Modeling sulfur dioxide uptake in dent corn during steeping

A mathematical model is employed to describe sulfur dioxide (SO 2) diffusion and reaction during steeping of dent corn. Experiments are performed to measure change of SO2 content of grain during process. A computer-aided nonlinear optimization technique is used to estimate the effective diffusion co...

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Autor principal: Haros, C.M
Otros Autores: Aguerre, R.J, Suarez, C.
Formato: Capítulo de libro
Lenguaje:Inglés
Publicado: 2005
Acceso en línea:Registro en Scopus
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100 1 |a Haros, C.M. 
245 1 0 |a Modeling sulfur dioxide uptake in dent corn during steeping 
260 |c 2005 
270 1 0 |m Suarez, C.; Depto. Industrias Tecn. de Alimentos, FCEyN-UBA, Ciudad Universitaria, Nunez, Buenos Aires 1428, Argentina; email: suarez@di.fcen.uba.ar 
506 |2 openaire  |e Política editorial 
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504 |a Chang, C.S., Rochelle, G.T., SO2 absorption into aqueous solutions (1981) American Institute of Chemical Engineering Journal, 27, pp. 292-298 
504 |a Crank, J., (1975) The Mathematics of Diffusion, , 2nd ed. Oxford University Press London 
504 |a Cussler, E.L., (1984) Diffusion, Mass Transfer in Fluids, , Cambridge University Press Cambridge, London, New York, New Rochelle, Melbourne, Sydney 
504 |a Eckhoff, S.R., Okos, M.R., Kinetics of sulfur dioxide reaction in corn grain (1986) Journal of Agriculture and Food Chemistry, 34, pp. 239-245 
504 |a Eckhoff, S.R., Okos, M.R., Sorption kinetics of sulfur dioxide on yellow dent corn (1990) Transactions of the ASAE, 33, pp. 855-861 
504 |a Fan, L.T., Chen, H.G., Shellenberger, J.A., Chung, D.S., Comparison of the rates of absorption of water by corn kernel with and without dissolved sulfur dioxide (1965) Cereal Chemistry, 42, pp. 385-396 
504 |a Fuller, E.C., Crist, R.H., The rate of oxidation of sulfite ions by oxygen (1941) Journal of the American Chemical Society, 63, pp. 1644-1650 
504 |a Haros, C.M., Aguerre, R.J., Suarez, C., Absorption kinetics of sulfur dioxide in flint corn during steeping (2001) Lebensmittel-Wissenschaft Und-Technologie, 34, pp. 293-298 
504 |a Haros, C.M., Suarez, C., Effect of drying, initial moisture and variety in corn wet milling (1998) Journal of Food Engineering, 34, pp. 473-481 
504 |a Haros, C.M., Viollaz, P.E., Suarez, C., Effect of temperature and SO2 on the rates of water absorption on three maize hybrids (1995) Journal of Food Engineering, 25, pp. 473-482 
504 |a Hegg, D.A., Hobbs, P.V., Oxidation of sulfur dioxide in aqueous systems with particular reference to the atmosphere (1978) Atmospheric Environment, 12, pp. 241-253 
504 |a Hsu, H.K., A diffusion model with a concentration-dependent diffusion coefficient for describing water movement in legumes during soaking (1983) Journal of Food Science, 48, pp. 618-622 
504 |a Legault, R.R., Hendel, C.E., Talburt, W.F., Rasnussan, L.B., Sulfite disappearance in dehydrated vegetable during storage (1949) Industrial and Engineering Chemistry, 41, pp. 1447-1451 
504 |a Lomauro, C.L., Babshi, A.S., Labuza, T.P., Evaluation of food moisture sorption isotherm equations. Part I (1985) Lebensmittel-Wissenschaft Und-Technologie, 18, pp. 111-117 
504 |a Maga, J.A., Cereal volatiles, a review (1978) Journal of Agriculture and Food Chemistry, 26, pp. 175-178 
