Analysis of the variation of molecular parameters of NR during vulcanization in the frame of the conformational tube model
The network structure of natural rubber (NR) achieved during vulcanization was analyzed using the model of rubber elasticity based on the tube concept, applied to the treatment of the stress-strain measurements. This theory allows the separation of constraint and crosslink contributions. Also, netwo...
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| Lenguaje: | Inglés |
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1997
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| Acceso en línea: | Registro en Scopus Handle Registro en la Biblioteca Digital |
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| LEADER | 04809caa a22007577a 4500 | ||
|---|---|---|---|
| 001 | PAPER-3149 | ||
| 003 | AR-BaUEN | ||
| 005 | 20250723111638.0 | ||
| 008 | 190411s1997 xx ||||fo|||| 00| 0 eng|d | ||
| 024 | 7 | |2 scopus |a 2-s2.0-0031558736 | |
| 030 | |a JAPNA | ||
| 040 | |a Scopus |b spa |c AR-BaUEN |d AR-BaUEN | ||
| 100 | 1 | |a Marzocca, Angel José | |
| 245 | 1 | 0 | |a Analysis of the variation of molecular parameters of NR during vulcanization in the frame of the conformational tube model |
| 260 | |c 1997 | ||
| 270 | 1 | 0 | |m Marzocca, A.J.; Universidad de Buenos Aires, Fac. de Ciencias Exactas y Naturales, Ciudad Universitaria, Buenos Aires (1428), Argentina |
| 504 | |a Heinrich, G., Straube, B., Helmis, G., (1988) Adv. Polym. Sci., 85, p. 33 | ||
| 504 | |a Straube, E., Heinrich, G., (1991) Kautsch. Gummi Kunstst., 44, p. 734 | ||
| 504 | |a Doi, M., Edwards, S.F., (1978) J. Chem. Soc. Faraday Trans. II, 85, p. 57 | ||
| 504 | |a Doi, M., Edwards, S.F., (1989) The Theory of Polymer Dynamics, , Oxford U.P., Oxford, UK | ||
| 504 | |a Marzocca, J.A., (1995) J. Appl. Polym. Sci., 58, p. 1839 | ||
| 504 | |a Gronski, W., Hoffmann, V., Simon, G., Wutzler, A., Straube, E., (1992) Rubber Chem. Technol., 65, p. 63 | ||
| 504 | |a Matzen, D., Straube, E., (1992) Colloid Polym. Sci., 270, p. 1 | ||
| 504 | |a Flory, P.J., (1953) Principles of Polymer Chemistry, , Cornell University Press, Ithaca, New York | ||
| 504 | |a Queslel, J.P., Mark, J.E., (1985) J. Chem. Phys., 82, p. 3449 | ||
| 504 | |a Queslel, J.P., Mark, J.E., (1985) Adv. Polym. Sci., 71, p. 229 | ||
| 504 | |a Bahar, I., Erbil, H.Y., Baysal, B.M., Erman, B., (1987) Macromolecules, 20, p. 1353 | ||
| 504 | |a Mark, J.E., Erman, B., (1988) Rubberlike Elasticity: A Molecular Primer, p. 51. , John Wiley & Sons, New York | ||
| 504 | |a Kastner, S., (1981) Colloid Polym. Sci., 259, p. 499 | ||
| 504 | |a Heinrich, G., Viglis, T.A., (1993) Macromolecules, 26, p. 1109 | ||
| 504 | |a Matteo, C.L., Gonzalez, J.J., Tischler, J.L., Marzocca, A.J., (1995) Kautsch. Gummi Kunstst., 48, p. 166 | ||
| 504 | |a Cunneen, J.I., Russell, R.M., (1970) Rubber Chem. Technol., 43, p. 1215 | ||
| 504 | |a Aharoni, S., (1986) Macromolecules, 19, p. 426 | ||
| 504 | |a Walker, L.A., Hell, W.F., (1986) Rubber Chem. Technol., 59, p. 286 | ||
| 504 | |a Loo, C.T., (1974) Polymer, 15, p. 357 | ||
| 504 | |a Simon, G., Gotschmann, B., Matzen, D., Schneider, H., (1989) Polym. Bull., 21, p. 475 | ||
| 506 | |2 openaire |e Política editorial | ||
| 520 | 3 | |a The network structure of natural rubber (NR) achieved during vulcanization was analyzed using the model of rubber elasticity based on the tube concept, applied to the treatment of the stress-strain measurements. This theory allows the separation of constraint and crosslink contributions. Also, network parameters can be calculated. The crosslink level of the material was changed using different times and temperatures of cure. The change in the molecular parameters of the model with the degree of cure was estimated. The present research is useful for the precise determination of the chemical crosslink density of the NR network. The values were compared with those obtained by means of equilibrium volume swelling measurement. © 1997 John Wiley & Sons, Inc. |l eng | |
| 593 | |a Universidad de Buenos Aires, Fac. de Ciencias Exactas y Naturales, Ciudad Universitaria, Buenos Aires (1428), Argentina | ||
| 593 | |a FATE SAICI, Research Group, Av. Blanco Encalada 3003, Prov. Buenos Aires (1644), Argentina | ||
| 690 | 1 | 0 | |a CROSSLINK DENSITY |
| 690 | 1 | 0 | |a NR VULCANIZATES |
| 690 | 1 | 0 | |a SWELLING |
| 690 | 1 | 0 | |a TUBE MODEL |
| 690 | 1 | 0 | |a CONFORMATIONS |
| 690 | 1 | 0 | |a CROSSLINKING |
| 690 | 1 | 0 | |a CURING |
| 690 | 1 | 0 | |a DENSITY (SPECIFIC GRAVITY) |
| 690 | 1 | 0 | |a ELASTICITY |
| 690 | 1 | 0 | |a MATHEMATICAL MODELS |
| 690 | 1 | 0 | |a MOLECULAR STRUCTURE |
| 690 | 1 | 0 | |a STRAIN MEASUREMENT |
| 690 | 1 | 0 | |a SWELLING |
| 690 | 1 | 0 | |a VULCANIZATION |
| 690 | 1 | 0 | |a CONFORMATION TUBE MODEL |
| 690 | 1 | 0 | |a RUBBER |
| 700 | 1 | |a Cerveny, S. | |
| 700 | 1 | |a Raimondo, R.B. | |
| 773 | 0 | |d 1997 |g v. 66 |h pp. 1085-1092 |k n. 6 |p J. Appl. Polym. Sci. |x 00218995 |w (AR-BaUEN)CENRE-330 |t Journal of Applied Polymer Science | |
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| 856 | 4 | 0 | |u https://hdl.handle.net/20.500.12110/paper_00218995_v66_n6_p1085_Marzocca |y Handle |
| 856 | 4 | 0 | |u https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_00218995_v66_n6_p1085_Marzocca |y Registro en la Biblioteca Digital |
| 961 | |a paper_00218995_v66_n6_p1085_Marzocca |b paper |c PE | ||
| 962 | |a info:eu-repo/semantics/article |a info:ar-repo/semantics/artículo |b info:eu-repo/semantics/publishedVersion | ||
| 963 | |a VARI | ||
| 999 | |c 64102 | ||