Europium(III) and terbium(III) trans-2-butenoates: Syntheses, crystal structures, and properties
Homometallic europium(III) and terbium(III) trans-2-butenoate polymers, chemical formulas [{Eu3(MeCH=CHCO2)9(H 2O)4}·H2O·EtOH]n (1) and [{Tb(MeCH=CHCO2)3(H2O)}·MeCH= CHCO2H]n (2) and their dimeric 1,10-phenanthroline derivatives [Ln2(MeCH=CHCO2)6(phen) 2]·2H2O, with Ln=Eu (3) and Tb (4), were prepar...
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| Formato: | Capítulo de libro |
| Lenguaje: | Inglés |
| Publicado: |
Elsevier S.A.
2003
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| Acceso en línea: | Registro en Scopus DOI Handle Registro en la Biblioteca Digital |
| Aporte de: | Registro referencial: Solicitar el recurso aquí |
| LEADER | 06955caa a22009497a 4500 | ||
|---|---|---|---|
| 001 | PAPER-4782 | ||
| 003 | AR-BaUEN | ||
| 005 | 20230518203422.0 | ||
| 008 | 190411s2003 xx ||||fo|||| 00| 0 eng|d | ||
| 024 | 7 | |2 scopus |a 2-s2.0-1042299781 | |
| 024 | 7 | |2 cas |a europium, 7440-53-1; terbium, 7440-27-9 | |
| 040 | |a Scopus |b spa |c AR-BaUEN |d AR-BaUEN | ||
| 030 | |a ICHAA | ||
| 100 | 1 | |a Barja, B. | |
| 245 | 1 | 0 | |a Europium(III) and terbium(III) trans-2-butenoates: Syntheses, crystal structures, and properties |
| 260 | |b Elsevier S.A. |c 2003 | ||
| 270 | 1 | 0 | |m Perec, M.; Depto. Quim. Inorg., Analitica Q., Fac. de Ciencias Exactas y Naturales, C1428EHA, Buenos Aires, Argentina; email: perec@q1.fcen.uba.ar |
| 506 | |2 openaire |e Política editorial | ||
| 504 | |a Bünzli, J.-C.G., (1989) Lanthanide Probes in Life, Chemical and Earth Sciences, Theory and Practice, p. 219. , J.-C.G. Bünzli, & G.R. Choppin. Amsterdam: Elsevier | ||
| 504 | |a De Silva, A.P., Gunaratne, H.Q.N., Rice, T.E., (1996) Angew. Chem., Int. Ed. Engl., 35, p. 2116 | ||
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| 504 | |a Yansheng, Y., Lubin, L., Mak, T.C.W., (1988) Chin. J. Struct. Chem. (Jiegou Huaxue), 7, p. 1 | ||
| 504 | |a (1984) Gmelin Handbook of Inorganic Chemistry, Sc, Y, La-Lu, Carboxylates, D5 | ||
| 504 | |a Nabar, M.A., Barve, S.D., (1984) J. Appl. Crystallogr., 17, p. 39. , Chem. Abstr. 100, 59895g | ||
| 504 | |a The Diffraction Pattern Was Matched with That of Eu2O 3: The JCPDS International Center for Diffraction Data, , Swarthmore, PA, 1992, Powder Diffraction File No.340072 | ||
| 504 | |a Sheldrick, G.M., (1997) SHELXS-97 and SHELXL-97, Software for Crystal Structure Analysis, , Madison, WI: Siemens Analytical X-ray Instruments | ||
| 504 | |a Van Vleck, J.H., (1965) The Theory of Electric and Magnetic Susceptibilities, , London: Oxford University Press | ||
| 504 | |a Herpin, A., (1968) Theorie de Magnetisme, , Paris: Presses Universitaires de France | ||
| 504 | |a Murov, S.L., Carmichael, I., Hug, G., (1993) Handbook of Photochemistry, p. 37. , New York: Marcel Dekker | ||
| 504 | |a Parker, D., Gareth Williams, J.A., (1996) J. Chem. Soc., Dalton Trans., p. 3613 | ||
| 504 | |a Parker, D., Dickins, R.S., Puschmann, H., Crossland, C., Howard, J.A.K., (2002) Chem. Rev., 102, p. 1977 | ||
| 504 | |a Quici, S., Marzanni, G., Cavazzini, M., Anelli, P.L., Botta, M., Gianolio, E., Accorsi, G., Barigelletti, F., (2002) Inorg. Chem., 41, p. 2777 | ||
