Photophysics of Xanthene Dyes at High Concentrations in Solid Environments: Charge Transfer Assisted Triplet Formation
The photophysical behavior of two xanthene dyes, Eosin Y and Phloxine B, included in microcrystalline cellulose particles is studied in a wide concentration range, with emphasis on the effect of dye concentration on fluorescence and triplet quantum yields. Absolute fluorescence quantum yields in the...
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Blackwell Publishing Inc.
2018
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| LEADER | 16744caa a22011417a 4500 | ||
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| 001 | PAPER-25091 | ||
| 003 | AR-BaUEN | ||
| 005 | 20241101092114.0 | ||
| 008 | 190410s2018 xx ||||fo|||| 00| 0 eng|d | ||
| 024 | 7 | |2 scopus |a 2-s2.0-85052431171 | |
| 030 | |a PHCBA | ||
| 040 | |a Scopus |b spa |c AR-BaUEN |d AR-BaUEN | ||
| 100 | 1 | |a Litman, Y.E. | |
| 245 | 1 | 0 | |a Photophysics of Xanthene Dyes at High Concentrations in Solid Environments: Charge Transfer Assisted Triplet Formation |
| 260 | |b Blackwell Publishing Inc. |c 2018 | ||
| 270 | 1 | 0 | |m San Román, E.; Departamento de Química Inorgánica, Analítica y Química Física, Facultad de Ciencias Exactas y Naturales, Universidad de Buenos AiresArgentina; email: esr@qi.fcen.uba.ar |
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| 506 | |2 openaire |e Política editorial | ||
| 520 | 3 | |a The photophysical behavior of two xanthene dyes, Eosin Y and Phloxine B, included in microcrystalline cellulose particles is studied in a wide concentration range, with emphasis on the effect of dye concentration on fluorescence and triplet quantum yields. Absolute fluorescence quantum yields in the solid-state were determined by means of diffuse reflectance and steady-state fluorescence measurements, whereas absolute triplet quantum yields were obtained by laser-induced optoacoustic spectroscopy and their dependence on dye concentration was confirmed by diffuse reflectance laser flash photolysis and time-resolved phosphorescence measurements. When both quantum yields are corrected for reabsorption and reemission of radiation, ΦF values decrease strongly on increasing dye concentration, while a less pronounced decay is observed for ΦT. Fluorescence concentration quenching is attributed to the formation of dye aggregates or virtual traps resulting from molecular crowding. Dimeric traps are however able to generate triplet states. A mechanism based on the intermediacy of charge-transfer states is proposed and discussed. Calculation of parameters for photoinduced electron transfer between dye molecules within the traps evidences the feasibility of the proposed mechanism. Results demonstrate that photoactive energy traps, capable of yielding dye triplet states, can be formed even in highly-concentrated systems with random dye distributions. © 2018 The American Society of Photobiology |l eng | |
| 536 | |a Detalles de la financiación: Universidad Nacional de La Plata | ||
| 536 | |a Detalles de la financiación: Universidad de Buenos Aires | ||
| 536 | |a Detalles de la financiación: Universidad Nacional de La Plata | ||
| 536 | |a Detalles de la financiación: Facultad de Ciencias Físicas y Matemáticas | ||
| 536 | |a Detalles de la financiación: Consejo Nacional de Investigaciones Científicas y Técnicas | ||
| 536 | |a Detalles de la financiación: Universidad de Buenos Aires | ||
| 536 | |a Detalles de la financiación: Agencia Nacional de Promoción Científica y Tecnológica | ||
| 536 | |a Detalles de la financiación: National Council for Scientific Research | ||
| 536 | |a Detalles de la financiación: Consejo Nacional de Rectores | ||
| 536 | |a Detalles de la financiación: Consejo Nacional de Investigaciones Científicas y Técnicas | ||
| 536 | |a Detalles de la financiación: 1Departamento de Qúımica Inorgánica, Analítica y Qúımica Física, Facultad de Ciencias Exactas y Naturales, Universidad de Buenos Aires, Buenos Aires, Argentina 2Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas (INIFTA), CCT-La Plata-CONICET, Universidad Nacional de La Plata (UNLP), La Plata, Argentina 3Instituto de Química Física de los Materiales, Medio Ambiente y Energía (INQUIMAE), CONICET - Universidad de Buenos Aires, Buenos Aires, Argentina 4Max Planck Institute for Chemical Energy Conversion, Mu€lheim an der Ruhr, Germany | ||
| 536 | |a Detalles de la financiación: Acknowledgements—This work has been supported by the University of Buenos Aires, the National Research Council of Argentina (CONICET) and the Agencia Nacional de Promoción Científica y Tecnológica (ANPCyT). H. B. R. and E. S. R. are members of CONICET. Y. L. held a fellowship from the Consejo Interuniversitario Nacional (CIN). | ||
| 593 | |a Departamento de Química Inorgánica, Analítica y Química Física, Facultad de Ciencias Exactas y Naturales, Universidad de Buenos Aires, Buenos Aires, Argentina | ||
| 593 | |a Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas (INIFTA), CCT-La Plata-CONICET, Universidad Nacional de La Plata (UNLP), La Plata, Argentina | ||
| 593 | |a Instituto de Química Física de los Materiales, Medio Ambiente y Energía (INQUIMAE), CONICET - Universidad de Buenos Aires, Buenos Aires, Argentina | ||
| 593 | |a Max Planck Institute for Chemical Energy Conversion, Mülheim an der Ruhr, Germany | ||
| 593 | |a Fritz Haber Institute of the Max Planck Society, Berlin, Germany | ||
| 700 | 1 | |a Rodríguez, H.B. | |
| 700 | 1 | |a Braslavsky, Silvia Elsa | |
| 700 | 1 | |a San Román, E. | |
| 773 | 0 | |d Blackwell Publishing Inc., 2018 |g v. 94 |h pp. 865-874 |k n. 5 |p Photochem. Photobiol. |x 00318655 |w (AR-BaUEN)CENRE-43 |t Photochemistry and Photobiology | |
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