Chemo-enzymatic synthesis of 1-O-hexadecyl-2-O-palmitoyl-sn-glycerol
Chemoenzymatic synthesis of 1-O-hexadecyl-2-O-palmitoyl-sn-glycerol was achieved by esterification of 1-O-hexadecyl-sn-glycerol, with palmitic acid in the presence of N,N-dicyclohexylcarbodiimide, and then subjected to alcoholysis catalysed by an immobilized 1,3-specific lipase. The highest yield (9...
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| Formato: | Capítulo de libro |
| Lenguaje: | Inglés |
| Publicado: |
1997
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| Acceso en línea: | Registro en Scopus DOI Handle Registro en la Biblioteca Digital |
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| LEADER | 04312caa a22006497a 4500 | ||
|---|---|---|---|
| 001 | PAPER-3168 | ||
| 003 | AR-BaUEN | ||
| 005 | 20230518203237.0 | ||
| 008 | 190411s1997 xx ||||fo|||| 00| 0 eng|d | ||
| 024 | 7 | |2 scopus |a 2-s2.0-0030880420 | |
| 040 | |a Scopus |b spa |c AR-BaUEN |d AR-BaUEN | ||
| 030 | |a BILED | ||
| 100 | 1 | |a Salto, M.L. | |
| 245 | 1 | 0 | |a Chemo-enzymatic synthesis of 1-O-hexadecyl-2-O-palmitoyl-sn-glycerol |
| 260 | |c 1997 | ||
| 270 | 1 | 0 | |m De Lederkremer, R.M.; Depatamento de Quimica Organica, Facultad Ciencias Exactas Naturales, Universidad de Buenos Aires, Pabellon 11, 1428 Buenos Aires, Argentina |
| 506 | |2 openaire |e Política editorial | ||
| 504 | |a Acosta Serrano, A., Schenkman, S., Yoshida, N., Mehlert, A., Richardson, J.M., Ferguson, M.A.J., (1995) J. Biol. Chem., 270, pp. 27244-27253 | ||
| 504 | |a Bertello, L.E., Gonçalvez, M.F., Colli, W., Lederkremer, R.M., (1995) Biochem. J., 310, pp. 255-261 | ||
| 504 | |a Bertello, L.E., Salto, M.L., Lederkremer, R.M., (1997) Lipids, , in press | ||
| 504 | |a Bornscheuer, U.T., (1995) Enzyme Microb. Technol., 17, pp. 578-586 | ||
| 504 | |a Haraldsson, G.G., Thorarensen, A., (1994) Tetrahedron Lett., 35, pp. 7681-7684 | ||
| 504 | |a Heise, N., Raper, J., Buxbaum, L.U., Peranovich, T.M.S., Cardoso De Almeida, M.L., (1996) J. Biol. Chem., 271, pp. 16877-16887 | ||
| 504 | |a Kwon, S.J., Han, J.J., Rhee, J.S., (1995) Enzyme Microb. Technol., 17, pp. 700-704 | ||
| 504 | |a Lederkremer, R.M., Lima, C.E., Ramirez, M.I., Gonçalvez, M.F., Colli, W., (1993) Eur. J. Biochem., 218, pp. 929-936 | ||
| 504 | |a Lutton, E.S., Stewart, C.B., (1970) Lipids, 5, pp. 545-553 | ||
| 504 | |a McConville, M.J., Ferguson, M.A.J., (1993) Biochem. J., 294, pp. 305-324 | ||
| 504 | |a Millqvist, A., Adlercreutz, P., Mattiasson, Bo., (1994) Enzyme Microb. Technol., 16, pp. 1042-1047 | ||
| 504 | |a Ogawa, T., Horisaki, T., (1983) Carbohydr. Res., 123, pp. C1-C4 | ||
| 504 | |a Subrahmanyam, C., Venkateswara Rao, C., Anjaneyulu, V., Satyanarayana, P., Subba Rao, P.V., (1992) Tetrahedron, 48, pp. 3111-3120 | ||
| 504 | |a Suzuki, S., Taneda, Y., Hirai, S., Satoh, Y., Toyota, T., (1993) Diabetes, 42, pp. 988-994 | ||
| 520 | 3 | |a Chemoenzymatic synthesis of 1-O-hexadecyl-2-O-palmitoyl-sn-glycerol was achieved by esterification of 1-O-hexadecyl-sn-glycerol, with palmitic acid in the presence of N,N-dicyclohexylcarbodiimide, and then subjected to alcoholysis catalysed by an immobilized 1,3-specific lipase. The highest yield (90% from 0.3 mM) was obtained in 3 h, using methyl isobutyl ketone as solvent with water activity 0.2. |l eng | |
| 536 | |a Detalles de la financiación: Universidad de Buenos Aires | ||
| 536 | |a Detalles de la financiación: Consejo Nacional de Investigaciones Científicas y Técnicas | ||
| 536 | |a Detalles de la financiación: We thank CONICET (Consejo Nacional de Investigaciones Científicas y Técnicas) and the University of Buenos Aires for financial support. | ||
| 593 | |a Depto. de Quim. Orgánica, Fac. de Ciencias Exactas y Naturales, Ciudad Universitaria, Pabellón II, 1428 Buenos Aires, Argentina | ||
| 690 | 1 | 0 | |a 4 METHYL 2 PENTANONE |
| 690 | 1 | 0 | |a DICYCLOHEXYLCARBODIIMIDE |
| 690 | 1 | 0 | |a GLYCEROL DERIVATIVE |
| 690 | 1 | 0 | |a PALMITIC ACID |
| 690 | 1 | 0 | |a SOLVENT |
| 690 | 1 | 0 | |a TRIACYLGLYCEROL LIPASE |
| 690 | 1 | 0 | |a ARTICLE |
| 690 | 1 | 0 | |a ENZYME IMMOBILIZATION |
| 690 | 1 | 0 | |a ESTERIFICATION |
| 690 | 1 | 0 | |a SYNTHESIS |
| 690 | 1 | 0 | |a TIME |
| 700 | 1 | |a Bertello, L.E. | |
| 700 | 1 | |a De Lederkremer, R.M. | |
| 773 | 0 | |d 1997 |g v. 19 |h pp. 853-855 |k n. 9 |p BIOTECHNOL. LETT. |x 01415492 |w (AR-BaUEN)CENRE-148 |t Biotechnology Letters | |
| 856 | 4 | 1 | |u https://www.scopus.com/inward/record.uri?eid=2-s2.0-0030880420&doi=10.1023%2fA%3a1018377318338&partnerID=40&md5=342f93ba8cdf1533942a1613eeb33586 |y Registro en Scopus |
| 856 | 4 | 0 | |u https://doi.org/10.1023/A:1018377318338 |y DOI |
| 856 | 4 | 0 | |u https://hdl.handle.net/20.500.12110/paper_01415492_v19_n9_p853_Salto |y Handle |
| 856 | 4 | 0 | |u https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_01415492_v19_n9_p853_Salto |y Registro en la Biblioteca Digital |
| 961 | |a paper_01415492_v19_n9_p853_Salto |b paper |c PE | ||
| 962 | |a info:eu-repo/semantics/article |a info:ar-repo/semantics/artículo |b info:eu-repo/semantics/publishedVersion | ||
| 999 | |c 64121 | ||