Underpotential deposition and dielectric electronegativity scale

The in situ differential reflectance spectrum of a polycrystalline gold electrode in 1 mol dm -3 HClO 4 solutions as a function of coverage of Pb, Ag and Cu adatoms, has been measured in the visible region. The optical response of the metal modified surfaces was analysed through correlations with pa...

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Autor principal: Alcober, C.
Otros Autores: Bilmes, S.A, Calvo, E., Posadas, D.
Formato: Capítulo de libro
Lenguaje:Inglés
Publicado: 1994
Acceso en línea:Registro en Scopus
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100 1 |a Alcober, C. 
245 1 0 |a Underpotential deposition and dielectric electronegativity scale 
260 |c 1994 
270 1 0 |m Bilmes, S.A.; Departamento de Química Inorgánica, Analítica y Quimica Física, Facultad de Ciencias Exactas y Naturales, Universidad de Buenos Aires, 1428 Buenos Aires, Argentina 
506 |2 openaire  |e Política editorial 
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520 3 |a The in situ differential reflectance spectrum of a polycrystalline gold electrode in 1 mol dm -3 HClO 4 solutions as a function of coverage of Pb, Ag and Cu adatoms, has been measured in the visible region. The optical response of the metal modified surfaces was analysed through correlations with parameters related to the electronic properties of the surface such as the electronic work function difference between the substrate and the metal adatoms and the dielectric electronegativity difference. A reasonable correlation between the interband threshold and the dielectric electronegativity difference was found.  |l eng 
593 |a Departamento de Química Inorgánica, Analítica y Quimica Física, Facultad de Ciencias Exactas y Naturales, Universidad de Buenos Aires, 1428 Buenos Aires, Argentina 
593 |a Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas (INIFTA), Facultad de Ciencias Exactas, Universidad Nacional de la Plata, Casilla de Correo 16, 1900 La Plata, Argentina 
700 1 |a Bilmes, S.A. 
700 1 |a Calvo, E. 
700 1 |a Posadas, D. 
773 0 |d 1994  |g v. 90  |h pp. 2395-2399  |k n. 16  |x 09565000  |t Journal of the Chemical Society, Faraday Transactions 
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856 4 0 |u https://doi.org/10.1039/FT9949002395  |y DOI 
856 4 0 |u https://hdl.handle.net/20.500.12110/paper_09565000_v90_n16_p2395_Alcober  |y Handle 
856 4 0 |u https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_09565000_v90_n16_p2395_Alcober  |y Registro en la Biblioteca Digital 
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