Thermotropic mesomorphism of mixed-valent diruthenium aliphatic carboxylates with axial anion bearing two aliphatic chains

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A homologous series of binuclear mixed-valent diruthenium tetracarboxylates, Ru2(O2C(CH2)n-2CH3)4DHDP (DHDP = di(hexadecyl)phosphate axial anion, n = 10, 12, 14, 16, and 18), have been synthesized and characterized, and the liquid crystalline properties of these compounds were examined. All the comp...

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Detalles Bibliográficos
Autor principal: Bottazzi, T.
Otros Autores: Cecchi, F., Zelcer, A., Heinrich, B., Donnio, B., Guillon, D., Cukiernik, F.D
Formato: Capítulo de libro
Lenguaje:Inglés
Publicado: 2013
Acceso en línea:Registro en Scopus
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Biblioteca Central Dr. Luis F. Leloir (FCEN) de Universidad de Buenos Aires
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100 1 |a Bottazzi, T. 
245 1 0 |a Thermotropic mesomorphism of mixed-valent diruthenium aliphatic carboxylates with axial anion bearing two aliphatic chains 
260 |c 2013 
270 1 0 |m Cukiernik, F.D.; Instituto de Ciencias, Universidad Nacional de General Sarmiento, Los Polvorines, Argentina; email: fabioc@qi.fcen.uba.ar 
506 |2 openaire  |e Política editorial 
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520 3 |a A homologous series of binuclear mixed-valent diruthenium tetracarboxylates, Ru2(O2C(CH2)n-2CH3)4DHDP (DHDP = di(hexadecyl)phosphate axial anion, n = 10, 12, 14, 16, and 18), have been synthesized and characterized, and the liquid crystalline properties of these compounds were examined. All the compounds exhibit a room-temperature crystalline lamellar phase and a high temperature (above 140°) Colh mesophase. Another, probably semi-crystalline, lamellar intermediate phase has also been found for all the studied compounds but for the n = 18 derivative. Comparison with related mesogenic homologous series where the equatorial ligands are also linear carboxylates, but the axial anions bear just one aliphatic chain (carboxylates, octylsulfonate, and dodecylsulfate), shows that the presence of a second aliphatic chain in the axial anion both lowers the transition temperatures and modifies the nature of the intermediate lamellar phase. Structural models at the molecular level are suggested for the crystalline lamellar and the Colh phases. © 2013 Taylor & Francis.  |l eng 
536 |a Detalles de la financiación: Secretaría de Ciencia y Técnica, Universidad de Buenos Aires, X219, X057 
536 |a Detalles de la financiación: Agencia Nacional de Promoción Científica y Tecnológica, PICT25409 
536 |a Detalles de la financiación: Consejo Nacional de Investigaciones Científicas y Técnicas 
536 |a Detalles de la financiación: We thank Martin Gaitan for his help to TB during the synthesis of most of the reported compounds. Financial support from UBACyT (X219 and X057) and ANPCyT (PICT25409) is acknowledged. TB thanks UNGS for a research fellowship, FC thanks CONICET for a PhD research fellowship. FDC and AZ are members of the research staff of Conicet. BD, BH, and DG thank CNRS and Université de Strasbourg for their support. 
593 |a Instituto de Ciencias, Universidad Nacional de General Sarmiento, Los Polvorines, Argentina 
593 |a INQUIMAE, Departamento de Química Inorgánica, Universidad de Buenos Aires, Ciudad Universitaria, Buenos Aires, Argentina 
593 |a Institut de Physique et Chimie des Matériaux de Strasbourg (IPCMS), Université de Strasbourg - CNRS, Strasbourg, France 
593 |a Gerencia Química, Centro Atómico Constituyentes, Comisión Nacional de Energía Atómica, Buenos Aires, Argentina 
690 1 0 |a COLUMNAR MESOPHASES 
690 1 0 |a COORDINATION POLYMERS 
690 1 0 |a DI(HEXADECYL)PHOSPHATE 
690 1 0 |a METALLOMESOGENS 
690 1 0 |a RUTHENIUM CARBOXYLATES 
700 1 |a Cecchi, F. 
700 1 |a Zelcer, A. 
700 1 |a Heinrich, B. 
700 1 |a Donnio, B. 
700 1 |a Guillon, D. 
700 1 |a Cukiernik, F.D. 
773 0 |d 2013  |g v. 66  |h pp. 3380-3390  |k n. 19  |p J. Coord. Chem.  |x 00958972  |w (AR-BaUEN)CENRE-5510  |t Journal of Coordination Chemistry 
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