Donnan permselectivity in layer-by-layer self-assembled redox polyelectrolye thin films

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Redox polyelectrolyte multilayers have been assembled with use of the layer-by-layer (LBL) deposition technique with cationic poly(allylamine) modified with Os(bpy)2ClPyCHO (PAH-Os) and anionic poly(styrene)sulfonate (PSS) or poly(vinyl)sulfonate (PVS). Different behavior has been observed in the fo...

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Autor principal: Calvo, E.J
Otros Autores: Wolosiuk, A.
Formato: Capítulo de libro
Lenguaje:Inglés
Publicado: 2002
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024 7 |2 cas  |a osmium, 7440-04-2; polystyrenesulfonic acid, 50851-57-5; vinyl derivative, 2669-89-8; water, 7732-18-5; Electrolytes; Polymers 
040 |a Scopus  |b spa  |c AR-BaUEN  |d AR-BaUEN 
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100 1 |a Calvo, E.J. 
245 1 0 |a Donnan permselectivity in layer-by-layer self-assembled redox polyelectrolye thin films 
260 |c 2002 
270 1 0 |m Calvo, E.J.; INQUIMAE, Depto. Quim. Inorg. Anal. y Fisica, Fac. de Ciencias Exact. y Naturales, Pabellon 2 Ciudad Universitaria, AR-1428 Buenos Aires, Argentina; email: calvo@ql.fcen.uba.ar 
506 |2 openaire  |e Política editorial 
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520 3 |a Redox polyelectrolyte multilayers have been assembled with use of the layer-by-layer (LBL) deposition technique with cationic poly(allylamine) modified with Os(bpy)2ClPyCHO (PAH-Os) and anionic poly(styrene)sulfonate (PSS) or poly(vinyl)sulfonate (PVS). Different behavior has been observed in the formal redox potential of the Os(II)/Os(III) couple in the polymer film with cyclic voltammetry depending on the charge of the outermost layer and the electrolyte concentration and pH. The electrochemical quartz crystal microbalance (EQCM) has been used to monitor the exchange of ions and solvent with the external electrolyte during redox switching. At low ionic strength Donnan permselectivity of anions or cations is apparent and the nature of the ion exclusion from the film is determined by the charge of the topmost layer and solution pH. At high electrolyte concentration Donnan breakdown is observed and the osmium redox potential approaches the value for the redox couple in solution. Exchange of anions and water with the external electrolyte under permselective conditions and salt and water under Donnan breakdown have been observed upon oxidation of the film at low pH for the PAH-Os terminating layer. Moreover, at high pH values and with PVS as the terminating layer EQCM mass measurements have shown that cation release was masked by water exchange.  |l eng 
593 |a INQUIMAE, Departamento de Química Inorgánica, Analítica y Química Física, Facultad de Ciencias Exactas y Naturales, Pabellón 2 Ciudad Universitaria, AR-1428 Buenos Aires, Argentina 
690 1 0 |a PERMSELECTIVITY 
690 1 0 |a CRYSTALS 
690 1 0 |a ELECTROLYTES 
690 1 0 |a IONIC STRENGTH 
690 1 0 |a PH EFFECTS 
690 1 0 |a POLYSTYRENES 
690 1 0 |a POSITIVE IONS 
690 1 0 |a QUARTZ 
690 1 0 |a THIN FILMS 
690 1 0 |a ANION 
690 1 0 |a CATION 
690 1 0 |a OSMIUM 
690 1 0 |a POLYELECTROLYTE 
690 1 0 |a POLYSTYRENESULFONIC ACID 
690 1 0 |a POLYVINYL SULFONATE 
690 1 0 |a UNCLASSIFIED DRUG 
690 1 0 |a VINYL DERIVATIVE 
690 1 0 |a WATER 
690 1 0 |a ACIDITY 
690 1 0 |a ALKALINITY 
690 1 0 |a ARTICLE 
690 1 0 |a CHEMICAL STRUCTURE 
690 1 0 |a CONCENTRATION RESPONSE 
690 1 0 |a CRYSTAL 
690 1 0 |a CYCLIC POTENTIOMETRY 
690 1 0 |a ELECTROCHEMISTRY 
690 1 0 |a FILM 
690 1 0 |a MASS 
690 1 0 |a OXIDATION REDUCTION POTENTIAL 
690 1 0 |a OXIDATION REDUCTION REACTION 
690 1 0 |a POLYMERIZATION 
690 1 0 |a REACTION ANALYSIS 
690 1 0 |a STRUCTURE ANALYSIS 
690 1 0 |a ELECTROCHEMISTRY 
690 1 0 |a ELECTROLYTES 
690 1 0 |a HYDROGEN-ION CONCENTRATION 
690 1 0 |a KINETICS 
690 1 0 |a OXIDATION-REDUCTION 
690 1 0 |a PERMEABILITY 
690 1 0 |a POLYMERS 
650 1 7 |2 spines  |a PH 
700 1 |a Wolosiuk, A. 
773 0 |d 2002  |g v. 124  |h pp. 8490-8497  |k n. 28  |p J. Am. Chem. Soc.  |x 00027863  |w (AR-BaUEN)CENRE-19  |t Journal of the American Chemical Society 
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856 4 0 |u https://doi.org/10.1021/ja020107h  |y DOI 
856 4 0 |u https://hdl.handle.net/20.500.12110/paper_00027863_v124_n28_p8490_Calvo  |y Handle 
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