Diffusion coefficients of iodide in high temperature aqueous solutions
The diffusion coefficients of iodide in water solutions containing NaHSO4 as supporting electrolyte have been measured between 102 and 215 °C using a high-temperature wall-tube cell. The temperature behavior of the diffusion coefficients is well described by the Arrhenius law and the activation ener...
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| Otros Autores: | , |
| Formato: | Capítulo de libro |
| Lenguaje: | Inglés |
| Publicado: |
2000
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| Acceso en línea: | Registro en Scopus DOI Handle Registro en la Biblioteca Digital |
| Aporte de: | Registro referencial: Solicitar el recurso aquí |
| LEADER | 05418caa a22007457a 4500 | ||
|---|---|---|---|
| 001 | PAPER-2263 | ||
| 003 | AR-BaUEN | ||
| 005 | 20230518203139.0 | ||
| 008 | 190411s2000 xx ||||fo|||| 00| 0 eng|d | ||
| 024 | 7 | |2 scopus |a 2-s2.0-0033825965 | |
| 040 | |a Scopus |b spa |c AR-BaUEN |d AR-BaUEN | ||
| 030 | |a ECCMF | ||
| 100 | 1 | |a Trevani, L.N. | |
| 245 | 1 | 0 | |a Diffusion coefficients of iodide in high temperature aqueous solutions |
| 260 | |c 2000 | ||
| 270 | 1 | 0 | |m Corti, H.R.; Inst. de Quimica Fisica Materiales, Fac. de Ciencias Exactas y Naturales, Universidad de Buenos Aires, Pabellon 11, 1428 Buenos Aires, Argentina; email: hrcorti@cnea.gov.ar |
| 506 | |2 openaire |e Política editorial | ||
| 504 | |a Ashton, L., Corti, H.R., Turner, D.J., (1986), A.M. Deane, P.E. Potter (Eds.), Proceedings of the Specialist's Workshop on Iodine Chemistry in Reactor Safety, AERE, Harwell, UK; Palmer, D.A., Lietzke, M.H., (1982) Radiochim. Acta, 31, p. 37 | ||
| 504 | |a Quist, A.S., Marshall, W.L., (1969) J. Phys. Chem., 73, p. 978 | ||
| 504 | |a Flarsheim, W.M., Tsou, Y., Tratchtenberg, I., Johnston, K.P., Bard, A.J., (1986) J. Phys. Chem., 90, p. 3857 | ||
| 504 | |a Liu, C., Snyder, S.R., Bard, A.J., (1997) J. Phys. Chem. B, 101, p. 1180 | ||
| 504 | |a Cantrel, L., Fulconis, J.-M., Chopin-Dumas, J., (1998) J. Solution Chem., 27, p. 373 | ||
| 504 | |a Trevani, L.N., Calvo, E., Corti, H.R., (1997) J. Chem. Soc., Faraday Trans., 93, p. 4319 | ||
| 504 | |a Pau, P.C.F., Berg, J.O., McMillan, W.G., (1990) J. Phys. Chem., 94, p. 2671 | ||
| 504 | |a Koneshan, S., Rasaiah, J.C., Lynden-Bell, R.M., Lee, S.H., (1998) J. Phys. Chem. B, 102, p. 4193 | ||
| 504 | |a Chin, D.T., Tsang, C.H., (1978) J. Electrochem. Soc., 125, p. 1461 | ||
| 504 | |a Wightman, R.M., Wipf, D.O., (1989), A.J. Bard (Ed.), Electroanalytical Chemistry, vol. 15, Marcel Dekker, New York; Watson, J.T.R., Basu, R.S., Levelt Sengers, J.V., (1980) J. Phys. Chem. Ref. Data, 9, p. 1255 | ||
| 504 | |a Hill, P.G., (1990) J. Phys. Chem. Ref. Data, 19, p. 1233 | ||
| 504 | |a Newman, J., (1966) J. Phys. Chem., 70, p. 1327 | ||
| 504 | |a Levich, B.G., (1942) Acta Physicochim. URSS, 17, p. 257 | ||
| 504 | |a Trevani, L.N., (1997), Thesis, University of Buenos Aires; Robinson, R.A., Stokes, R.H., (1959), Electrolyte Solutions, 2nd ed., Butterworth, London, Appendix 6.2; Spiro, M., Creeth, A.M., (1990) J. Chem. Soc., Faraday Trans., 86, p. 3573 | ||
