Catalytic combustion of methane over ceria-zirconia catalysts

The energy production by combustion of methane or natural gas in gas turbines and burners constitutes a well-developed technology. However, due to the fact that methane is a hydrocarbon molecule difficult to oxidize, the homogeneous combustion with air occurs in flames with very high temperatures. T...

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Autor principal: Larrondo, Susana Adelina
Otros Autores: Zimicz, M.G
Formato: Capítulo de libro
Lenguaje:Inglés
Publicado: Nova Science Publishers, Inc. 2011
Acceso en línea:Registro en Scopus
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100 1 |a Larrondo, Susana Adelina 
245 1 0 |a Catalytic combustion of methane over ceria-zirconia catalysts 
260 |b Nova Science Publishers, Inc.  |c 2011 
270 1 0 |m Larrondo, S.A.; Departamento de Ingeniería Química, Pabellón de Industrias, Universidad de Buenos Aires, Ciudad Universitaria, (1428) Buenos Aires, Argentina; email: susana@di.fcen.uba.ar 
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506 |2 openaire  |e Política editorial 
520 3 |a The energy production by combustion of methane or natural gas in gas turbines and burners constitutes a well-developed technology. However, due to the fact that methane is a hydrocarbon molecule difficult to oxidize, the homogeneous combustion with air occurs in flames with very high temperatures. These high temperatures thermodynamically favor the formation of nitrogen oxides (NOx), which constitutes the "photochemical smog", harmful to aquatic and terrestrial ecosystems and to human health.In recent years, global concern about the rapid increase in emissions of gaseous pollutants and greenhouse gases caused by the growth in energy demand has been growing. Under the Kyoto protocol, the reductions of hydrocarbons, carbon dioxide (CO2) and NOx emissions, and the increase of combustion efficiency, especially in the case of methane and natural gas, have become a central research topic.The catalytic combustion of methane emerges as a possible solution due to its advantages over the homogeneous combustion. The presence of a catalyst facilitates the total oxidation of methane and, moreover, a suitable catalyst will promote the total combustion at lower temperatures than the homogeneous reaction, leading to a reduction of NOx emissions. The goal in this area is to develop a catalyst that promotes the total oxidation of methane at low temperatures, reducing the emission of greenhouse and harmful gases.In this review, the important aspects of the catalytic combustion of methane using ceria-zirconia catalysts are addressed. The major findings in recent years are presented. © 2011 Nova Science Publishers, Inc. All Rights Reserved.  |l eng 
593 |a Departamento de Ingeniería Química, Pabellón de Industrias, Universidad de Buenos Aires, Ciudad Universitaria, (1428) Buenos Aires, Argentina 
593 |a CINSO (Centro de Investigaciones en Sólidos), CONICET-CITEFA, J.B. de La Salle 4397, (1603) Villa Martelli, Pcia. de Buenos Aires, Argentina 
700 1 |a Zimicz, M.G. 
773 0 |d Nova Science Publishers, Inc., 2011  |h pp. 173-188  |p Catalytic Combust.  |z 9781613242797  |t Catalytic Combustion 
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