Influence of the crosslinking content on the structural properties of polybutadiene rubbers with different isomeric composition

In the present work first results on structural properties of three commercial isomers of polybutadiene rubber are presented. To this aim, rheometry, PALS, DSC and swelling techniques were used. Different samples were prepared containing diverse amounts of dycumil peroxide as crosslinking agent and...

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Autor principal: Rodríguez Garraza, Ana Lucía
Otros Autores: Mansilla, Marcela Angela, Carlos, M., Silvina, C., Ángel, M., Alberto, S., He C.Q, Wu Y.C, Qi N., Chen Z.Q
Formato: Acta de conferencia Capítulo de libro
Lenguaje:Inglés
Publicado: Trans Tech Publications Ltd 2016
Acceso en línea:Registro en Scopus
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100 1 |a Rodríguez Garraza, Ana Lucía 
245 1 0 |a Influence of the crosslinking content on the structural properties of polybutadiene rubbers with different isomeric composition 
260 |b Trans Tech Publications Ltd  |c 2016 
270 1 0 |m Marcela, M.; IFIMAT y CIFICEN (CONICET-UNCPBA-CICPBA), Pinto 399, Argentina; email: mmansilla@df.uba.ar 
504 |a Mark, J.E., (2007) Properties of Polymer Handbook, , Springer, New York 
504 |a Mansilla, M.A., Marzocca, A., Analysis of network structure formed in styrene-butadiene rubber cured with sulfur/TBBS system (2007) J. Appl. Polym. Sci., 103, pp. 1105-1112 
504 |a Dluzneski, P.R., Peroxide vulcanization of elastomers (2001) Rubber Chem. Technol., 74, pp. 451-492 
504 |a Loan, D., Crosslinking efficiencies of dicumyl peroxide in unsaturated synthetic rubbers (1963) J. Appl. Polym. Sci., 7, pp. 2259-2268 
504 |a Rodríguez Garraza, A.L., (2015) Estudio de la Microestructura y su Influencia en Propiedades Físicas del Caucho Polibutadieno y Caucho Poliisopreno Reticulado Con Peroxido, , http://digital.bl.fcen.uba.ar/Download/Tesis/Tesis_5796_RodriguezGarraza.pdf, PhD Thesis, University of Buenos Aires, Argentina 
504 |a Mansilla, M.A., Marzocca, A.J., Macchi, C., Somoza, A., Influence of vulcanization temperature on the cure kinetics and on the microstructural properties in Natural Rubber/Styrene-Butadiene Rubber blends prepared by solution mixing (2015) Eur. Polym. J., 69, pp. 50-61 
504 |a Mansilla, M.A., Rodriguez Garraza, A.L., Silva, L., Salgueiro, W., Macchi, C., Marzocca, A.J., Somoza, A., Evolution of the free volume and glass transition temperature with the degree of cure of polybutadiene rubbers (2013) Polym. Test., 32, pp. 686-690 
504 |a Marzocca, A.J., Salgueiro, W., Somoza, A., Physical phenomena related to free volumes in rubber and blends (2013) Advances in Elastomer II, pp. 399-426. , A, P. M. Visakh, S. Thomas, A. K. Chandra AK, A. P Mathew Eds., Springer, Verlag Berlin Heidelberg 
504 |a Rodriguez Garraza, A.L., Sorichetti, P., Marzocca, A.J., Matteo, C.L., Monti, G.A., Influence of the microstructure of vulcanized polybutadiene rubber on the dielectric properties (2011) Polym. Test., 30, pp. 657-662 
504 |a Marzocca, A.J., Rodríguez Garraza, A.L., Sorichetti, P., Mosca, H.O., Cure kinetics and swelling behaviour in polybutadiene rubber (2010) Polym. Test., 29, pp. 477-482 
504 |a Marzocca, A.J., Rodriguez Garraza, A.L., Mansilla, M.A., Evaluation of the polymer-solvent interaction parameter χ for the system cured polybutadiene rubber and toluene (2010) Polym. Test., 29, pp. 119-126 
504 |a Kansy, J., Microcomputer program for analysis of positron annihilation lifetime spectra (1996) Nucl. Instrum. Meth. A, 374, pp. 235-244 
504 |a Tao, S.J., Positronium annihilation in molecular substances (1972) J. Chem. Phys., 56, pp. 5499-5510 
504 |a Eldrup, M., Lightbody, D., Sherwood, N.J., The temperature dependence of positron lifetimes in solid pivalic acid (1981) Chem. Phys., 63, pp. 51-58 
504 |a Jasinska, B., Koziol, A.E., Goworek, T., Ortho-positronium lifetimes in nonspherical voids (1996) J. Radioanal. Nucl. Ch., 210, pp. 617-623 
504 |a Nakanishi, H., Wang, S.J., Jean, Y.C., (1988) Positron Annihilation Studies of Fluids, p. 292. , S. C. Sharma Ed., World Scientific, SingaporeA4 - Clover Technology Group, Inc. (NuClover); ESo Express, LLC; National Natural Science Foundation of China (NSFC); Science and Technology Department of Hubei Province; Wuhan University 
506 |2 openaire  |e Política editorial 
520 3 |a In the present work first results on structural properties of three commercial isomers of polybutadiene rubber are presented. To this aim, rheometry, PALS, DSC and swelling techniques were used. Different samples were prepared containing diverse amounts of dycumil peroxide as crosslinking agent and vulcanized at 433 K.A correlation among the experimental results obtained using different techniques is also discussed. © 2016 Trans Tech Publications, Switzerland.  |l eng 
593 |a Laboratorio de Polímeros y Materiales Compuestos, Departamento de Física, Universidad de Buenos Aires, Ciudad Universitaria, Buenos Aires, C1428EHA, Argentina 
593 |a IFIMAT y CIFICEN (CONICET-UNCPBA-CICPBA), Pinto 399, Tandil, B7000GHG, Argentina 
593 |a Centro de Física de Materiales (CSIC-UPV/EHU), Paseo Manuel Lardizábal 5, San-Sebastián, 20018, Spain 
593 |a Donostia International Physics Center, Paseo Manuel Lardizábal 4, San-Sebastián, 20018, Spain 
690 1 0 |a PALS 
690 1 0 |a POLYBUTADIENE RUBBER 
690 1 0 |a SWELLING 
690 1 0 |a VULCANIZATION 
690 1 0 |a ISOMERS 
690 1 0 |a POLYBUTADIENES 
690 1 0 |a RUBBER 
690 1 0 |a SWELLING 
690 1 0 |a VULCANIZATION 
690 1 0 |a CROSS LINKING AGENTS 
690 1 0 |a ISOMERIC COMPOSITIONS 
690 1 0 |a PALS 
690 1 0 |a POLYBUTADIENE RUBBERS 
690 1 0 |a RHEOMETRY 
690 1 0 |a STRUCTURAL PROPERTIES 
700 1 |a Mansilla, Marcela Angela 
700 1 |a Carlos, M. 
700 1 |a Silvina, C. 
700 1 |a Ángel, M. 
700 1 |a Alberto, S. 
700 1 |a He C.Q. 
700 1 |a Wu Y.C. 
700 1 |a Qi N. 
700 1 |a Chen Z.Q. 
711 2 |d 20 September 2016 through 25 September 2016 
773 0 |d Trans Tech Publications Ltd, 2016  |g v. 373 DDF  |h pp. 269-273  |p Defect Diffus. Forum  |n Defect and Diffusion Forum  |x 10120386  |z 9783038356059  |t 17th International Conference onPositron Annihilation, ICPA-17 
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