Crystal structures and luminescent properties of terbium(III) carboxylates
Single crystals of three terbium(III) carboxylates of formulae [Tb2(CH3COO)6(H2O)4] ·4H2O (1), [Tb2(CF3COO)6(H2O)6] (2) and [Tb(Hoda)3]·H2oda·H2O (3) (H2oda=2,2′-oxydiacetic acid) were obtained and their structures determined by X-ray crystallography. Compounds 1 and 2 are dimeric, in the former the...
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2003
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| LEADER | 08726caa a22011057a 4500 | ||
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| 001 | PAPER-5020 | ||
| 003 | AR-BaUEN | ||
| 005 | 20230518203438.0 | ||
| 008 | 190411s2003 xx ||||fo|||| 00| 0 eng|d | ||
| 024 | 7 | |2 scopus |a 2-s2.0-0037465623 | |
| 024 | 7 | |2 cas |a terbium, 7440-27-9; water, 7732-18-5 | |
| 040 | |a Scopus |b spa |c AR-BaUEN |d AR-BaUEN | ||
| 030 | |a ICHAA | ||
| 100 | 1 | |a Barja, B. | |
| 245 | 1 | 0 | |a Crystal structures and luminescent properties of terbium(III) carboxylates |
| 260 | |c 2003 | ||
| 270 | 1 | 0 | |m Perec, M.; Depto. Quim. Inorg., Analitica Q., Fac. de Ciencias Exactas y Naturales, Universidad de Buenos Aires, 1428 Buenos Aires, Argentina; email: perec@g1.fcen.uba.ar |
| 506 | |2 openaire |e Política editorial | ||
| 504 | |a Mehrotra, C., Bohra, R., (1983) Metal Carboxylates, , Academic Press: New York | ||
| 504 | |a Ouchi, A., Suzuki, Y., Ohki, Y., Koizumi, Y., (1988) Coord. Chem. Rev., 92, p. 29 | ||
| 504 | |a (1984) Gmelin Handbook of Inorganic Chemistry, , Sc, Y, La-Lu Carboxylates, D5, Springer, New York | ||
| 504 | |a Hart, F.A., (1987) Comprehensive Coordination Chemistry, 3. , G. Wilkinson, R.D. Gillard, McCleverty J.A. Oxford: Pergamon. Chapter 38 | ||
| 504 | |a Reineke, T.M., Eddaoudi, M., Fehr, M., Kelly, D., Yaghi, O.M., (1999) J. Am. Chem. Soc., 121, p. 1651 | ||
| 504 | |a Ma, L., Evans, O.R., Foxman, B.M., Lin, W., (1999) Inorg. Chem., 38, p. 5837 | ||
| 504 | |a Seo, J.S., Whang, D., Lee, H., Jun, S.I., Oh, J., Jeon, Y.J., Kim, K., (2000) Nature, 404, p. 982 | ||
| 504 | |a Ballato, J., Lewis J.S. III, Holloway, P., (1999) Mater. Res. Soc. Bull., 24, p. 51 | ||
| 504 | |a Bünzli, J.-C.G., (1989) Lanthanide Probes in life, Chemical and Earth Sciences, , G.R. Chopin, & J.-C.G. Bünzli. Amsterdam: Elsevier Science. Chapter 7 | ||
| 504 | |a Wang, S., Pang, Z., Smith, K.D.L., Wagner, M.J., (1994) J. Chem. Soc., Dalton Trans., p. 955 | ||
| 504 | |a Yansheng, Y., Lubin, L., Mak, T.C.W., (1988) Chin. J. Struct. Chem. (Jiegou Huaxue), 7, p. 1 | ||
| 504 | |a Ganapathy, S., Chacko, V.P., Bryant, R.G., Etter, M.C., (1986) J. Am. Chem. Soc., 108, p. 3159 | ||
| 504 | |a Panin, E.S., Kavun, V.Ya., Sergienko, V.I., Butvetskii, B.V., (1985) Koord. Him., 11, p. 1539 | ||
| 504 | |a Aramendia, P.F., Baggio, R., Garland, M.T., Perec, M., (2000) Inorg. Chim. Acta, 303, p. 306 | ||
| 504 | |a Pascal, P., (1910) Ann. Chim. Phys., 19, p. 5 | ||
| 504 | |a (1992) Powder Diffraction File 13-387, JCPDS, , International Center for Diffraction Data, Newtown Square, PA | ||
