Simulation of CO preferential oxidation (COPrOx) monolithic reactors
In this work, a COPrOx monolithic reactor with a CuO/CeO 2/Al2O3 catalytic washcoat was modelled to purify a H2 stream for a 2 kW PEM fuel cell. Preliminary simulations included isothermal monoliths operating between 423 and 463 K, and the optimization of linear axial temperature profiles. For a fix...
Guardado en:
| Autor principal: | |
|---|---|
| Otros Autores: | , , , |
| Formato: | Capítulo de libro |
| Lenguaje: | Inglés |
| Publicado: |
2014
|
| Acceso en línea: | Registro en Scopus DOI Handle Registro en la Biblioteca Digital |
| Aporte de: | Registro referencial: Solicitar el recurso aquí |
| LEADER | 10071caa a22009137a 4500 | ||
|---|---|---|---|
| 001 | PAPER-23967 | ||
| 003 | AR-BaUEN | ||
| 005 | 20240927143228.0 | ||
| 008 | 190411s2014 xx ||||fo|||| 00| 0 eng|d | ||
| 024 | 7 | |2 scopus |a 2-s2.0-84894533472 | |
| 040 | |a Scopus |b spa |c AR-BaUEN |d AR-BaUEN | ||
| 100 | 1 | |a Jeifetz, L.G. | |
| 245 | 1 | 0 | |a Simulation of CO preferential oxidation (COPrOx) monolithic reactors |
| 260 | |c 2014 | ||
| 270 | 1 | 0 | |m Jeifetz, L.G.; Department of Chemical Engineering, Laboratorio de Procesos Catalíticos, Universidad de Buenos Aires, Buenos Aires 1428, Argentina; email: lejeifetz@gmail.com |
| 504 | |a Giunta, P., Amadeo, N., Laborde, M., Simulation of a low temperature water gas shift reactor using the heterogeneous model Application to a PEM fuel cell (2006) J Power Sources, 156, pp. 489-496 | ||
| 504 | |a Ayastuy, J., Gil-Rodriguez, A., Gonzalez-Marcos, M., Gutierrez-Ortiz, M., Effect of process variables on Pt/CeO2 catalyst behaviour for the PROX reaction (2006) Int J Hyd Energy, 31, pp. 2231-2242 | ||
| 504 | |a Sirijaruphan, A., Goodwin, J., Rice, R., Effect of temperature and pressure on the surface kinetic parameters of Pt/γ-Al2O3 during selective CO oxidation (2004) J Catal, 227, pp. 547-551 | ||
| 504 | |a Lopez, E., Kolios, G., Eigenberger, G., Preferential oxidation of CO in a folded-plate reactor (2007) Chem Eng Sci, 62, pp. 5598-5601 | ||
| 504 | |a Echigo, M., Shinke, N., Takami, S., Higashiguchi, S., Hirai, K., Tabata, T., Developmentof residentialPEFCcogenerationsystems:Rucatalyst for CO preferential oxidation in reformed gas (2003) Catal Today, 84, pp. 209-215 | ||
| 504 | |a Moreno, M., Baronetti, G., Laborde, M., Mariño, F., Kinetics of preferential CO oxidation in H2 excess (COPrOx) over CuO/CeO2 catalysts (2008) Int J Hyd Energy, 33, pp. 3538-3542 | ||
| 504 | |a Sedmak, G., Hocevar, S., Levec, J., Kinetics of selective CO oxidation in excess of H2 over the nanostructured Cu0.1Ce0.9O2 y catalyst (2003) J Catal, 213, pp. 135-150 | ||
| 504 | |a Lee, H., Kim, D., Kinetics of CO and H2 oxidation over CuO-CeO2 catalyst in H2 mixtures with CO2 and H2O (2008) Catal Today, 132, pp. 109-116 | ||
| 504 | |a Giunta, P., Moreno, M., Mariño, F., Amadeo, N., Laborde, M., COPrOx fixed bed reactor. Temperature control schemes (2012) Chem Eng Technol, 35, pp. 1055-1063 | ||
| 504 | |a Ávila, P., Montes, M., Miró, E., Monolithic reactors for environmental applications A review on preparation technologies (2005) Chem Eng J, 109, pp. 11-36 | ||
| 504 | |a Cybulski, A., Moulijn, J.A., (1998) The present and the future of structured catalysis-An overview, pp. 1-14. , Cybulski A,Moulijn JA, editors. Structured catalysts and reactors. New York: Marcel Dekker | ||
| 504 | |a Groppi, G., Tronconi, E., Honeycomb supports with high thermal conductivity for gas/solid chemical processes (2005) Catal Today, 105, pp. 297-304 | ||
