Kinetic studies on the glutamate:glyoxylate transaminase of Euglena gracilis

The kinetic properties of L-glutamate:glyoxylate transminase have been investigated. Glycine formation was linear with both protein concentration and incubation time. L-glutamate was the most effective amino donor. Optimal concentrations for L-glutamate and glyoxylate were 150-200 mM and 10-20 mM, r...

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Autor principal: Lombardo, M.E
Otros Autores: Araujo, L.S, Del C. Batlle, A.M
Formato: Capítulo de libro
Lenguaje:Inglés
Publicado: 1996
Acceso en línea:Registro en Scopus
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Registro en la Biblioteca Digital
Aporte de:Registro referencial: Solicitar el recurso aquí
LEADER 05861caa a22007217a 4500
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024 7 |2 scopus  |a 2-s2.0-0030484653 
024 7 |2 cas  |a aminotransferase, 9031-66-7; glutamic acid, 11070-68-1, 138-15-8, 56-86-0, 6899-05-4; glycine, 56-40-6, 6000-43-7, 6000-44-8; glyoxylic acid, 298-12-4 
040 |a Scopus  |b spa  |c AR-BaUEN  |d AR-BaUEN 
030 |a JPPBE 
100 1 |a Lombardo, M.E. 
245 1 0 |a Kinetic studies on the glutamate:glyoxylate transaminase of Euglena gracilis 
260 |c 1996 
270 1 0 |m Del C Batlle, A.M.Viamonte 1881, 10 A, CP-1056 Buenos Aires, Argentina 
506 |2 openaire  |e Política editorial 
504 |a Collins, N., Merrett, M.J., The localization of glycollate-pathway enzymes, Euglena (1975) Biochem. J., 148, pp. 321-328 
504 |a Noguchi, T., Mori, R., Biosynthesis of porphyrin precursors in mammals. Identity of alanine: ,δ-dioxovalerate aminotransferase with alanine: Glyoxylate aminotransferase (1981) J. Biol. Chem., 256, pp. 10335-10339 
504 |a Foley, T., Beale, S.I., δ-Aminolevulinic acid formation from ,δ-dioxovaleric acid in extracts of Euglena gracilis (1982) Plant Physiol., 70, pp. 1495-1502 
504 |a Shioi, Y., Nagamine, M., Sasa, T., Purification and properties of L-alanine:4,5-dioxovalerate aminotransferase from Chlorella regularis (1984) Arch. Biochem. Biophys., 234, pp. 117-124 
504 |a Lombardo, M.E., Araujo, L.S., Juknat, A.A., Del C. Batlle, A.M., Glutmate:4,5-dioxovaleric acid transaminase from Euglena gracilis. Kinetic studies (1989) Eur. J. Biochem., 182, pp. 657-660 
504 |a Varticovski, L., Kushner, J.P., Burnham, B.F., Biosynthesis of porphyrin precursors. Purification and characterization of mammaliam L-alanine: ,δ-dioxovaleric acid aminotransferase (1980) J. Biol. Chem., 255, pp. 3742-3747 
504 |a Lombardo, M.E., Araujo, L.S., Juknat, A.A., Del C. Batlle, A.M., Effect of illumination on growth, chlorophyll content and δ-aminolevulinic acid synthesis in Euglena gracilis (1988) Comp. Biochem. Physiol., 91 B, pp. 279-284 
504 |a Lombardo, M.E., Araujo, L.S., Branca, A., Del C. Batlle, A.M., A method for estimating glycine in the presence of excess glutamate with o-phthaldialdehyde (1990) Z. Naturforsch., 45 C, pp. 911-914 
504 |a Lowry, O.H., Rosebrough, N.J., Farr, A.L., Randall, R.J., Protein measurement with the Polin phenol reagent (1951) J. Biol. Chem., 193, pp. 265-275 
504 |a Kah, A., Dörnemamm, D., Senger, H., Isolation and purification to apparent homogeneity of 4,5-dioxovalerate aminotransferase from Scenedesmus obliquus mutant C-2A′ (1988) Z. Naturforsch., 43 C, pp. 563-571 
520 3 |a The kinetic properties of L-glutamate:glyoxylate transminase have been investigated. Glycine formation was linear with both protein concentration and incubation time. L-glutamate was the most effective amino donor. Optimal concentrations for L-glutamate and glyoxylate were 150-200 mM and 10-20 mM, respectively. Initial velocity studies suggested a ping-pong reaction mechanism with a K(m) value of 89.90-66.50 mM for L-glutamate and of 12.50-10.75 mM for glyoxylate. A competitive parabolic substrate inhibition by glyoxylate at concentrations greater than 20 mM was observed. A pure linear non-competitive inhibition between glyoxylate and 4,5-dioxovaleric acid (1.1-2.8 mM) was found. We show here that in vivo different enzymes exist for the transamination of glyoxylate and DOVA.  |l eng 
536 |a Detalles de la financiación: National Council for Scientific Research 
536 |a Detalles de la financiación: Consejo Nacional de Investigaciones Científicas y Técnicas 
536 |a Detalles de la financiación: Maria Elisa Lombardo and Alcira M. del C. Batlle hold the post of Scientific Researchers in the Argentine National Research Council (CONICET). Lidi~: Susana Araujo is a Research Fellow of the University of Buenos Aires. This work was supported by grants from the CONICET. 
593 |a Ctro. de Invest. Sobre P., Ciudad Universitaria Pab. II 2do., Piso - 1428, Buenos Aires, Argentina 
593 |a Viamonte 1881, 10 A, CP-1056 Buenos Aires, Argentina 
690 1 0 |a 5-AMINOLEVULINIC ACID BIOSYNTHESIS 
690 1 0 |a EUGLENA GRACILIS 
690 1 0 |a GLUTAMATE:4,5-DIOXOVALERATE TRASAMINASE 
690 1 0 |a GLUTAMATE:GLYOXYLATE TRANSAMINASE 
690 1 0 |a AMINOTRANSFERASE 
690 1 0 |a GLUTAMIC ACID 
690 1 0 |a GLYCINE 
690 1 0 |a GLYOXYLIC ACID 
690 1 0 |a VALERIC ACID DERIVATIVE 
690 1 0 |a ARTICLE 
690 1 0 |a CONTROLLED STUDY 
690 1 0 |a ENZYME INHIBITION 
690 1 0 |a ENZYME KINETICS 
690 1 0 |a ENZYME MECHANISM 
690 1 0 |a ENZYME SUBSTRATE COMPLEX 
690 1 0 |a EUGLENA GRACILIS 
690 1 0 |a NONHUMAN 
690 1 0 |a PRIORITY JOURNAL 
690 1 0 |a TRANSAMINATION 
700 1 |a Araujo, L.S. 
700 1 |a Del C. Batlle, A.M. 
773 0 |d 1996  |g v. 36  |h pp. 241-244  |k n. 3  |p J. PHOTOCHEM. PHOTOBIOL. B BIOL.  |x 10111344  |w (AR-BaUEN)CENRE-515  |t Journal of Photochemistry and Photobiology B: Biology 
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856 4 0 |u https://hdl.handle.net/20.500.12110/paper_10111344_v36_n3_p241_Lombardo  |y Handle 
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