| 504 | |a Baggio, R., Garland, M.T., Moreno, Y., Peña, O., Perec, M., Spodine, E., (2000) J. Chem. Soc., Dalton Trans., p. 2061 | ||
| 504 | |a Baggio, R., Garland, M.T., Perec, M., (1997) Inorg. Chem., 36, p. 950 | ||
| 504 | |a Sheldrick, G.M., (1997) SHELXL-97: Program for Crystal Structure Refinement, , University of Göttingen, Göttingen, Germany | ||
| 504 | |a Sheldrick, G.M., (1991) XP in SHELXL-PC, Version 4.2, , Siemens Analytical X-ray Instruments Inc., Madison, WI | ||
| 504 | |a Yansheng, Y., Lubin, L., Mak, T.C.W., (1988) Chin. J. Struct. Chem., 7, p. 1 | ||
| 504 | |a Favas, M.C., Kepert, D.L., Skelton, B.W., White, A.H., (1980) J. Chem. Soc., Dalton Trans., p. 454 | ||
| 504 | |a Bats, J.W., Kalus, R., Fuess, H., (1979) Acta Crystallogr., B, 35, p. 1225 | ||
| 504 | |a Sawase, H., Koizumi, Y., Suzuki, Y., Shimoi, M., Ouchi, A., (1984) Bull. Chem. Soc. Jpn., 57, p. 2730 | ||
| 504 | |a Bone, S.P., Sowerby, D.B., Verma, R.D., (1978) J. Chem. Soc., Dalton Trans., p. 1544 | ||
| 504 | |a Kavun, V.Ya., Kaidalova, T.A., Kostin, V.I., Panin, E.S., Chemyshov, B.N., (1984) Koord. Him., 10, p. 1502 | ||
| 504 | |a Zhang, J., Zhang, S., Xiuqin, M., Gecheng, W., Ninghai, H., Zhongsheng, J., (1988) Chin. J. Appl. Chem., 5, p. 30 | ||
| 504 | |a Romanenko, G.V., Sokolova, S.P., Lanionov, S.V., (1999) Zh. Struct. Him., 40, p. 387 | ||
| 504 | |a Baggio, R., Garland, M.T., Perec, M., (1997) Inorg. Chem., 30, p. 950 | ||
| 504 | |a Baggio, R., Garland, M.T., Perec, M., (1998) Inorg. Chim. Acta, 281, p. 18 | ||
| 504 | |a Kahn, O., (1993) Molecular Magnetism, , Weinheim: VCH | ||
| 504 | |a Parker, D., Williams, G., (1996) J. Chem. Soc., Dalton Trans., p. 3613 | ||
| 504 | |a Horrocks, W.D., Sudnick, D.R., (1979) J. Am. Chem. Soc., 101, p. 334 | ||
| 504 | |a Beeby, A., Clarkson, I.M., Dickins, R.S., Faulkner, S., Parker, D., Royle, L., De Sousa, A.S., Woods, M., (1999) J. Chem. Soc., Perkin Trans. 2, p. 493 | ||
| 504 | |a Kessler, M.A., (1998) Anal. Chim. Acta, 364, p. 125 | ||
| 504 | |a Berton, M., Mancin, F., Stocchero, G., Tecila, P., Tonellato, U., (2001) Langmuir, 17, p. 7521 | ||
| 504 | |a Legendziewicz, J., Borzechowska, M., (2000) J. Alloys Compd., 300-301, p. 353 | ||
| 520 | 3 | |a Single crystals of three terbium(III) carboxylates of formulae [Tb2(CH3COO)6(H2O)4] ·4H2O (1), [Tb2(CF3COO)6(H2O)6] (2) and [Tb(Hoda)3]·H2oda·H2O (3) (H2oda=2,2′-oxydiacetic acid) were obtained and their structures determined by X-ray crystallography. Compounds 1 and 2 are dimeric, in the former the terbium atoms are bound by two tridentate carboxylates in the μ2-bridging mode, whereas in the latter the bridging is fourfold with all carboxylates in the syn-syn coordination mode. Compound 3 is mononuclear containing three tridentate Hoda anions, and consecutive units are linked by a network of H-bonds involving the interstitial molecules. The luminescence spectra of the carboxylates were analyzed in the solid