| 504 | |a Heck, R.M., Gulati, S., Farrauto, R.J., The application of monoliths for gas phase catalytic reactions (2001) Chem Eng J, 82, pp. 149-156 | ||
| 504 | |a Tomašic, V., Jović, F., State-of-The-Art in the monolithic catalysts/ reactors (2006) Appl Catal A Gen, 311, pp. 112-121 | ||
| 504 | |a Korotkikh, O., Farrauto, R., Selective catalytic oxidation of CO in H2: Fuel cell applications (2000) Catal Today, 62, pp. 249-254 | ||
| 504 | |a Gómez, L.E., Tiscornia, I.S., Boix, A.V., Miró, E.E., Co/ZrO2 catalysts coated on cordierite monoliths for CO preferential oxidation (2011) Appl Catal A Gen, 401, pp. 124-133 | ||
| 504 | |a Roberts, G.W., Chin, P., Sun, X., Spivey, J.J., Preferential oxidation of carbon monoxide with Pt/Fe monolithic catalysts: Interactions between external transport and the reverse water-gas-shift reaction (2003) Appl Catal B Environ, 46, pp. 601-611 | ||
| 504 | |a Zhou, S., Yuan, Z., Wang, S., Selective CO oxidation with real methanol reformate over monolithic Pt group catalysts: PEMFC applications (2006) Int J Hyd Energy, 31, pp. 924-933 | ||
| 504 | |a Ahluwalia, R.K., Zhang, Q., Chmielewski, D.J., Lauzze, K.C., Inbody, M.A., Performance of CO preferential oxidation reactor with noble-metal catalyst coated on ceramic monolith for on-board fuel processing applications (2005) Catal Today, 99, pp. 271-283 | ||
| 504 | |a Zeng, S.H., Liu, Y., Nd-or Zr-modified CuO-CeO2/Al2O3/FeCrAl monolithic catalysts for preferential oxidation of carbonmonoxide in hydrogen-rich gases (2008) Appl Surf Sci, 254, pp. 4879-4885 | ||
| 504 | |a Bissett, E.J., Oh, S.H., PrOx reactor model for fuel cell feedstream processing (2005) Chem Eng Sci, 60, pp. 4722-4735 | ||
| 504 | |a Depcik, C., Srinivasan, A., One+One-dimensional modeling of monolithic catalytic converters (1949) Chem Eng Technol, 2011, p. 34 | ||
| 504 | |a Tronconi, E., Groppi, G., Boger, T., Heibel, A., Monolithic catalysts with "high conductivity honeycomb supports for gas/solid exothermic reactions: Characterization of the heat-Transfer properties (2004) Chem Eng Sci, 59, pp. 4941-4949 | ||
| 504 | |a Arzamendi, G., Uriz, I., Diéguez, P.M., Laguna, O.H., Hernández, W.Y., Álvarez, A., Selective CO removal over Au/CeFe and CeCu catalysts in microreactors studied through kinetic analysis and CFD simulations (2011) Chem Eng J, 167, pp. 588-596 | ||
| 504 | |a Gonzo, E., Hydrogen from methanol-steam reforming. Isothermal and adiabatic monolith reactors' simulation (2008) Int J Hyd Energy, 33, pp. 3511-3516 | ||
| 504 | |a Groppi, G., Tronconi, E., Design of novel monolith catalyst supports for gas/solid reactions with heat exchange (2000) Chem Eng Sci, 55, pp. 2161-2171 | ||
| 504 | |a Chen, J., Yang, H., Wang, N., Ring, Z., Dabros, T., Mathematical modelling of monolith catalysts and reactors for gas phase reactions (2008) Appl Catal A Gen, 345, pp. 1-11 | ||
| 504 | |a Valentini, M., Groppi, G., Cristiani, C., Levi, M., Tronconi, E., Forzatti, P., The deposition of γ-Al2O3 layers on ceramic and metallic supports for the preparation of structured catalysts (2001) Catal Today, 69, pp. 307-314 | ||
| 504 | |a Graschinsky, C., Ubogui, J., Sarto, A., Tejeda, R., Laborde, M., Francesconi, J., (2010) Hydrogen production from bioethanol: Pilot plant scale, , In VI Chemical Engineering Argentinean Conference, Mar del Plata, Argentina | ||
| 504 | |a Mariño, F., Descorme, C., Duprez, D., Supported base metal catalysts for the preferential oxidation of carbon monoxide in the presence of excess hydrogen (PROX) (2005) Appl Catal B Environ, 58, pp. 175-183 | ||
| 504 | |a Moreno, M., (2011) Hydrogen Catalytic Purification., , PhD thesis, Engineering School, University of Buenos Aires | ||
