Solubility of solids in near-critical fluids II. CHI3and CI4in ethene
The solubilities of CHI3(s) and CI4(s) in near-critical fluid C2H4have been spectrophoto-metrically determined. Isothermal solubility measurements were carried out under subcritical conditions in the dense phase at temperature (273.13±0.01) K for CHI3and (274.47±0.01) K for CI4, and under supercriti...
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1993
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| LEADER | 03307caa a22003617a 4500 | ||
|---|---|---|---|
| 001 | PAPER-239 | ||
| 003 | AR-BaUEN | ||
| 005 | 20230518202937.0 | ||
| 008 | 190411s1993 xx ||||fo|||| 00| 0 eng|d | ||
| 024 | 7 | |2 scopus |a 2-s2.0-0001042728 | |
| 040 | |a Scopus |b spa |c AR-BaUEN |d AR-BaUEN | ||
| 100 | 1 | |a Marceca, E. | |
| 245 | 1 | 0 | |a Solubility of solids in near-critical fluids II. CHI3and CI4in ethene |
| 260 | |c 1993 | ||
| 270 | 1 | 0 | |m Fernández-Prini, R.; Departmento de Quimica Inorgánica, Analitica y Quimica Fisica, Instituto de Quimica Fisica de Materiales, Energia y Ambiente, Facultad de Ciencias Exactas y Naturales, Universidad de Buenos Aires, Cuidad Universitaria Pabellón II, 1428-Capital Federal, Argentina |
| 506 | |2 openaire |e Política editorial | ||
| 504 | |a Fernández, D.P., Fernández-Prini, R., (1992) J. Chem. Thermodynamics, 24, p. 377 | ||
| 504 | |a Müller, H., Seck, H., (1930) Physikui. Z, 31, p. 815 | ||
| 504 | |a Ito, M., Huang, P.C., Kosower, E.M., (1961) Trans. Faraday Soc, 57, p. 1662 | ||
| 504 | |a Unger, K.K., Roumeliotis, P., (1983) J. Chromatography, 282, p. 519 | ||
| 504 | |a Jacobsen, R.T., Jahangiri, M., Stewart, R.B., McCarty, R.D., Levelt Sengers, J.M.H., White, H.J., Jr., Sengers, J.V., Olchowy, G.A., (1987) Final Report on IUPAC. Ethylene Tables, , Project Centre, London | ||
| 504 | |a Kumar, S.K., Johnston, K.P., (1988) J. Supercrit. Fluids, 1, p. 15 | ||
| 520 | 3 | |a The solubilities of CHI3(s) and CI4(s) in near-critical fluid C2H4have been spectrophoto-metrically determined. Isothermal solubility measurements were carried out under subcritical conditions in the dense phase at temperature (273.13±0.01) K for CHI3and (274.47±0.01) K for CI4, and under supercritical conditions at (293.85±0.04) K and (303.19±0.03) K for CHI3and (392.87±0.05) K for CI4; isobaric runs were done for both solutes at a pressure of (6.370±0.001) MPa. Solubilities increase strongly with p and T close to the thermodynamic state where the compressibility or the expansivity of the solvent, respectively, pass through a maximum. It is observed that CI4is almost ten times less soluble than CHI3in near-critical C2H4. © 1993 Academic Press Ltd. |l eng | |
| 593 | |a Departmento de Quimica Inorgánica, Analitica y Quimica Fisica, Instituto de Quimica Fisica de Materiales, Energia y Ambiente, Facultad de Ciencias Exactas y Naturales, Universidad de Buenos Aires, Cuidad Universitaria Pabellón II, 1428-Capital Federal, Argentina | ||
| 700 | 1 | |a Fernández-Prini, R. | |
| 773 | 0 | |d 1993 |g v. 25 |h pp. 237-247 |k n. 2 |p J Chem Thermodyn |x 00219614 |w (AR-BaUEN)CENRE-575 |t The Journal of Chemical Thermodynamics | |
| 856 | 4 | 1 | |u https://www.scopus.com/inward/record.uri?eid=2-s2.0-0001042728&doi=10.1006%2fjcht.1993.1023&partnerID=40&md5=ad6f1c28f93aca11c40e97a776974c35 |y Registro en Scopus |
| 856 | 4 | 0 | |u https://doi.org/10.1006/jcht.1993.1023 |y DOI |
| 856 | 4 | 0 | |u https://hdl.handle.net/20.500.12110/paper_00219614_v25_n2_p237_Marceca |y Handle |
| 856 | 4 | 0 | |u https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_00219614_v25_n2_p237_Marceca |y Registro en la Biblioteca Digital |
| 961 | |a paper_00219614_v25_n2_p237_Marceca |b paper |c PE | ||
| 962 | |a info:eu-repo/semantics/article |a info:ar-repo/semantics/artículo |b info:eu-repo/semantics/publishedVersion | ||
| 999 | |c 61192 | ||