Luminescent hybrid oxydiacetic/ethyleneglycol/TEOS/Eu(III) material: Thermal and spectroscopic analysis
A luminescent hybrid organic-inorganic material was synthesized with the sol-gel technique by hydrolysis of tetraethoxysilane (TEOS) and an organic precursor obtained through the esterification of oda (oxydiacetic acid) and EG (ethyleneglycol) in acid media. The Eu(III) ion was included in the syste...
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2010
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| LEADER | 12331caa a22011297a 4500 | ||
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| 001 | PAPER-22886 | ||
| 003 | AR-BaUEN | ||
| 005 | 20230518205430.0 | ||
| 008 | 190411s2010 xx ||||fo|||| 00| 0 eng|d | ||
| 024 | 7 | |2 scopus |a 2-s2.0-77953812312 | |
| 040 | |a Scopus |b spa |c AR-BaUEN |d AR-BaUEN | ||
| 030 | |a JSGTE | ||
| 100 | 1 | |a Marchi, M.C. | |
| 245 | 1 | 0 | |a Luminescent hybrid oxydiacetic/ethyleneglycol/TEOS/Eu(III) material: Thermal and spectroscopic analysis |
| 260 | |c 2010 | ||
| 270 | 1 | 0 | |m Barja, B. C.; INQUIMAE, Departamento de Química Inorgánica, Ciudad Universitaria, Pabellón 2, C1428EHA Buenos Aires, Argentina; email: barja@qi.fcen.uba.ar |
| 506 | |2 openaire |e Política editorial | ||
| 504 | |a Carlos, L.D., Ferreira, R.A.S., De Zea Bermudez, V., Ribeiro, S.J.L., Lanthanide-containing light-emitting organic-inorganic hybrids: A bet on the future (2009) Adv Mater, 21, pp. 509-534. , 10.1002/adma.200801635 1:CAS:528:DC%2BD1MXitFSjsbk%3D | ||
| 504 | |a Binnemans, K., Lanthanide-based luminescent hybrid materials (2009) Chem Rev, 109, pp. 4283-4374. , 10.1021/cr8003983 1:CAS:528:DC%2BD1MXptleltLk%3D 19650663 | ||
| 504 | |a Reisfeld, R., Saraidarov, T., Gaft, M., Pietraszkiewicz, M., Luminescence of cryptate-type Eu3+ complexes incorporated in inorganic and ormocer sol-gel matrices (2007) Optical Materials, 29 (5), pp. 521-527. , DOI 10.1016/j.optmat.2005.08.048, PII S0925346705004805 | ||
| 504 | |a Besson, E., Mehdi, A., Reye, C., Corriu, R.J.P., Functionalisation of the framework of mesoporous organosilicas by rare-earth complexes (2006) Journal of Materials Chemistry, 16 (3), pp. 246-248. , DOI 10.1039/b514878b | ||
| 504 | |a Battisha, I.K., El Beyally, A., El Mongy, S.A., Nahrawi, A.M., Development of the FTIR properties of nano-structure silica gel doped with different rare earth elements, prepared by sol-gel route (2007) Journal of Sol-Gel Science and Technology, 41 (2), pp. 129-137. , DOI 10.1007/s10971-006-0520-z | ||
| 504 | |a Avila, L.R., Nassor, E.C., Pereira, P.F.S., Cestari, A., Ciuffi, K.J., Calefi, P.S., Nassar, E.J., Preparation and properties of europium-doped phosphosilicate glasses obtained by the sol-gel method (2008) J Non-Cryst Solids, 354, pp. 4806-4810. , 10.1016/j.jnoncrysol.2008.04.038 1:CAS:528:DC%2BD1cXht1Chur%2FO 2008JNCS.354.4806A | ||
| 504 | |a Nassar, E.J., Ciuffi, K.J., Lima Ribeiro, S.J., Messaddeq, Y., Europium incorporated in silica matrix obtained by sol-gel: Luminescent materials (2003) Mater Res, 6 (4), pp. 557-562. , 1:CAS:528:DC%2BD3sXpvVyrt7Y%3D | ||
