Hydrogen production from the low-temperature water-gas shift reaction: Kinetics and simulation of the industrial reactor

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The kinetics of the water-gas shift reaction (WGSR) over a copper/zinc oxide/alumina catalyst have been studied. The experiments were carried out at 453-503 K and atmospheric pressure. A reactive mixture of similar composition to that employed in the industrial process was used. An integral reactor,...

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Autor principal: Amadeo, Norma Elvira
Otros Autores: Laborde, M.A
Formato: Capítulo de libro
Lenguaje:Inglés
Publicado: 1995
Acceso en línea:Registro en Scopus
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Biblioteca Central Dr. Luis F. Leloir (FCEN) de Universidad de Buenos Aires
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100 1 |a Amadeo, Norma Elvira 
245 1 0 |a Hydrogen production from the low-temperature water-gas shift reaction: Kinetics and simulation of the industrial reactor 
260 |c 1995 
270 1 0 |m Amadeo, N.E.; Departamento de Ingenieria Química(FI), PINMATE(FCEyN) Universidad de Buenos Aires, CONICETArgentina 
504 |a Newsome, (1980) Catal. Rev. Sci. Engng, 21, p. 275 
504 |a Moe, (1962) Chem. Engng Progr., 58, p. 33 
504 |a Bohlbro, The Kinetics of the Water Gas Conversion. II. Investigations at Elevated Pressures. (1962) Acta Chemica Scandinavica, 16, p. 431 
504 |a Shchibrya, Morozov, Temkin, (1965) Kinet. Catal., USSR, 6, p. 1010 
504 |a Cherednik, Morozov, Temkin, (1969) Kinet. Catal., USSR, 10, p. 94 
504 |a Semenova, Lyudkovskaya, Markina, Volynkina, Cherkasov, Sharkina, Khitrova, Shpiro, (1977) Kinet. Katal., USSR, 18, p. 1014 
504 |a Kuijpers, Tjepkema, van der Wal, (1986) Appl. Catal., 25, p. 139 
504 |a Chinchen, Spencer, Waught, Whan, (1987) J. Chem. Soc., Faraday Trans. 1, 83, p. 2193 
504 |a Nakamura, Campbell, Campbell, (1990) J. Chem. Soc. Faraday Trans., 86, p. 2725 
504 |a Colbourn, Hadden, Vandervell, Waugh, Webb, (1991) J. Catal., 130, p. 514 
504 |a Ernst, Campbell, Moretti, (1992) J. Catal., 134, p. 66 
504 |a Fujita, Usui, Usui, Takezawa, (1992) J. Catal., 134, p. 220 
504 |a Fiolitakis, Hofmann, (1983) J. Catal., 80, p. 328 
504 |a Van Herwijnen, On the kinetics and mechanism of the CO-shift conversion on a copper/zinc oxide catalyst (1973) Ph.D. Thesis, , 3rd edn, Delft University, The Netherlands 
504 |a Amenomiya, (1979) J. Catal., 57, p. 64 
504 |a Van Herwijnen, de Jong, (1980) J. Catal., 63, p. 83 
504 |a Van Herwijnen, Guzalski, de Jong, (1980) J. Catal., 63, p. 94 
504 |a Grenoble, Estadt, Ollis, (1981) J. Catal., 67, p. 90 
504 |a De Porter, A comprehensive mechanism for the Fischer-Tropsch synthesis (1981) Chemical Reviews, 81, p. 447 
504 |a Amenomiya, Pleizier, (1982) J. Catal., 76, p. 345 
504 |a Edwards, Scharader, (1984) J. Phys. Chem., 88, p. 5620 
504 |a Bybell, Deutsch, Herman, Himelfarb, Nunan, Young, Bogdan, Klier, (1986) Syposium on Fundamental Chemistry of Promoters and Poisons in Heterogeneous Catalysis, p. 116. , New York, 13–18 April 
504 |a Klier, Young, Nunan, (1986) Ind. Engng Chem. Fundam., 25, p. 36 
504 |a Salmi, Hakkarainen, (1989) Appl. Catal., 49, p. 285 
504 |a Campbell, Daube, (1987) J. Catal., 104, p. 109 
504 |a Kinnaird, Webb, Chinchen, (1987) J. Chem. Soc., Faraday Trans. 1, 83, p. 3399 
504 |a Quincoces, Amadeo, González, (1992) XII Simposio Iberoamericano de Catálisis, Segovia, España, 1, p. 529. , 3rd edn 
504 |a Barreto, González, Laborde, Moreno, Viñas, (1991) 7mas Jornadas Argentinas de Catálisis, , Mar del Plata, Argentina 
504 |a Amadeo, Cerrella, Laborde, Pennella, (1992) XIII Simposio Iberoamericano de Catálisis, Segovia, España, 2, p. 779. , 3rd edn 
