Mixed-Valent Diruthenium Long-Chain Carboxylates. 2. Magnetic Properties
The magnetic properties of several mixed-valent diruthenium long-chain carboxylates of general formula Ru2(RCO2)4X (X = Cl, DOS, or RCO2, DOS = dodecyl sulfate, and RCO2 = linear aliphatic carboxylate or dialkoxy- or trialkoxybenzoate) were studied in the temperature range 6-400 K. All of the compou...
Guardado en:
| Autor principal: | |
|---|---|
| Otros Autores: | , , |
| Formato: | Capítulo de libro |
| Lenguaje: | Inglés |
| Publicado: |
1998
|
| Acceso en línea: | Registro en Scopus Handle Registro en la Biblioteca Digital |
| Aporte de: | Registro referencial: Solicitar el recurso aquí |
| LEADER | 08695caa a22008657a 4500 | ||
|---|---|---|---|
| 001 | PAPER-2902 | ||
| 003 | AR-BaUEN | ||
| 005 | 20230518203222.0 | ||
| 008 | 190411s1998 xx ||||fo|||| 00| 0 eng|d | ||
| 024 | 7 | |2 scopus |a 2-s2.0-0000347195 | |
| 040 | |a Scopus |b spa |c AR-BaUEN |d AR-BaUEN | ||
| 030 | |a INOCA | ||
| 100 | 1 | |a Cukiernik, F.D. | |
| 245 | 1 | 0 | |a Mixed-Valent Diruthenium Long-Chain Carboxylates. 2. Magnetic Properties |
| 260 | |c 1998 | ||
| 270 | 1 | 0 | |m Cukiernik, F.D.; Depto. de Quim. Inorgánica, Fac. de Ciencias Exactas y Naturales, Universidad de Buenos Aires, Nuñez (1428) Capital Federal, Argentina |
| 506 | |2 openaire |e Política editorial | ||
| 504 | |a Stephenson, T.A., Wilkinson, G.J., (1966) J. Inorg. Nucl. Chem., 8, p. 2285 | ||
| 504 | |a Bennett, M.J., Caulton, K.G., Cotton, F.A., (1969) Inorg. Chem., 8, p. 1 | ||
| 504 | |a Norman, J.G., Renzoni, G.E., Case, D.A., (1979) J. Am. Chem. Soc., 101, p. 5256 | ||
| 504 | |a Cukiernik, F.D., Maldivi, P., Giroud-Godquin, A.M., Marchon, J.C., Ibn-Elhaj, M., Guillon, D., Skoulios, A., (1991) Liq. Cryst., 9, p. 903 | ||
| 504 | |a Cukiernik, F.D., Ibn-Elhaj, M., Chaia, Z.D., Marchon, J.C., Giroud-Godquin, A.M., Guillon, D., Skoulios, A., Maldivi, P., (1998) Chem. Mater., 10, p. 83 | ||
| 504 | |a Mukaida, M., Nomura, T., Ishimori, T., (1972) Bull. Chem. Soc. Jpn., 45, p. 2143 | ||
| 504 | |a Das, B.K., Chakravarty, A.R., (1988) Polyhedron, 7, p. 685 | ||
| 504 | |a Barral, M.C., Jiménez-Aparicio, R., Rial, C., Royer, E., Saucedo, M.J., Urbanos, F.A., (1990) Polyhedron, 9, p. 1723 | ||
| 504 | |a Higgins, P., McCann, M., (1988) J. Chem. Soc., Dalton Trans., p. 661 | ||
| 504 | |a Carvill, A., Higgins, P., McCann, M., Ryan, H., Shiels, A., (1989) J. Chem. Soc., Dalton Trans., p. 2435 | ||
| 504 | |a Telser, J., Drago, R.S., (1984) Inorg. Chem., 23, p. 3114 | ||
| 504 | |a Telser, J., Miskowsky, V.M., Drago, R.S., Wong, N.M., (1985) Inorg. Chem., 24, p. 4765 | ||
| 504 | |a Cukiernik, F.D., Giroud-Godquin, A.M., Maldivi, P., Marchon, J.C., (1994) Inorg. Chim. Acta, 215, p. 203 | ||
| 504 | |a Cotton, F.A., Kim, Y., Ren, T., (1992) Inorg. Chem., 31, p. 2608 | ||
| 504 | |a Cotton, F.A., Kim, Y., Ren, T., (1992) Inorg. Chem., 31, p. 2723 | ||
| 504 | |a note; Cotton, F.A., Kim, Y., Ren, T., (1993) Polyhedron, 12, p. 607 | ||
| 504 | |a Sheldrick, G.M., (1985) Crystallographic Computing, 3, pp. 175-179. , Sheldrick, G. M., Krüger, C, Goddard, R., Eds.; Oxford University Press: England | ||