| 504 | |a Palmer, D.A., Ramette, R.W., Mesmer, R.E., (1984) J. Solution Chem., 13, p. 673 | ||
| 504 | |a Leaist, D.G., (1988) J. Solution Chem., 17, p. 359 | ||
| 520 | 3 | |a The diffusion coefficients of iodide in water solutions containing NaHSO4 as supporting electrolyte have been measured between 102 and 215 °C using a high-temperature wall-tube cell. The temperature behavior of the diffusion coefficients is well described by the Arrhenius law and the activation energy for the mass transport is 17 kJ mol-1. The results are compared to those calculated from the iodide conductivity at infinite dilution and to recent results from other authors. The solvation and speciation of the iodide ion in aqueous solutions at high temperature are analyzed. (C) 2000 Elsevier Science S.A. |l eng | |
| 536 | |a Detalles de la financiación: Consejo Nacional de Investigaciones Científicas y Técnicas | ||
| 536 | |a Detalles de la financiación: Consejo Nacional de Investigaciones Científicas y Técnicas, UBACyT | ||
| 536 | |a Detalles de la financiación: The authors are grateful for partial financial support by Consejo Nacional de Investigaciones Cientı́ficas y Técnicas (CONICET) and UBACyT. | ||
| 593 | |a Instituto De Química Física De Los Materiales, Medio Ambiente Y Energía, Facultad De Ciencias Exactas Y Naturales, Pabellón II, 1428 Buenos Aires, Argentina | ||
| 593 | |a Unidad De Actividad Química, Centro Atómico Constituyentes, Comisión Nacional De Energía Atómica, Gral Paz 1499, 1625 San Martín, Buenos Aires, Argentina | ||
| 593 | |a Escuela De Ciencia Y Tecnología, Universidad Nacional De Gral. San Martín, Calle 78 No. 3901, 1653 Villa Ballester, Buenos Aires, Argentina | ||
| 690 | 1 | 0 | |a DIFFUSION |
| 690 | 1 | 0 | |a HIGH TEMPERATURE |
| 690 | 1 | 0 | |a IODIDE |
| 690 | 1 | 0 | |a SOLVATION |
| 690 | 1 | 0 | |a WALL-TUBE ELECTRODE |
| 690 | 1 | 0 | |a IODIDE |
| 690 | 1 | 0 | |a AQUEOUS SOLUTION |
| 690 | 1 | 0 | |a ARTICLE |
| 690 | 1 | 0 | |a CALCULATION |
| 690 | 1 | 0 | |a CONDUCTANCE |
| 690 | 1 | 0 | |a DIFFUSION |
| 690 | 1 | 0 | |a NUCLEAR ENERGY |
| 690 | 1 | 0 | |a POTENTIOMETRY |
| 690 | 1 | 0 | |a SOLVATION |
| 690 | 1 | 0 | |a TEMPERATURE |
| 700 | 1 | |a Calvo, E. | |
| 700 | 1 | |a Corti, H.R. | |
| 773 | 0 | |d 2000 |g v. 2 |h pp. 312-316 |k n. 5 |p Electrochem. Commun. |x 13882481 |w (AR-BaUEN)CENRE-1729 |t Electrochemistry Communications | |
| 856 | 4 | 1 | |u https://www.scopus.com/inward/record.uri?eid=2-s2.0-0033825965&doi=10.1016%2fS1388-2481%2800%2900023-0&partnerID=40&md5=22eef11024a86dda9948a9d02f153ff7 |y Registro en Scopus |
| 856 | 4 | 0 | |u https://doi.org/10.1016/S1388-2481(00)00023-0 |y DOI |
| 856 | 4 | 0 | |u https://hdl.handle.net/20.500.12110/paper_13882481_v2_n5_p312_Trevani |y Handle |
| 856 | 4 | 0 | |u https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_13882481_v2_n5_p312_Trevani |y Registro en la Biblioteca Digital |
| 961 | |a paper_13882481_v2_n5_p312_Trevani |b paper |c PE | ||
| 962 | |a info:eu-repo/semantics/article |a info:ar-repo/semantics/artículo |b info:eu-repo/semantics/publishedVersion | ||
| 999 | |c 63216 | ||