| 504 | |a Ofelt, G.S., Structure of the f6 configuration with application to rare earth ions (1963) J Chem Phys, 38, pp. 2171-2180. , 10.1063/1.1733947 1:CAS:528:DyaF3sXntVKlug%3D%3D 1963JChPh.38.2171O | ||
| 504 | |a Parker, D., Williams, G., Getting excited about lanthanide complexation chemistry (1996) J Chem Soc Dalton Trans, 18, pp. 3613-3628. , 10.1039/dt9960003613 | ||
| 504 | |a Beeby, A., Clarkson, I.M., Dickins, R.S., Faulkner, S., Parker, D., Royle, L., De Souza, A.S., Woods, M.J., Non-radiative deactivation of the excited ststes of europium, terbium and ytterbium complexes by proximate energy-matched OH, NH and CH oscillators: An improved luminescence method for establishing solution hydration states (1999) J Chem Soc Perkin Trans, 2, pp. 493-503 | ||
| 504 | |a Reisfeld, R., Zigansky, E., Gaft, M., Europium probe for estimation of site symmetry in glass films, glasses and crystals (2004) Mol Phy, 102, pp. 1319-1330. , 10.1080/00268970410001728609 1:CAS:528:DC%2BD2cXosl2gs70%3D 2004MolPh.102.1319R | ||
| 504 | |a Carlos, L.D., Ferreira Sá, R.A., Gonçalves, M.C., De Zea Bermudez, V., Local coordination of Eu(III) in organic-inorganic amine functionalized hybrids (2004) J Alloys Comp, 374, pp. 50-55. , 10.1016/j.jallcom.2003.11.063 1:CAS:528:DC%2BD2cXks1Grurs%3D | ||
| 504 | |a Ewjl, O., Van Dongen, A.M.A., Europium (III) in oxide glasses. Dependence of the emission spectrum upon composition (1989) J Non-Cryst Solids, 111, pp. 205-213. , 10.1016/0022-3093(89)90282-2 1:CAS:528:DyaK3cXmsFyjsw%3D%3D 1989JNCS.111.205O | ||
| 504 | |a Richardson, F.S., Terbium (III) and europium (III) Ions as luminescent probes and stains for biomolecular systems (1982) Chem Rev, 82, pp. 541-552. , 10.1021/cr00051a004 1:CAS:528:DyaL38XmtFWktr0%3D | ||
| 504 | |a Zhang, Y., Wang, M., Structural information given by R curve of Eu3+ probe during the heat treatment process of SiO2-B2O3 gel glasses (1999) Materials Letters, 41 (3), pp. 149-152. , DOI 10.1016/S0167-577X(99)00122-6 | ||
| 504 | |a Albin, M., Whittle, R.R., Horrocks Jr., W.D., Laser spectroscopic and X-ray structural investigation of europium(III)-oxydiacetate complexes in solution and in the solid state (1985) Inorg Chem, 24, pp. 4591-4594. , 10.1021/ic00220a032 1:CAS:528:DyaL28XhsVSlsg%3D%3D | ||
| 504 | |a Ribeiro, S.J.L., Dahmouche, K., Ribeiro, C.A., Santilli, C.V., Pulcinelli, S.H., Study of hybrid silica-polyethyleneglycol xerogels by Eu3+ luminescence spectroscopy (1998) J Sol-Gel Sci Technol, 13, pp. 427-432. , 10.1023/A:1008673211834 1:CAS:528:DyaK1MXpvFehtw%3D%3D | ||
| 504 | |a Lenza, R.F.S., Vasconcelos, W.L., Preparation of silica by sol-gel method using formamide (2001) Mater Res, 4, pp. 189-194. , 1:CAS:528:DC%2BD3MXmvV2mtLo%3D | ||
| 504 | |a Parvathy Rao, A., Venkasteswara Rao, A., Studies on the effect of organic additives on the monolithicity and optical properties of the rhodamine 6G doped silica xerogels (2003) Mater Lett, 57, pp. 3741-3747. , 10.1016/S0167-577X(03)00172-1 | ||
