Origin of mixed-layered (R1) muscovite-chlorite in an anchizonal slate from Puncoviscana Formation (Salta Province, Argentina)

Mica-chlorite mixed-layering was identified by X-ray diffraction (XRD) as a major or subordinate constituent in several slates of the Puncoviscana Formation from Sierra de Mojotoro (Eastern Cordillera, NW Argentina). In order to determine the crystallochemical characteristics of these mixed-layered...

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Autor principal: Do Campo, M.
Otros Autores: Nieto, F.
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Lenguaje:Inglés
Publicado: 2005
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100 1 |a Do Campo, M. 
245 1 0 |a Origin of mixed-layered (R1) muscovite-chlorite in an anchizonal slate from Puncoviscana Formation (Salta Province, Argentina) 
260 |c 2005 
270 1 0 |m Do Campo, M.; Instituto de Geocronología y Geología Isotópica, Facultad de Ciencias Exactas y Naturales, U.B.A., 1428 Buenos Aires, Argentina; email: docampo@ingeis.uba.ar 
506 |2 openaire  |e Política editorial 
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504 |a Do Campo, M., (1999) Mineralogía, Geoquímica Y Geocronología De La Formación Puncoviscana (Neoproterozoico) Entre Los 23°30′ Y 25°50′ De Latitud Sur, Noroeste De Argentina, p. 287. , PhD thesis (unpublished), Universidad de Buenos Aires, Argentina 
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504 |a Omarini, R.H., (1983) Caracterización Litológica, Diferenciación Y Génesis De La Formación Puncoviscana Entre El Valle De Lerma Y La Faja Eruptiva De La Puna, p. 202. , PhD thesis (unpublished), Universidad Nacional de Salta, Argentina 
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520 3 |a Mica-chlorite mixed-layering was identified by X-ray diffraction (XRD) as a major or subordinate constituent in several slates of the Puncoviscana Formation from Sierra de Mojotoro (Eastern Cordillera, NW Argentina). In order to determine the crystallochemical characteristics of these mixed-layered sequences and interpret their petrological meaning, anchizonal slate P90 was chosen for TEM observations. In this slate, dioctahedral mica and chlorite form interleaved phyllosilicate grains (IPG) or stacks, up to 110 μm long, preferentially oriented with (001) planes at a high angle to the slaty cleavage but also oblique to S0. In agreement with XRD results, the main phyllosilicates identified by transmission electron microscopy (TEM) were dioctahedral mica and random mixed-layer muscovite-chlorite, with chlorite in subordinate amounts and scarce smectite. In the lattice-fringe images of mixed-layer packets, a sequence of irregular stacking that produced apparent 24 Å (10 + 14) layers was observed, but it was frequently possible to distinguish the 10 Å layers from adjacent 14 Å layers. In nearly all packets, 14 Å layers prevail, exhibiting 14 Å:10 Å ratios between 1:1 and 3:1. Some elongated lenticular fissures which are probably a consequence of layer collapse caused by the TEM vacuum were identified in these packets. The straight, continuous appearance of lattice fringes plus the scarce evidence of collapsed layers identified suggest that these packets correspond principally to mixed-layer muscovite-chlorite, which is confirmed by analytical electron microscopy analyses. However, smectite-like layers are probably the third component of some of these mixed-layer sequences, which may account for their high Si and low (Fe + Mg) contents, their low interlayer charge in relation to theoretical interlayer muscovite-chlorite, and for the presence of Ca in the interlayer site. Textural relationships between chlorite and muscovite packets in IPG along with the observed transformations from 14 Å to 10 Å along the layer, is compatible with a prograde metamorphic replacement of chlorite in stacks by dioctahedral mica layers, probably in the presence of an aqueous fluid. © 2005 The Mineralogical Society.  |l eng 
593 |a Instituto de Geocronología y Geología Isotópica, Facultad de Ciencias Exactas y Naturales, U.B.A., 1428 Buenos Aires, Argentina 
593 |a Departamento de Mineralogía y Petrología, I.A.C.T., Universidad de Granada-CSIC, Avda. Fuentenueva s/n, 18002 Granada, Spain 
690 1 0 |a ANCHIZONE 
690 1 0 |a CENTRAL ANDES 
690 1 0 |a MIXED-LAYERING 
690 1 0 |a PUNCOVISCANA FORMATION 
690 1 0 |a CRYSTAL LATTICES 
690 1 0 |a CRYSTALLOGRAPHY 
690 1 0 |a ENERGY DISPERSIVE SPECTROSCOPY 
690 1 0 |a IMAGE ANALYSIS 
690 1 0 |a METAMORPHIC ROCKS 
690 1 0 |a SCANNING ELECTRON MICROSCOPY 
690 1 0 |a SLATE 
690 1 0 |a TRANSMISSION ELECTRON MICROSCOPY 
690 1 0 |a X RAY DIFFRACTION ANALYSIS 
690 1 0 |a ANCHIZONAL SLATE 
690 1 0 |a LATTICE FRINGES 
690 1 0 |a MIXED LAYERING 
690 1 0 |a MUSCOVITE-CHLORITE 
690 1 0 |a CHLORIDE MINERALS 
690 1 0 |a CHLORITE 
690 1 0 |a CLAY MINERAL 
690 1 0 |a MINERAL ALTERATION 
690 1 0 |a WESTERN HEMISPHERE 
690 1 0 |a WORLD 
651 4 |a ARGENTINA 
651 4 |a ARGENTINA 
651 4 |a ARGENTINA 
651 4 |a SALTA [ARGENTINA] 
651 4 |a SOUTH AMERICA 
650 1 7 |2 spines  |a MICA 
650 1 7 |2 spines  |a MICA 
700 1 |a Nieto, F. 
773 0 |d 2005  |g v. 40  |h pp. 317-332  |k n. 3  |p Clay Miner.  |x 00098558  |t Clay Minerals 
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