Analysis of the master curve for the viscoelastic behaviour of polymers

A detailed analysis of typical master curves reported in the literature for the dynamic modulus and compliance of unfilled polyuretane rubber and poly(n-octyl methacrylate), respectively, and for the transient modulus of styrene-butadiene rubber is performed. It is shown that the time-temperature su...

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Detalles Bibliográficos
Autor principal: Povolo, Francisco
Otros Autores: Hermida, E.B
Formato: Capítulo de libro
Lenguaje:Inglés
Publicado: 1991
Acceso en línea:Registro en Scopus
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100 1 |a Povolo, Francisco 
245 1 0 |a Analysis of the master curve for the viscoelastic behaviour of polymers 
260 |c 1991 
270 1 0 |m Povolo, F.; Comisión Nacional de Energia Atómica, Dto. Materiales, Au. Libertador 8250, 1429 Buenos Aires, Argentina 
504 |a Alfrey, Doty, (1945) J. Appl. Phys., 16, p. 700 
504 |a Berry, Fox, (1967) Adv. Polym. Sci., 5, p. 261 
504 |a BS 903 Part A 42 (1983); Bueche, (1956) J. Chem. Phys., 24, p. 148 
504 |a Bueche, Mobility of Molecules in Liquids near the Glass Temperature (1956) The Journal of Chemical Physics, 30, p. 748 
504 |a Bueche, (1962) J. Chem. Phys., 36, p. 2940 
504 |a Chung, Applicability of the free volume concept on relaxation phenomena in the glass transition range (1966) Rheologica Acta, 5, p. 262 
504 |a Cohen, Turnbull, (1959) J. Chem. Phys., 31, p. 1164 
504 |a Doolittle, (1951) J. Appl Phys., 22, p. 1471 
504 |a Doolittle, (1952) J. Appl Phys., 23, p. 236 
504 |a Ferry, (1950) J. Am. Chem. Soc., 72, p. 3746 
504 |a Ferry, (1980) Viscoelastic Properties of Polymers, , Wiley, New York 
504 |a Fillers, Tschoegl, (1977) Trans. Soc. Rheol., 21, p. 51 
504 |a Fulcher, (1925) J. Am. Chem. Soc., 8, p. 339 
504 |a Fulcher, (1925) J. Am. Chem. Soc., 8, p. 789 
504 |a Kovacs, (1966) Rheol. Acta, 5, p. 262 
504 |a Leaderman, (1943) Elastic and Creep Properties of Filamentous Materials and Other High Polymers, , The Textile Foundation, Washington 
504 |a Moonan, Tschoegl, (1983) Macromolecules, 16, p. 55 
504 |a Moonan, Tschoegl, (1985) J. Polym. Sci. Polym. Phys. Ed., 23, p. 623 
504 |a Müller, Zum plastisch-elastischen Verhalten der Materie III (1949) Kolloid-Zeitschrift, 114, p. 2 
504 |a Nowick, Berry, (1972) Inelastic Relaxation in Crystalline Solids, , Academic Press, New York 
504 |a Plazek, (1982) J. Polym Sci. Polym. Phys. Ed., 20, p. 729 
504 |a Plazek, Plazek, (1983) Macromolecules, 16, p. 1469 
504 |a Povolo, (1989) J. Mater. Sci., 24, p. 1513 
504 |a Povolo, F. and Fontelos, M. J. Mater. Sci., submitted; Povolo, Fontelos, (1987) J. Mater. Sci., 22, p. 1530 
504 |a Povolo, Hermida, (1988) J. Mater. Sci., 23, p. 1255 
504 |a Povolo, Rubiolo, (1983) J. Mater. Sci., 18, p. 821 
504 |a Schwarzl, van der Val, Bree, (1972) Chim. Ind., 54, p. 51 
504 |a Tager, (1978) Physical Chemistry of Polymers, p. 90. , MIR, Moscow 
504 |a Tamman, Hesse, Die Abh�ngigkeit der Viscosit�t von der Temperatur bie unterk�hlten Fl�ssigkeiten (1926) Zeitschrift f�r anorganische und allgemeine Chemie, 156, p. 245 
504 |a Tobolsky, Andrews, (1943) J. Chem. Phys., 11, p. 125 
504 |a Turnbull, Cohen, (1961) J. Chem. Phys., 34, p. 120 
504 |a Vogel, (1921) Phys. Z., 22, p. 645 
504 |a Wagner, (1915) Elektotech. Z., 36, p. 135 
504 |a Wagner, (1915) Elektotech. Z., 36, p. 163 
504 |a Williams, Landel, Ferry, (1955) J. Am. Chem. Soc., 77, p. 3701 
506 |2 openaire  |e Política editorial 
520 3 |a A detailed analysis of typical master curves reported in the literature for the dynamic modulus and compliance of unfilled polyuretane rubber and poly(n-octyl methacrylate), respectively, and for the transient modulus of styrene-butadiene rubber is performed. It is shown that the time-temperature superposition is not strictly obeyed, that is, the individual curves do not satisfy the scaling conditions with a translation path parallel to the horizontal axis. In fact, only a partial matching of the individual curves is obtained, on constructing the master curve, which can be described by a Maxwell. Finally, the meaning of the parameters obtained for the Maxwell element and for the constants of the Williams-Landel-Ferry equation is discussed. © 1991.  |l eng 
536 |a Detalles de la financiación: Consejo Nacional de Investigaciones Científicas y Técnicas 
536 |a Detalles de la financiación: This work was supportedin part by the Con-sejo Nacional de InvestigacioneCs ientificasy Tdcnicas( CONICET) and the "ProyectoM ultina-cional de Investigaci6ny Desarrolloe n Materi-ales" OAS-CNEA. 
593 |a Comisión Nacional de Energia Atómica, Dto. Materiales, Au. Libertador 8250, 1429 Buenos Aires, Argentina 
593 |a Universidad de Buenos Aires, Facultad de Ciencias Exactas y Naturales, Dto. de Fisica. Pabellón I, Ciudad Universitaria, 1428 Buenos Aires, Argentina 
690 1 0 |a POLYMETHYL METHACRYLATE 
690 1 0 |a POLYURETHANES 
690 1 0 |a RUBBER 
690 1 0 |a COMPLIANCE 
690 1 0 |a DYNAMIC MODULUS 
690 1 0 |a POLY(N-OCTYL-METHACRYLATE) 
690 1 0 |a UNFILLED POLYURETHANE RUBBER 
690 1 0 |a POLYMERS 
700 1 |a Hermida, E.B. 
773 0 |d 1991  |g v. 12  |h pp. 35-46  |k n. 1  |p Mech Mater  |x 01676636  |t Mechanics of Materials 
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