| 504 | |a Uchida, N., Ishiyama, N., Kato, Z., Uematsu, K., Chemical Effects of DCCA to the sol-gel reaction process (1994) J Mater Sci, 29, pp. 5188-5192. , 10.1007/BF01151115 1:CAS:528:DyaK2cXmtlKrsLo%3D 1994JMatS.29.5188U | ||
| 504 | |a Parashar, V.K., Raman, V., Bahl, O.P., The role of N, N, dimethylformamide and glycol in the preparation and properties of sol-gel derived silica (1996) J Mater Sci Lett, 15, pp. 1403-1407. , 10.1007/BF00275289 1:CAS:528:DyaK28Xls1GhsLk%3D | ||
| 504 | |a Stefanescu, M., Stoia, M., Stefanescu, O., Thermal and FT-IR study of the hybrid ethylene-glycol-silica matrix (2007) Journal of Sol-Gel Science and Technology, 41 (1), pp. 71-78. , DOI 10.1007/s10971-006-0118-5 | ||
| 504 | |a Ramsis, H., Perez-Ruiz, E., Roger, J., Bourret, E., Delarbre, J.L., Maury, L., Vibrational study of diglycolic acid and potassium diglycolate salts (1995) J Raman Spectrosc, 26, pp. 131-136. , 10.1002/jrs.1250260205 1:CAS:528:DyaK2MXktFSjtbc%3D 1995JRSp.26.131R | ||
| 504 | |a Roeges, N.P.G., (1994) A Guide to the Complete Interpretation of Infrared Spectra of Organic Structures, , Wiley New York Chapter 7, page 174 | ||
| 504 | |a Brinker, C.J., Scherer, G.W., (1990) Sol-gel Science. The Physics and Chemistry of Sol-gel Processing, , Academic Press New York Chapter 9, Section 2.4.2 | ||
| 504 | |a Karakassides, M.A., Petridis, D., Gournis, D., Infrared reflectance study of thermally treated Li- and Cs-montmorillonites (1997) Clays and Clay Minerals, 45 (5), pp. 649-658 | ||
| 504 | |a Stefanescu, M., Stoia, M., Stefanescu, O., Popa, A., Simon, M., Ionescu, C., The interaction between TEOS and some polyols: Thermal analysis and FTIR (2007) Journal of Thermal Analysis and Calorimetry, 88 (1), pp. 19-26. , DOI 10.1007/s10973-006-8002-7 | ||
| 504 | |a Brinker, C.J., Scherer, G.W., (1990) Sol-gel Science. The Physics and Chemistry of Sol-gel Processing, , Academic Press New York Chapter 9, Section 2.2.3 | ||
| 504 | |a Vinciguerra, V., Bucci, R., Marini, F., Napoli, A., Thermal behaviour of iminodiacetic, oxydiacetic and thiodiacetic acids (2006) Journal of Thermal Analysis and Calorimetry, 83 (2), pp. 475-478. , DOI 10.1007/s10973-005-6939-6 | ||
| 504 | |a Lana, S.L.B., Seddon, A.B., X-ray diffraction studies of sol-gel derived ORMOSILS based on combination of tetramethoxysilane and trimethoxysilane (1998) J Sol-Gel Sci Technol, 13, pp. 461-466. , 10.1023/A:1008685614559 1:CAS:528:DyaK1MXpvFegsw%3D%3D | ||
| 504 | |a Lavin, V., Babu, P., Jayasankar, C.K., Martin, I.R., Rodriguez, V.D., On the local structure of Eu3+ ions in oxyfluoride glasses. Comparison with fluoride and oxide glasses (2001) Journal of Chemical Physics, 115 (23), pp. 10935-10944. , DOI 10.1063/1.1420731 | ||
| 504 | |a McDonagh, C., Ennis, G., Marron, P., O'Kelly, B., Tang, Z.R., McGilp, J.F., Characterization of sol-gel glasses using optical probes (1992) J Non-Cryst Solids, 147-148, pp. 97-101. , 10.1016/S0022-3093(05)80600-3 | ||
| 504 | |a Kirby, A.F., Richardson, F.S., Optical excitation and emission spectra of Eu3+ in microcrystalline samples of trigonal Na[Eu(ODA)3].2NaCIO 4.6H2O (1983) J Phys Chem, 87, pp. 2557-2563. , 10.1021/j100237a019 1:CAS:528:DyaL3sXktlShsrc%3D | ||
