Biodegradation of the indolic system of gramine in Hordeum vulgare
Intact Hordeum vulgare seedlings degraded [2-14C]gramine, [2-14C]indole-3-carboxaldehyde and [2-14C]indole-3-carboxylic acid to 14CO2. The plants also degraded [6-3H]gramine to labelled water. Moreover, [2-14C, 6-3H]gramine is degraded to 3H2O through tritium-labelled anthranilic acid. These results...
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1991
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| LEADER | 04759caa a22006857a 4500 | ||
|---|---|---|---|
| 001 | PAPER-416 | ||
| 003 | AR-BaUEN | ||
| 005 | 20230518202946.0 | ||
| 008 | 190411s1991 xx ||||fo|||| 00| 0 eng|d | ||
| 024 | 7 | |2 scopus |a 2-s2.0-0009426687 | |
| 040 | |a Scopus |b spa |c AR-BaUEN |d AR-BaUEN | ||
| 030 | |a PYTCA | ||
| 100 | 1 | |a Ghini, A.A. | |
| 245 | 1 | 0 | |a Biodegradation of the indolic system of gramine in Hordeum vulgare |
| 260 | |c 1991 | ||
| 270 | 1 | 0 | |m Ghini, A.A.; Departamento de Química Orgánica, Facultad de Ciencias Exactas y Naturales, Universidad de Buenos Aires, Pabellon 2, Ciudad Universitaria, 1428 Buenos Aires, Argentina |
| 506 | |2 openaire |e Política editorial | ||
| 504 | |a Ghini, Burton, Gros, (1990) Phytochemistry, 29, p. 1781 | ||
| 504 | |a Ghini, Burton, Gros, (1982) An. Asoc. Quim. Argent., 70, p. 1079 | ||
| 504 | |a Brewer, Pesce, Ashworth, (1974) Experimental Techniques in Biochemistry, , Prentice-Hall, New Jersey | ||
| 504 | |a Stahl, (1969) Thin-Layer Chromatography, , Springer, New York | ||
| 504 | |a Ghini, Burton, Gros, (1982) Phytochemistry, 21, p. 605 | ||
| 504 | |a Schallenberg, Meyer, (1981) Planta Med., 42, p. 133 | ||
| 504 | |a Metzler, (1977) Biochemistry. The Chemical Reactions of Living Cells, , Academic Press, New York | ||
| 504 | |a Dalgliesh, (1951) Q. Rev., 5, p. 227 | ||
| 504 | |a Gifford, Cossins, (1982) Phytochemistry, 21, p. 1479 | ||
| 504 | |a Gifford, Cossins, (1982) Phytochemistry, 21, p. 1485 | ||
| 504 | |a James, Snyder, (1963) Org. Synth. Call., 4, p. 539. , John Wiley, New York | ||
| 504 | |a O'Donovan, Leete, (1963) J. Am. Chem. Soc., 85, p. 461 | ||
| 504 | |a Breccia, Marion, THE BIOGENESIS OF ALKALOIDS: XXII. SOME INTERMEDIATE STEPS IN THE TRANSFORMATION OF TRYPTOPHAN TO GRAMINE (1959) Canadian Journal of Chemistry, 37, p. 1066 | ||
| 504 | |a Bowden, Marion, THE BIOGENESIS OF ALKALOIDS: V. RADIOAUTOGRAPHS OF BARLEY LEAVES FED WITH TRYPT0PHAN-β-C14 (1951) Canadian Journal of Chemistry, 29, p. 1043 | ||
| 504 | |a Leete, Marion, THE BIOGENESIS OF ALKALOIDS: X. THE ORIGIN OF THE N-METHYL GROUPS OF THE ALKALOIDS OF BARLEY (1954) Canadian Journal of Chemistry, 32, p. 646 | ||
| 504 | |a Ghini, Burton, Gros, (1986) J. Lab. Compds Radiopharm., 23, p. 857 | ||
| 504 | |a Man, (1980) Secondary Metabolism., , Clarendon Press, Oxford, Oxford Chemistry Series | ||
| 504 | |a Hankes, Henderson, (1957) J. Biol. Chem., 225, p. 349 | ||
| 504 | |a Mason, (1957) Advances in Enzymology, 29, p. 79. , Academic Press, New York | ||
| 504 | |a Wiss, Bettendorf, (1957) Z. Physiol. Chem., 306, p. 145 | ||
| 504 | |a Kirby, Ogunkoya, 1278. Deuterium and tritium exchange reactions of phenols and the synthesis of labelled 3,4-dihydroxyphenylalanines (1965) Journal of the Chemical Society (Resumed), p. 6914 | ||
| 504 | |a Magnus, Iskric, Kveder, (1971) Planta, 97, p. 116 | ||
| 520 | 3 | |a Intact Hordeum vulgare seedlings degraded [2-14C]gramine, [2-14C]indole-3-carboxaldehyde and [2-14C]indole-3-carboxylic acid to 14CO2. The plants also degraded [6-3H]gramine to labelled water. Moreover, [2-14C, 6-3H]gramine is degraded to 3H2O through tritium-labelled anthranilic acid. These results point to a breakdown of the aromatic system of gramine by successive steps involving indole-3-carboxylic acid, N-formylanthranilic acid and anthranilic acid which then follows its known degradation pathway. The last steps of the process proceed at a very fast rate. © 1992. |l eng | |
| 593 | |a Departamento de Química Orgánica, Facultad de Ciencias Exactas y Naturales, Universidad de Buenos Aires, Pabellon 2, Ciudad Universitaria, 1428 Buenos Aires, Argentina | ||
| 690 | 1 | 0 | |a BARLEY |
| 690 | 1 | 0 | |a BIODEGRADATION |
| 690 | 1 | 0 | |a GRAMINEAE |
| 690 | 1 | 0 | |a HORDEUM VULGARE |
| 690 | 1 | 0 | |a [2-14C]GRAMINE |
| 690 | 1 | 0 | |a [2-14C]INDOLE-3-CARBOXALDEHYDE |
| 690 | 1 | 0 | |a [2-14C]INDOLE-3-CARBOXYLIC ACID |
| 690 | 1 | 0 | |a [6-3H]GRAMINE. |
| 700 | 1 | |a Burton, G. | |
| 700 | 1 | |a Gros, E.G. | |
| 773 | 0 | |d 1991 |g v. 30 |h pp. 779-784 |k n. 3 |p Phytochemistry |x 00319422 |w (AR-BaUEN)CENRE-88 |t Phytochemistry | |
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| 856 | 4 | 0 | |u https://doi.org/10.1016/0031-9422(91)85251-T |y DOI |
| 856 | 4 | 0 | |u https://hdl.handle.net/20.500.12110/paper_00319422_v30_n3_p779_Ghini |y Handle |
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