Cleavage reaction of 5β,6β steroidal epoxides carrying different groups at C-3
The particular behavior of 5β,6β steroidal epoxides carrying different groups at C-3 was studied. These epoxides may exhibit different cleavage behavior according to the nature of the solvent, the acid-base state of the medium, and the leaving abilities of the C-3 substituent. Results and alternativ...
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| Formato: | Capítulo de libro |
| Lenguaje: | Inglés |
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1995
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| LEADER | 08197caa a22009257a 4500 | ||
|---|---|---|---|
| 001 | PAPER-3695 | ||
| 003 | AR-BaUEN | ||
| 005 | 20230518203309.0 | ||
| 008 | 190411s1995 xx ||||fo|||| 00| 0 eng|d | ||
| 024 | 7 | |2 scopus |a 2-s2.0-0029155626 | |
| 024 | 7 | |2 cas |a Cations; Epoxy Compounds; Lithium, 7439-93-2; Solvents; Steroids | |
| 040 | |a Scopus |b spa |c AR-BaUEN |d AR-BaUEN | ||
| 030 | |a STEDA | ||
| 100 | 1 | |a Gros, E.G. | |
| 245 | 1 | 0 | |a Cleavage reaction of 5β,6β steroidal epoxides carrying different groups at C-3 |
| 260 | |c 1995 | ||
| 270 | 1 | 0 | |m Galagovsky, L.R. |
| 506 | |2 openaire |e Política editorial | ||
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| 520 | 3 | |a The particular behavior of 5β,6β steroidal epoxides carrying different groups at C-3 was studied. These epoxides may exhibit different cleavage behavior according to the nature of the solvent, the acid-base state of the medium, and the leaving abilities of the C-3 substituent. Results and alternative mechanisms are presented. © 1995. |l eng | |
| 593 | |a Departamento de Química Orgánica, Facultad de Ciencias Exactas y Naturales, Universidad de Buenos Aires, Ciudad Universitaria, Buenos Aires, Argentina | ||
| 690 | 1 | 0 | |a CLEAVAGE OF EPOXIDES |
| 690 | 1 | 0 | |a RING A STEROIDAL ELIMINATION |
| 690 | 1 | 0 | |a STEROIDAL EPOXIDES |
| 690 | 1 | 0 | |a EPOXIDE |
| 690 | 1 | 0 | |a LITHIUM CHLORIDE |
| 690 | 1 | 0 | |a N,N DIMETHYLACETAMIDE |
| 690 | 1 | 0 | |a STEROID |
| 690 | 1 | 0 | |a ARTICLE |
| 690 | 1 | 0 | |a CHEMICAL REACTION |
| 690 | 1 | 0 | |a DEGRADATION |
| 690 | 1 | 0 | |a PROTON NUCLEAR MAGNETIC RESONANCE |
| 690 | 1 | 0 | |a CATIONS |
| 690 | 1 | 0 | |a EPOXY COMPOUNDS |
| 690 | 1 | 0 | |a LITHIUM |
| 690 | 1 | 0 | |a MOLECULAR STRUCTURE |
| 690 | 1 | 0 | |a SOLVENTS |
| 690 | 1 | 0 | |a STEROIDS |
| 690 | 1 | 0 | |a SUPPORT, NON-U.S. GOV'T |
| 650 | 1 | 7 | |2 spines |a PH |
| 773 | 0 | |d 1995 |g v. 60 |h pp. 434-438 |k n. 7 |p Steroids |x 0039128X |w (AR-BaUEN)CENRE-577 |t Steroids | |
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| 856 | 4 | 0 | |u https://hdl.handle.net/20.500.12110/paper_0039128X_v60_n7_p434_Gros |y Handle |
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