| 520 | 3 | |a A luminescent hybrid organic-inorganic material was synthesized with the sol-gel technique by hydrolysis of tetraethoxysilane (TEOS) and an organic precursor obtained through the esterification of oda (oxydiacetic acid) and EG (ethyleneglycol) in acid media. The Eu(III) ion was included in the system to monitor the formation of the complex between the lanthanide and the ligand oda in the hybrid matrix. The spectral features of the emission of the Eu(III) ion together with the data obtained from infrared spectroscopy, thermogravimetric and differential thermal analysis, and scanning electron microscopy permit the structural characterization of the system and its comparison with a reference sample in which no organic moieties were hydrolyzed during the sol-gel process. © 2010 Springer Science+Business Media, LLC. |l eng | |
| 536 | |a Detalles de la financiación: National Council for Scientific Research, UB-ACyTX006 | ||
| 536 | |a Detalles de la financiación: Universidad de Buenos Aires, PICT33973 | ||
| 536 | |a Detalles de la financiación: Agencia Nacional de Promoción Científica y Tecnológica | ||
| 536 | |a Detalles de la financiación: Consejo Nacional de Investigaciones Científicas y Técnicas | ||
| 536 | |a Detalles de la financiación: Acknowledgments BCB and PFA are members of Carrera del In-vestigador Científico (Research Staff) from CONICET (National Research Council of Argentina). MCM is researcher at the Univers-idad de Buenos Aires. The work was supported by grants UB-ACyTX006 (Universidad de Buenos Aires) and PICT33973 (ANPCyT, Argentina). | ||
| 593 | |a INQUIMAE, Departamento de Química Inorgánica, Ciudad Universitaria, Pabellón 2, C1428EHA Buenos Aires, Argentina | ||
| 690 | 1 | 0 | |a EUROPIUM(III) COMPLEXES |
| 690 | 1 | 0 | |a LUMINESCENCE AND DCCA |
| 690 | 1 | 0 | |a SOL-GEL |
| 690 | 1 | 0 | |a TEOS |
| 690 | 1 | 0 | |a ACID MEDIA |
| 690 | 1 | 0 | |a EUROPIUM COMPLEX |
| 690 | 1 | 0 | |a EUROPIUM(III) COMPLEXES |
| 690 | 1 | 0 | |a HYBRID MATRIX |
| 690 | 1 | 0 | |a HYBRID ORGANIC-INORGANIC MATERIALS |
| 690 | 1 | 0 | |a LANTHANIDES |
| 690 | 1 | 0 | |a ORGANIC MOIETY |
| 690 | 1 | 0 | |a ORGANIC PRECURSOR |
| 690 | 1 | 0 | |a OXYDIACETIC ACID |
| 690 | 1 | 0 | |a SOL-GEL TECHNIQUE |
| 690 | 1 | 0 | |a SPECTRAL FEATURE |
| 690 | 1 | 0 | |a STRUCTURAL CHARACTERIZATION |
| 690 | 1 | 0 | |a TETRAETHOXYSILANES |
| 690 | 1 | 0 | |a DIFFERENTIAL THERMAL ANALYSIS |
| 690 | 1 | 0 | |a ESTERS |
| 690 | 1 | 0 | |a EUROPIUM |
| 690 | 1 | 0 | |a GELS |
| 690 | 1 | 0 | |a HYDROLYSIS |
| 690 | 1 | 0 | |a INFRARED SPECTROSCOPY |
| 690 | 1 | 0 | |a LUMINESCENCE |
| 690 | 1 | 0 | |a SCANNING ELECTRON MICROSCOPY |
| 690 | 1 | 0 | |a SOL-GELS |
| 690 | 1 | 0 | |a SOLS |
| 690 | 1 | 0 | |a SPECTROSCOPIC ANALYSIS |
| 690 | 1 | 0 | |a THERMOGRAVIMETRIC ANALYSIS |
| 690 | 1 | 0 | |a SOL-GEL PROCESS |
| 700 | 1 | |a Aramendía, P.F. | |
| 700 | 1 | |a Barja, B.C. | |
| 773 | 0 | |d 2010 |g v. 54 |h pp. 292-300 |k n. 3 |p J Sol Gel Sci Technol |x 09280707 |t Journal of Sol-Gel Science and Technology | |
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