| 504 | |a Semeniuk, H.M., (2011) CuO/CeO2/Al2O3 catalysts for the preferential oxidation of CO (COPrOx), , Eng. thesis, Engineering School, University of Buenos Aires | ||
| 504 | |a Elnashaie, S.S., Elshishini, S.S., Modelling, simulation and optimization of industrial fixed bed catalytic reactors (1993) Amsterdam: Gordon and Breach Science Publishers | ||
| 504 | |a Poulier, C., Smith, D.S., Absi, J., Thermal conductivity of pressed powder compacts: Tin oxide and alumina (2007) J Eur Ceram Soc, 27, pp. 475-478 | ||
| 504 | |a Papadias, D., Edsberg, L., Björnbom, P., Simplified method for effectiveness factor calculations in irregular geometries of washcoats (2000) Chem Eng Sci, 55, pp. 1447-1459 | ||
| 504 | |a Jeifetz, L.G., Monolithic reactors modelling for its application to the preferential CO oxidation reaction (COPrOx), 2012. , Eng. thesis, Engineering School, University of Buenos Aires | ||
| 506 | |2 openaire |e Política editorial | ||
| 520 | 3 | |a In this work, a COPrOx monolithic reactor with a CuO/CeO 2/Al2O3 catalytic washcoat was modelled to purify a H2 stream for a 2 kW PEM fuel cell. Preliminary simulations included isothermal monoliths operating between 423 and 463 K, and the optimization of linear axial temperature profiles. For a fixed total system size and a desired CO outlet molar fraction lower than 20 ppm, an isothermal temperature profile maximized the global selectivity towards CO oxidation. Then, different schemes of adiabatic monoliths with interstage cooling were modelled and evaluated. It was found that wide operating temperature ranges lower the necessary number of stages, but decrease the global selectivity and rise system sensitivity to inlet temperatures. A 1D heterogeneous model was used to simulate the monoliths. © 2014 by Walter de Gruyter Berlin / Boston 2014. |l eng | |
| 536 | |a Detalles de la financiación: Agencia Nacional de Promoción Científica y Tecnológica | ||
| 536 | |a Detalles de la financiación: Acknowledgements: To ANPCYT, CONICET and University of Buenos Aires for the financial support. | ||
| 593 | |a Department of Chemical Engineering, Laboratorio de Procesos Catalíticos, Universidad de Buenos Aires, Buenos Aires 1428, Argentina | ||
| 690 | 1 | 0 | |a COPROX |
| 690 | 1 | 0 | |a HEAT EXCHANGE |
| 690 | 1 | 0 | |a MODELLING |
| 690 | 1 | 0 | |a MONOLITHIC REACTOR |
| 690 | 1 | 0 | |a PEM FUEL CELL |
| 690 | 1 | 0 | |a CO PREFERENTIAL OXIDATION |
| 690 | 1 | 0 | |a CO-PROX |
| 690 | 1 | 0 | |a HEAT EXCHANGE |
| 690 | 1 | 0 | |a MONOLITHIC REACTOR |
| 690 | 1 | 0 | |a PEM FUEL CELL |
| 690 | 1 | 0 | |a MODELS |
| 700 | 1 | |a Giunta, P.D. | |
| 700 | 1 | |a Mariño, F.J. | |
| 700 | 1 | |a Amadeo, Nora Elvira | |
| 700 | 1 | |a Laborde, M.A. | |
| 773 | 0 | |d 2014 |g v. 12 |k n. 1 |p Int. J. Chem. Reactor Eng. |x 15426580 |t International Journal of Chemical Reactor Engineering | |
| 856 | 4 | 1 | |u https://www.scopus.com/inward/record.uri?eid=2-s2.0-84894533472&doi=10.1515%2fijcre-2013-0071&partnerID=40&md5=37fb5deae0e8f78ccfa0536603f93614 |y Registro en Scopus |
| 856 | 4 | 0 | |u https://doi.org/10.1515/ijcre-2013-0071 |y DOI |
| 856 | 4 | 0 | |u https://hdl.handle.net/20.500.12110/paper_15426580_v12_n1_p_Jeifetz |y Handle |
| 856 | 4 | 0 | |u https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_15426580_v12_n1_p_Jeifetz |y Registro en la Biblioteca Digital |
| 961 | |a paper_15426580_v12_n1_p_Jeifetz |b paper |c PE | ||
| 962 | |a info:eu-repo/semantics/article |a info:ar-repo/semantics/artículo |b info:eu-repo/semantics/publishedVersion | ||
| 999 | |c 84920 | ||