504 |a May, J.B., Wet milling: Process and products (1987) Corn: Chemistry and Technology, pp. 377-397. , S.A. Watson P.E. Ramstad American Association of Cereal Chemists St. Paul 
504 |a Parry, J.L., Mathematical modelling and computer simulation of heat and mass transfer in agricultural grain drying: A review (1985) Journal of Agricultural Engineering Research, 32, pp. 1-29 
504 |a Perry, R.H., Chilton, C.H., (1973) Chemical Engineering Handbook. (5th Ed.), , Int. Student. Tokyo: McGraw Hill Kogakusha, Ltd 
504 |a Ponting, J.D., Johnson, G., Determination of sulfur dioxide in fruits (1945) Industrial and Engineering Chemistry, 17, pp. 682-686 
504 |a Robutti, J.L., Borras, F.S., Eyherarbide, G.H., Zein composition of mechanically separated coarse and fine portions of maize hybrids (1997) Cereal Chemistry, 74, pp. 75-78 
504 |a Rodriguez, N., Zaritzky, N.E., Modeling of sulfur dioxide uptake in pre-peeled potatoes of different geometrical shapes (1986) Journal of Food Science, 51, pp. 618-622 
504 |a Rossello, C., Cañellas, J., Santiesteban, I., Mulet, A., Simulation of the absorption process of sulphur dioxide in apricots (1993) Lebensmittel-Wissenschaft Und-Technologie, 26, pp. 322-328 
504 |a Schroeter, L.C., Kinetics of air oxidation of sulfurous acid salts (1963) Journal of Pharmaceutical Sciences, 52, pp. 559-563 
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520 3 |a A mathematical model is employed to describe sulfur dioxide (SO 2) diffusion and reaction during steeping of dent corn. Experiments are performed to measure change of SO2 content of grain during process. A computer-aided nonlinear optimization technique is used to estimate the effective diffusion coefficients and rate constants in the temperature range 25-55°C. The effective diffusion coefficient for SO2 varied between 2.27×10-11 and 6.24×10-11 m 2/s and had an Arrhenius activation energy of 24.3 kJ/mol. The reaction rate of SO2 in dent corn followed first-order kinetics, with rate constants in the range of 0.80×10-6-5.38×10 -6 s-1 and activation energy of 49.16 kJ/mol. © 2004 Published by Elsevier Ltd.on behalf of Swiss Society of Food Science and Technology.  |l eng 
536 |a Detalles de la financiación: Universidad de Buenos Aires 
536 |a Detalles de la financiación: We acknowledge the financial support of CONICET and Universidad de Buenos Aires. 
593 |a Depto. Industrias Tecn. de Alimentos, FCEyN-UBA, Ciudad Universitaria, Nunez, Buenos Aires 1428, Argentina 
593 |a Departamento de Tecnología, Universidad de Luján, Cruce Rutas 5 y 7, C.C. 221, Pcia. de Buenos Aires, Argentina 
690 1 0 |a SULFUR DIOXIDE ABSORPTION 
690 1 0 |a SULFUR DIOXIDE DIFFUSIVITY 
690 1 0 |a SULFUR DIOXIDE REACTION 
690 1 0 |a ACTIVATION ENERGY 
690 1 0 |a DIFFUSION 
690 1 0 |a GRAIN (AGRICULTURAL PRODUCT) 
690 1 0 |a NONLINEAR SYSTEMS 
690 1 0 |a OPTIMIZATION 
690 1 0 |a RATE CONSTANTS 
690 1 0 |a SULFUR DIOXIDE 
690 1 0 |a COMPUTER-AIDED NONLINEAR OPTIMIZATION 
690 1 0 |a DIFFUSION COEFFICIENTS 
690 1 0 |a FIRST-ORDER KINETICS 
690 1 0 |a NONLINEAR OPTIMIZATION 
690 1 0 |a FOOD PRODUCTS 
690 1 0 |a ACTIVATION ENERGY 
690 1 0 |a CHEMICAL REACTIONS 
690 1 0 |a CORN 
690 1 0 |a DIFFUSION 
690 1 0 |a OPTIMIZATION 
690 1 0 |a SULFUR DIOXIDE 
690 1 0 |a ZEA MAYS 
700 1 |a Aguerre, R.J. 
700 1 |a Suarez, C. 
773 0 |d 2005  |g v. 38  |h pp. 393-398  |k n. 4  |p LWT - Food Sci. Technol.  |x 00236438  |w (AR-BaUEN)CENRE-292  |t LWT - Food Science and Technology 
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