| 504 | |a Sheldrick, G.M., (1976) SHELX 76: Program for Crystal Structure Determination, , University of Cambridge: England | ||
| 504 | |a Cromer, D.T., Waber, J.T., (1974) International Tables for X-ray Crystallography, 4, pp. 99-101. , Ibers, J. A., Hamilton, W. C., Eds.; Kynoch Press: Birmingham, England, Table 2.2B | ||
| 504 | |a Cromer, D.T., (1974) International Table for X-ray Crystallography, 4, p. 149. , Ibers, J. A., Hamilton. W. C., Eds.; Kynoch Press: Birmingham, England, Table 2.3.1 | ||
| 504 | |a Flack, H.D., (1985) Acta Crystallogr., A41, p. 500 | ||
| 504 | |a Selwood, P.W., (1956) Magnetochemistry, 2nd Ed., p. 78. , Interscience: New York | ||
| 504 | |a Johnson, C.K., (1965), ORTEP, Report ORNL-3794; Oak Ridge National Laboratory: Oak Ridge, TN; Michalowicz, D.A., Michalowicz, A., MACORTEP; Laboratoire de Physicochimie Structurale, Université Paris Val de Marne, UFR de Sciences et Technologies, 94010 Créteil Marne, UFR de Sciences et Technologies, 94010 Créteil; Lindsay, A.J., Wilkinson, G., Motevalli, M., Hursthouse, M.B., (1987) J. Chem. Soc., Dalton Trans., p. 2723 | ||
| 504 | |a Togano, T., Mukaida, M., Nomura, T., (1980) Bull. Chem. Soc. Jpn., 53, p. 2085 | ||
| 504 | |a Bino, A., Cotton, F.A., Felthouse, T.R., (1979) Inorg. Chem., 18, p. 2599 | ||
| 504 | |a Marsh, R.E., Schomaker, V., (1981) Inorg. Chem., 20, p. 299 | ||
| 504 | |a Kimura, T., Sakurai, T., Shima, M., Togano, T., Mukaida, M., Nomura, T., (1982) Bull Chem. Soc. Jpn., 55, p. 3927 | ||
| 504 | |a Miskowsky, V.M., Loher, T.M., Gray, H.B., (1987) Inorg. Chem., 26, p. 1098 | ||
| 504 | |a McCann, G.M., Canvill, A., Guinan, P., Higgins, P., Campbell, J., Ryan, H., Walsh, M., Gallagher, J., (1991) Polyhedron, 10, p. 2273 | ||
| 504 | |a Das, B.K., Chakravarty, A.R., (1991) Polyhedron, 10, p. 491 | ||
| 504 | |a Barrai, M.C., Jiménez-Aparicio, R., Priego, J.L., Royer, E.C., Gutiérrez-Puebla, E., Ruiz Valero, C., (1992) Polyhedron, 11, p. 2209 | ||
| 504 | |a Martin, D.S., Newman, R.A., Vlasnik, L.S., (1980) Inorg. Chem., 26, p. 3404 | ||
| 504 | |a McCann, M., Carvill, A., Cardin, C., Convery, M., (1993) Polyhedron, 12, p. 1163 | ||
| 504 | |a Cotton, F.A., Matusz, M., Zhong, B., (1988) Inorg. Chem., 27, p. 4368 | ||
| 504 | |a Spohn, M., Strähle, J., Hiller, W., (1986) Z. Natursforsch, 41 B, p. 541 | ||
| 504 | |a O'Connor, C.J., (1982) Prog, Inorg. Chem, 29, p. 203 | ||
| 504 | |a note; note; The simulated powder X-ray diffraction patterns were calculated by E. Amalric (ILL-Grenoble) and J. Laugier (CEA-Grenoble); Hay, P.J., Thibeault, J.C., Hoffmann, R., (1975) J. Am. Chem. Soc., 97, p. 4884 | ||
| 504 | |a Kahn, O., Briat, B., (1976) J. Chem. Soc., Faraday Trans. 2, 72, p. 268 | ||
| 504 | |a Kahn, O., (1984) Magneto-Structural Correlations in Exchange Coupled Systems, p. 37. , Willett, R. D., Gatteschi, D., Kahn, O., Eds.; Nato Asi Series; D. Riedel Publishing Co.: Hingham, MA | ||
| 504 | |a Estiu, G., Maldivi, P., Cukiemik, F.D., work in progress; Maldivi, P., Giroud-Godquin, A.M., Marchon, J.C., Guillon, D., Skoulios, A., (1989) Chem. Phys. Lett., 157, p. 552 | ||
