5 HYDROXY 4 HYDROXYMETHYL 6 METHYLPYRIDIN 3 YL)METHYL 13 DOCOSENOIC ACID |
| 690 | 1 | 0 | |a (5 HYDROXY 4 HYDROXYMETHYL 6 METHYLPYRIDIN 3 YL)METHYL 5,8,11,14 EICOSATETRAENOIC ACID |
| 690 | 1 | 0 | |a (5 HYDROXY 4 HYDROXYMETHYL 6 METHYLPYRIDIN 3 YL)METHYL 9 OCTADECANOIC ACID |
| 690 | 1 | 0 | |a (5 HYDROXY 4 HYDROXYMETHYL 6 METHYLPYRIDIN 3 YL)METHYL 9,12 OCTADECANOIC ACID |
| 690 | 1 | 0 | |a (5 HYDROXY 4 HYDROXYMETHYL 6 METHYLPYRIDIN 3 YL)METHYL 9,12,15 OCTADECATRIENOIC ACID |
| 690 | 1 | 0 | |a (5 HYDROXY 4 HYDROXYMETHYL 6 METHYLPYRIDIN 3 YL)METHYLEICOSANOIC ACID |
| 690 | 1 | 0 | |a (5 HYDROXY 4 HYDROXYMETHYL 6 METHYLPYRIDIN 3 YL)METHYLOCTADECANOIC ACID |
| 690 | 1 | 0 | |a CARBOXYLIC ACID |
| 690 | 1 | 0 | |a FATTY ACID DERIVATIVE |
| 690 | 1 | 0 | |a FOOD ADDITIVE |
| 690 | 1 | 0 | |a PYRIDOXINE DERIVATIVE |
| 690 | 1 | 0 | |a SURFACTANT |
| 690 | 1 | 0 | |a TRIACYLGLYCEROL LIPASE |
| 690 | 1 | 0 | |a UNCLASSIFIED DRUG |
| 690 | 1 | 0 | |a ACYLATION |
| 690 | 1 | 0 | |a ARTICLE |
| 690 | 1 | 0 | |a CATALYSIS |
| 690 | 1 | 0 | |a COSMETIC INDUSTRY |
| 690 | 1 | 0 | |a DRUG ACTIVITY |
| 690 | 1 | 0 | |a DRUG FORMULATION |
| 690 | 1 | 0 | |a DRUG SYNTHESIS |
| 690 | 1 | 0 | |a ENZYMATIC ASSAY |
| 690 | 1 | 0 | |a ENZYME SUBSTRATE |
| 690 | 1 | 0 | |a NONHUMAN |
| 690 | 1 | 0 | |a PHARMACEUTICAL ENGINEERING |
| 690 | 1 | 0 | |a SWINE |
| 690 | 1 | 0 | |a SUS SCROFA |
| 650 | 1 | 7 | |2 spines |a PANCREAS |
| 700 | 1 | |a Mangone, C.P. | |
| 773 | 0 | |d 2002 |g v. 20 |h pp. 275-279 |k n. 4 |p Biocatal. Biotransform. |x 10242422 |w (AR-BaUEN)CENRE-3908 |t Biocatalysis and Biotransformation | |
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| 856 | 4 | 0 | |u https://doi.org/10.1080/10242420290004910 |y DOI |
| 856 | 4 | 0 | |u https://hdl.handle.net/20.500.12110/paper_10242422_v20_n4_p275_Baldessari |y Handle |
| 856 | 4 | 0 | |u https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_10242422_v20_n4_p275_Baldessari |y Registro en la Biblioteca Digital |
| 961 | |a paper_10242422_v20_n4_p275_Baldessari |b paper |c PE | ||
| 962 | |a info:eu-repo/semantics/article |a info:ar-repo/semantics/artículo |b info:eu-repo/semantics/publishedVersion | ||
| 999 | |c 66287 | ||