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| 520 | 3 | |a Homometallic europium(III) and terbium(III) trans-2-butenoate polymers, chemical formulas [{Eu3(MeCH=CHCO2)9(H 2O)4}·H2O·EtOH]n (1) and [{Tb(MeCH=CHCO2)3(H2O)}·MeCH= CHCO2H]n (2) and their dimeric 1,10-phenanthroline derivatives [Ln2(MeCH=CHCO2)6(phen) 2]·2H2O, with Ln=Eu (3) and Tb (4), were prepared and characterized by single-crystal X-ray diffraction. The coordination polymers 1 and 2 adopt different carboxylate-bridged infinite chain structures. While the europium compound 1 shows three independent europium centers linked to each other by three different types and number of carboxylate bridges, the terbium polymer 2 shows one independent metal center bridged by the same type of double carboxylates along the chains. Compounds 3 and 4 are isomorphous dinuclear structures with quadruply bridged carboxylate groups, two in the η1:η1:μ2 and two in the η 2:η1:μ2 modes. The magnetic and photophysical behaviors of the four compounds are reported in the solid state. © 2003 Elsevier B.V. All rights reserved. |l eng | |
| 536 | |a Detalles de la financiación: Fondo Nacional de Desarrollo Científico, Tecnológico y de Innovación Tecnológica, 1020802 | ||
| 536 | |a Detalles de la financiación: C-13575 | ||
| 536 | |a Detalles de la financiación: Consejo Nacional de Innovación, Ciencia y Tecnología, FONDAP 11980002 | ||
| 536 | |a Detalles de la financiación: Agencia Nacional de Promoción Científica y Tecnológica, CONICET-PIP 0388, PICT 4438 | ||
| 536 | |a Detalles de la financiación: This work was supported by Fundacion Andes C-13575, CONICYT FONDAP 11980002, PICS 922, FONDECYT 1020802 (Chile) and ANPCyT PICT 4438 and CONICET-PIP 0388 (Argentina). P.F.A. and M.P. are members of CONICET. | ||
| 593 | |a Depto. Quim. Inorg., Analitica Q., Fac. de Ciencias Exactas y Naturales, C1428EHA, Buenos Aires, Argentina | ||
| 593 | |a Departamento de Fisica, Comision Nacional de Energia Atomica, Avda del Libertador 8250, 1429 Buenos Aires, Argentina | ||
| 593 | |a Departamento de Fisica, Fac. de Cie. Fisicas y Matematicas, Universidad de Chile, Avda B. Encalada 2008, Casilla 487-3, Santiago, Chile | ||
| 593 | |a U.M.R. 6511, L.C.S.I.M. CNRS, Université Rennes I, 35042 Rennes, France | ||
| 690 | 1 | 0 | |a CRYSTAL STRUCTURES |
| 690 | 1 | 0 | |a EUROPIUM(III) COMPLEXES |
| 690 | 1 | 0 | |a LUMINESCENCE |
| 690 | 1 | 0 | |a TERBIUM(III) COMPLEXES |
| 690 | 1 | 0 | |a BRIDGED COMPOUND |
| 690 | 1 | 0 | |a CARBOXYLIC ACID DERIVATIVE |
| 690 | 1 | 0 | |a COORDINATION COMPOUND |
| 690 | 1 | 0 | |a EUROPIUM |
| 690 | 1 | 0 | |a EUROPIUM 2 BUTENOATE |
| 690 | 1 | 0 | |a METAL COMPLEX |
| 690 | 1 | 0 | |a TERBIUM |
| 690 | 1 | 0 | |a TERBIUM 2 BUTENOATE |
| 690 | 1 | 0 | |a UNCLASSIFIED DRUG |
| 690 | 1 | 0 | |a ARTICLE |
| 690 | 1 | 0 | |a CRYSTAL |
| 690 | 1 | 0 | |a CRYSTAL STRUCTURE |
| 690 | 1 | 0 | |a MAGNETISM |
| 690 | 1 | 0 | |a PHYSICAL CHEMISTRY |
| 690 | 1 | 0 | |a SOLID STATE |
| 690 | 1 | 0 | |a SYNTHESIS |
| 690 | 1 | 0 | |a X RAY DIFFRACTION |
| 700 | 1 | |a Aramendia, P. | |
| 700 | 1 | |a Baggio, R. | |
| 700 | 1 | |a Garland, M.T. | |
| 700 | 1 | |a Peña, O. | |
| 700 | 1 | |a Perec, M. | |
| 773 | 0 | |d Elsevier S.A., 2003 |g v. 355 |h pp. 183-190 |p Inorg. Chim. Acta |x 00201693 |w (AR-BaUEN)CENRE-31 |t Inorganica Chimica Acta | |
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