Functional surfaces through the creation of adhesion and charged patterns on azopolymer surface relief gratings

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We show that an azopolymer can be used to create a supramolecular architecture in a parallel process with patterned surface properties. By illuminating with an interference pattern, we created adhesion and charge patterns that reflect the molecular ordering. We studied the recording process in two l...

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Autor principal: Capeluto, María Gabriela
Otros Autores: Falcione, Rebeca, Salvador, R.F, Eceiza, A., Goyanes, S., Ledesma, S.A
Formato: Capítulo de libro
Lenguaje:Inglés
Publicado: Elsevier B.V. 2019
Materias:
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Acceso en línea:Registro en Scopus
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100 1 |a Capeluto, María Gabriela 
245 1 0 |a Functional surfaces through the creation of adhesion and charged patterns on azopolymer surface relief gratings 
260 |b Elsevier B.V.  |c 2019 
270 1 0 |m Capeluto, M.G.; Laboratorio de Procesado de Imágenes (LPI), Departamento de Física, Facultad de Ciencias Exactas y Naturales, Universidad de Buenos Aires and IFIBA, CONICET, Cuidad UniversitariaArgentina; email: maga@df.uba.ar 
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506 |2 openaire  |e Política editorial 
520 3 |a We show that an azopolymer can be used to create a supramolecular architecture in a parallel process with patterned surface properties. By illuminating with an interference pattern, we created adhesion and charge patterns that reflect the molecular ordering. We studied the recording process in two limit situations. When birefringence dominates over mass transport, an adhesion pattern was recorded even in absence of a surface relief grating (SRG). When mass transport dominates, we measured a higher frequency adhesion and relief patterns on top of the SRG. We measured an increased negative charge in the regions where molecules are expected to be parallel aligned in trans conformational state. © 2019 Elsevier B.V.  |l eng 
536 |a Detalles de la financiación: Universidad de Buenos Aires, UBACYT 20020170100564BA, 20020170100381BA 
536 |a Detalles de la financiación: IT-776-13 
536 |a Detalles de la financiación: Euskal Herriko Unibertsitatea 
536 |a Detalles de la financiación: Agencia Nacional de Promoción Científica y Tecnológica, PICT 2017-2362, PICT 2014-2432, PICT-2014-3537 
536 |a Detalles de la financiación: The authors would like to thank the financial support from the University of Buenos Aires (UBACYT 20020170100564BA and 20020170100381BA ), ANPCyT ( PICT 2017-2362 , PICT-2014-3537 , PICT 2014-2432 ) and the Basque Government ( IT-776-13 ). The authors would also like to thank the technical support from “Macrobehaviour-Mesostructure-Nanotechnology” SGIker unit from the University of the Basque Country (Spain), and the Quantum Electronics Lab (UBA, Argentina) for lending the instrumental r e. Appendix A 
593 |a Laboratorio de Procesado de Imágenes (LPI), Departamento de Física, Facultad de Ciencias Exactas y Naturales, Universidad de Buenos Aires and IFIBA, CONICET, Cuidad Universitaria, Buenos Aires, 1428, Argentina 
593 |a Laboratorio de Polímeros y Materiales Compuestos (LPM&C), Departamento de Física, Facultad de Ciencias Exactas y Naturales, Universidad de Buenos Aires and IFIBA, CONICET, Cuidad Universitaria, Buenos Aires, 1428, Argentina 
593 |a Grupo “Materiales + Tecnologías”, Departamento de Ingeniería Química y Del Medio Ambiente, Escuela de Ingeniería de Gipuzkoa, Universidad Del País Vasco, Pza. Europa 1, Donostia-San Sebastián, 20018, Spain 
650 1 7 |2 spines  |a ADHESION 
650 1 7 |2 spines  |a ADHESION 
690 1 0 |a AZOPOLYMER 
690 1 0 |a FUNCTIONAL SURFACES 
690 1 0 |a SURFACE RELIEF GRATINGS 
690 1 0 |a ELECTRICAL ENGINEERING 
690 1 0 |a MAGNETIC MATERIALS 
690 1 0 |a AZOPOLYMER 
690 1 0 |a CONFORMATIONAL STATE 
690 1 0 |a FUNCTIONAL SURFACES 
690 1 0 |a HIGHER FREQUENCIES 
690 1 0 |a INTERFERENCE PATTERNS 
690 1 0 |a MOLECULAR ORDERING 
690 1 0 |a SUPRAMOLECULAR ARCHITECTURES 
690 1 0 |a SURFACE RELIEF GRATINGS 
700 1 |a Falcione, Rebeca 
700 1 |a Salvador, R.F. 
700 1 |a Eceiza, A. 
700 1 |a Goyanes, S. 
700 1 |a Ledesma, S.A. 
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