| 504 | |a Marchon, J.C., Maldivi, P., Giroud-Godquin, A.M., Guillon, D., Skoulios, A., Strommen, D., (1990) Philos. Trans. R. Soc. London, A330, p. 109 | ||
| 504 | |a Bonnet, L., Cukiernik, F.D., Maldivi, P., Giroud-Godquin, A.M., Marchon, J.C., Ibn-Elhaj, M., Guillon, D., Skoulios, A., (1994) Chem. Mater., 6, p. 31 | ||
| 504 | |a Giroud-Godquin, A.M., Latour, J.M., Marchon, J.C., (1985) Inorg. Chem., 24, p. 4452 | ||
| 504 | |a note; Ramos Moita, M.F., Duarte, M.L.T.S., Fausto, R., (1994) J. Chem. Soc., Faraday Trans., 90, p. 2953 | ||
| 520 | 3 | |a The magnetic properties of several mixed-valent diruthenium long-chain carboxylates of general formula Ru2(RCO2)4X (X = Cl, DOS, or RCO2, DOS = dodecyl sulfate, and RCO2 = linear aliphatic carboxylate or dialkoxy- or trialkoxybenzoate) were studied in the temperature range 6-400 K. All of the compounds exhibit a strong zero-field splitting (D = ca. 75 cm-1), independent of the nature of the axial anion X or of the equatorial substituent R. In the X = RCO2 series an intermolecular antiferromagnetic (AF) interaction zJ = ca. -2 cm-1 was found, whereas in the case of an X = DOS analogue, this interaction is very weak (-0.2 cm-1). The X = Cl series shows three distinct types of interdimer magnetic exchange: very weak, moderate (|zJ| ≈ 2 cm-1), or strong (|zJ| > 10 cm-1). One representative complex in this series, Ru2(C4H9CO2)4Cl, has been structurally characterized by X-ray crystallography. Crystal data: tetragonal system, space group I42d, a = 14.137(3) Å, c = 26.246(5) Å, and Z = 8. Examination of the structures and magnetic behaviors suggests that the AF exchange in this series correlates with the Ru-Cl-Ru intermolecular angle; a qualitative explanation in terms of overlap of magnetic orbitals is proposed. Magnetic susceptibility measurements in the columnar mesophase of the mesomorphic congeners indicate that no significant structural change occurs at the crystal-liquid crystal transition. |l eng | |
| 593 | |a Dept. Rech. Fond. Sur Matiere Cond., Lab. de Chimie de Coordination, CEA-Grenoble, 17 Rue des Martyrs, 38054 Grenoble Cedex 9, France | ||
| 593 | |a Depto. de Quim. Inorgánica, Fac. de Ciencias Exactas y Naturales, Universidad de Buenos Aires, Nuñez (1428) Capital Federal, Argentina | ||
| 700 | 1 | |a Luneau, D. | |
| 700 | 1 | |a Marchon, J.-C. | |
| 700 | 1 | |a Maldivi, P. | |
| 773 | 0 | |d 1998 |g v. 37 |h pp. 3698-3704 |k n. 15 |p Inorg. Chem. |x 00201669 |w (AR-BaUEN)CENRE-60 |t Inorganic Chemistry | |
| 856 | 4 | 1 | |u https://www.scopus.com/inward/record.uri?eid=2-s2.0-0000347195&partnerID=40&md5=d99d8561dd5801b390c6fa9991c4a121 |y Registro en Scopus |
| 856 | 4 | 0 | |u https://hdl.handle.net/20.500.12110/paper_00201669_v37_n15_p3698_Cukiernik |y Handle |
| 856 | 4 | 0 | |u https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_00201669_v37_n15_p3698_Cukiernik |y Registro en la Biblioteca Digital |
| 961 | |a paper_00201669_v37_n15_p3698_Cukiernik |b paper |c PE | ||
| 962 | |a info:eu-repo/semantics/article |a info:ar-repo/semantics/artículo |b info:eu-repo/semantics/publishedVersion | ||
| 963 | |a VARI | ||
| 999 | |c 63855 | ||