504 |a N. E. Amadeo, E. G. Cerrella, M. A. Laborde and F. Pennella, Latin Am. Appl. Res. (in press); Barreto, González, Laborde, Moreno, Viñas, (1990) XII Simposio Iberoamericano de Catalise, , Rio de Janeiro 
504 |a Quiroga, Gottifredi, (1982) Avances en la Determinación de Parámetros Cinéticos en Sistemas de Reacciones Complejas, , Fundación para la educación, la ciencia y la cultura, Buenos Aires, Argentina 
504 |a Campbell, (1970) Ind. Engng Chem. Proc. Res. Dev., 9, p. 588. , 3rd edn 
504 |a Froment, Bischoff, (1979) Chemical Reactor, Analysis and Design, , 3rd edn, Wiley, New York 
504 |a Ovesen, Stoltze, Norskov, Campbell, (1992) J. Catal., 134, p. 445 
504 |a Rase, (1977) Chemical Reactors Design for Process Plants, 2. , 3rd edn, Wiley, New York 
504 |a Velasco, Ortiz, Marcos, Amadeo, Laborde, Paz, Optimal inlet temperature trajectories for adiabatic packed reactors with catalyst decay (1992) Chemical Engineering Science, 47, p. 1495 
504 |a Boudart, (1968) Kinetics of Chemical Processes, , 3rd edn, Prentice Hall, New York 
506 |2 openaire  |e Política editorial 
520 3 |a The kinetics of the water-gas shift reaction (WGSR) over a copper/zinc oxide/alumina catalyst have been studied. The experiments were carried out at 453-503 K and atmospheric pressure. A reactive mixture of similar composition to that employed in the industrial process was used. An integral reactor, an integral procedure and a data treatment valid for near equilibrium conditions were employed. A number of representative models were examined. It was found that only a Langmuir-Hinshelwood model, which considers the adsorption of four species (CO, CO2, H2 and H2O) and the surface reaction as the controlling step, adequately describes the reaction behaviour at the temperature and concentration ranges investigated. Values of adsorption constants and adsorption heats for the four components involved in the WGSR are given. An algorithm for the simulation of an adiabatic fixed-bed reactor was developed with the aim of checking the kinetics expression. Both the industrial and simulated compositions agree. It is proved that the kinetic expression proposed which is in harmony with a Langmuir-Hinshelwood mechanism is useful in designing industrial low-temperature converters. © 1995.  |l eng 
536 |a Detalles de la financiación: Acknowlrdgrments---The authors thank CONICET (Consejo National de Investigaciones Cientificas y Tecnicas), the Univer-sidad de Buenos Aires and the Antorchas Foundation for financial support. They also thank Dr Graciela Cerrella for the experimental work. 
593 |a Departamento de Ingenieria Química(FI), PINMATE(FCEyN) Universidad de Buenos Aires, CONICET, Argentina 
593 |a Pabellón de Industrias, Ciudad Universitaria 1428 Buenos Aires, Argentina 
690 1 0 |a ADSORPTION 
690 1 0 |a ALGORITHMS 
690 1 0 |a ATMOSPHERIC PRESSURE 
690 1 0 |a CARBON DIOXIDE 
690 1 0 |a CARBON MONOXIDE 
690 1 0 |a CATALYSTS 
690 1 0 |a CHEMICAL REACTORS 
690 1 0 |a COMPUTER SIMULATION 
690 1 0 |a LOW TEMPERATURE EFFECTS 
690 1 0 |a MATHEMATICAL MODELS 
690 1 0 |a REACTION KINETICS 
690 1 0 |a WATER 
690 1 0 |a HYDROGEN PRODUCTION 
690 1 0 |a INDUSTRIAL LOW-TEMPERATURE CONVERTERS 
690 1 0 |a LANGMUIR-HINSHELWOOD MODEL 
690 1 0 |a WATER-GAS SHIFT REACTION 
690 1 0 |a HYDROGEN 
700 1 |a Laborde, M.A. 
773 0 |d 1995  |g v. 20  |h pp. 949-956  |k n. 12  |p Int J Hydrogen Energy  |x 03603199  |w (AR-BaUEN)CENRE-5264  |t International Journal of Hydrogen Energy 
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856 4 0 |u https://doi.org/10.1016/0360-3199(94)00130-R  |y DOI 
856 4 0 |u https://hdl.handle.net/20.500.12110/paper_03603199_v20_n12_p949_Amadeo  |y Handle 
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999 |c 64603 

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