state and in aqueous solution. Comparison of the emission lifetimes in H2O and D2O allowed the determination of the average value for q, the number of coordinated water molecules, being 9.2 for 1 and 2 and 3.6 for 3, respectively. The quenching effect of Cu(II) on the luminescence of the terbium(III) carboxylates was evaluated through the emission decay constants. From the addition of Cu(II) to an aqueous solution of 3, single crystals of polymeric [{Cu3Tb2(oda)6(H2O)6} ·12H2O]n (4) were isolated with completely quenched luminescence. Compound 4 exhibits an overall antiferromagnetic interaction. © 2002 Elsevier Science B.V. All rights reserved. |l eng | |
| 536 | |a Detalles de la financiación: Fondo Nacional de Desarrollo Científico, Tecnológico y de Innovación Tecnológica, CONICET-PIP0388, 1020802, ANPCyT-PICT4438 | ||
| 536 | |a Detalles de la financiación: C-13575 | ||
| 536 | |a Detalles de la financiación: Consejo Nacional de Innovación, Ciencia y Tecnología, FONDAP 11980002 | ||
| 536 | |a Detalles de la financiación: This work was supported by Fundacion Andes C-13575, CONICYT FONDAP 11980002, PICS 922, FONDECYT 1020802 (Chile) and ANPCyT-PICT4438 and CONICET-PIP0388 (Argentina). P.F.A. and M.P. are members of CONICET. | ||
| 593 | |a Depto. Quim. Inorg., Analitica Q., Fac. de Ciencias Exactas y Naturales, Universidad de Buenos Aires, 1428 Buenos Aires, Argentina | ||
| 593 | |a Departamento de Física, Comision Nac. de Ener. Atomica, Avda del Libertador 8250, 1429 Buenos Aires, Argentina | ||
| 593 | |a Departamento de Física, Fac. de Cie. Fis. y Matemat., Universidad de Chile, Avda. Blanco Encalada 2008, Santiago, Chile | ||
| 593 | |a U.M.R. 6511, CNRS, Université Rennes I, 35042 Rennes, France | ||
| 690 | 1 | 0 | |a CRYSTAL STRUCTURES |
| 690 | 1 | 0 | |a LUMINESCENCE |
| 690 | 1 | 0 | |a TERBIUM(III) CARBOXYLATES |
| 690 | 1 | 0 | |a ACETIC ACID DERIVATIVE |
| 690 | 1 | 0 | |a CARBOXYLIC ACID DERIVATIVE |
| 690 | 1 | 0 | |a COPPER COMPLEX |
| 690 | 1 | 0 | |a TERBIUM |
| 690 | 1 | 0 | |a WATER |
| 690 | 1 | 0 | |a AQUEOUS SOLUTION |
| 690 | 1 | 0 | |a ARTICLE |
| 690 | 1 | 0 | |a CHEMOLUMINESCENCE |
| 690 | 1 | 0 | |a CRYSTAL STRUCTURE |
| 690 | 1 | 0 | |a HYDROGEN BOND |
| 690 | 1 | 0 | |a INFRARED SPECTROSCOPY |
| 690 | 1 | 0 | |a MAGNETISM |
| 690 | 1 | 0 | |a SOLID STATE |
| 690 | 1 | 0 | |a X RAY CRYSTALLOGRAPHY |
| 700 | 1 | |a Baggio, R. | |
| 700 | 1 | |a Garland, M.T. | |
| 700 | 1 | |a Aramendia, P.F. | |
| 700 | 1 | |a Peña, O. | |
| 700 | 1 | |a Perec, M. | |
| 773 | 0 | |d 2003 |g v. 346 |h pp. 187-196 |p Inorg. Chim. Acta |x 00201693 |w (AR-BaUEN)CENRE-31 |t Inorganica Chimica Acta | |
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| 856 | 4 | 0 | |u https://doi.org/10.1016/S0020-1693(02)01429-9 |y DOI |
| 856 | 4 | 0 | |u https://hdl.handle.net/20.500.12110/paper_00201693_v346_n_p187_Barja |y Handle |
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| 963 | |a VARI | ||
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