Micro-Raman spectroscopy of carbon-based black pigments

Carbon-based black pigments are a wide group of dark-colored materials, which are classified according to the starting material used and their method of manufacture. Raman spectroscopy is an ideal technique for the characterization of carbonaceous matter: crystalline carbon materials present well-de...

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Detalles Bibliográficos
Autor principal: Tomasini, E.P
Otros Autores: Halac, E.B, Reinoso, M., Di Liscia, E.J, Maier, M.S
Formato: Capítulo de libro
Lenguaje:Inglés
Publicado: 2012
Acceso en línea:Registro en Scopus
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Registro en la Biblioteca Digital
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100 1 |a Tomasini, E.P. 
245 1 0 |a Micro-Raman spectroscopy of carbon-based black pigments 
260 |c 2012 
270 1 0 |m Maier, M.S.; UMYMFOR, Departamento de Química Orgánica, Ciudad Universitaria (C1428EGA), Pabellõn 2, Ciudad Autõnoma de Buenos Aires, Argentina; email: maier@qo.fcen.uba.ar 
506 |2 openaire  |e Política editorial 
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520 3 |a Carbon-based black pigments are a wide group of dark-colored materials, which are classified according to the starting material used and their method of manufacture. Raman spectroscopy is an ideal technique for the characterization of carbonaceous matter: crystalline carbon materials present well-defined peaks, which can be easily assigned; amorphous carbon materials, on the other hand, show broad bands between 1300 and 1600 cm -1. The aim of this work was the discrimination between carbon-based pigments by micro-Raman spectroscopy. Five carbon-based pigments provided by Zecchi (lampblack, ivory black, bistre, bitumen, and graphite), two humic-earth materials [Van Dyck (Kremer) and Earth of Kassel (Zecchi)], and a commercial wood charcoal were studied. Raman spectra of all the samples showed the characteristic bands at approximately 1580 and 1350 cm -1; however, a clear difference in position, width, and relative intensity could be observed for most of the samples. The resulting analysis showed that micro-Raman spectroscopy allowed the discrimination of most of the reference pigments and allowed the identification of carbon-based black pigments in two South American colonial paintings dated from the early 18th century. Copyright © 2012 John Wiley & Sons, Ltd.  |l eng 
593 |a UMYMFOR, Departamento de Química Orgánica, Ciudad Universitaria (C1428EGA), Pabellõn 2, Ciudad Autõnoma de Buenos Aires, Argentina 
593 |a Gerencia de Investigaciõn y Aplicaciones, Comisiõn Nacional de Energía Atõmica Villa Martelli, Av. General Paz 1499 (B1650KNA), Buenos Aires, Argentina 
593 |a Escuela de Ciencia y Tecnología, Universidad Nacional de San Martín San Martín, M. de Irigoyen 3100 (B1650KNA), Buenos Aires, Argentina 
690 1 0 |a ART AND ARCHAEOLOGY 
690 1 0 |a CARBON-BASED PIGMENTS 
690 1 0 |a COLONIAL ART 
690 1 0 |a MICRO-RAMAN SPECTROSCOPY 
700 1 |a Halac, E.B. 
700 1 |a Reinoso, M. 
700 1 |a Di Liscia, E.J. 
700 1 |a Maier, M.S. 
773 0 |d 2012  |g v. 43  |h pp. 1671-1675  |k n. 11  |p J. Raman Spectrosc.  |x 03770486  |t Journal of Raman Spectroscopy 
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