Reactivity and spectroscopy of the {Ru(DMAP)5} fragment: An {Ru(NH3)5} analogue
Reaction of trans-Ru(DMSO)4Cl2 with DMAP (DMAP = 4-dimethylaminopyridine) yields the yellow [Ru(DMAP)6]2+ cation in good yield. The crystal and molecular structure of [Ru(DMAP) 6]Cl2·6CH3CH2OH was determined by X-ray diffraction methods. The complex crystallizes in the trigonal R3 space group with a...
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2008
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| LEADER | 08809caa a22009017a 4500 | ||
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| 001 | PAPER-22419 | ||
| 003 | AR-BaUEN | ||
| 005 | 20241206083155.0 | ||
| 008 | 190411s2008 xx ||||fo|||| 00| 0 eng|d | ||
| 024 | 7 | |2 scopus |a 2-s2.0-42449118021 | |
| 030 | |a INOCA | ||
| 040 | |a Scopus |b spa |c AR-BaUEN |d AR-BaUEN | ||
| 100 | 1 | |a Rossi, M.B. | |
| 245 | 1 | 0 | |a Reactivity and spectroscopy of the {Ru(DMAP)5} fragment: An {Ru(NH3)5} analogue |
| 260 | |c 2008 | ||
| 270 | 1 | 0 | |m Alborés, P.; Departamento de Química Inorgánica, Analítica Y Química Física, INQUIMAE, Ciudad Universitaria, C1428EHA Buenos Aires, Argentina; email: albores@qi.fcen.uba.ar |
| 504 | |a Taube, H., (1979) Pure Appl. Chem, 51, p. 901 | ||
| 504 | |a Watzky, M.A., Macatangay, A.V., VanCamp, R.A., Mazzetto, S.E., Song, X.Q., Endicott, J.F., Buranda, T., (1997) J. Phys. Chem. A, 101, p. 8441 | ||
| 504 | |a Watzky, M.A., Endicott, J.F., Song, X.Q., Lei, Y.B., Macatangay, A., (1996) Inorg. Chem, 35, p. 3463 | ||
| 504 | |a Sommovigo, M., Ferretti, A., Venturi, M., Ceroni, P., Giardi, C., Denti, G., (2002) Inorg. Chem, 41, p. 1263 | ||
| 504 | |a Scandola, F., Argazzi, R., Bignozzi, C.A., Chiorboli, C., Indelli, M.T., Rampi, M.A., (1993) Coord. Chem. Rev, 125, p. 283 | ||
| 504 | |a Moscherosch, M., Waldhor, E., Binder, H., Kaim, W., Fiedler, J., (1995) Inorg. Chem, 34, p. 4326 | ||
| 504 | |a Macatangay, A.V., Endicott, J.F., (2000) Inorg. Chem, 39, p. 437 | ||
| 504 | |a Bignozzi, C.A., Argazzi, R., Schoonover, J.R., Gordon, K.C., Dyer, R.B., Scandola, F., (1992) Inorg. Chem, 31, p. 5260 | ||
| 504 | |a Creutz, C., Taube, H., (1969) J. Am. Chem. Soc, 91, p. 3988 | ||
| 504 | |a (2000) CRC Handbook of Chemistry and Physics, p. 1995. , 81st ed, Lide, D. R, Ed, CRC Press: Boca Raton, FL | ||
| 504 | |a Albores, P., Slep, L.D., Weyhermuller, T., Baraldo, L.M., (2004) Inorg. Chem, 43, p. 6762 | ||
| 504 | |a Evans, I.P., Spencer, A., Wilkinson, G., (1973) J. Chem. Soc., Dalton Trans, p. 204 | ||
| 504 | |a Templeton, J.L., (1979) J. Am. Chem. Soc, 101, p. 4906 | ||
| 504 | |a Ford, P., Rudd, D.F.P., Gaunder, R., Taube, H., (1968) J. Am. Chem. Soc, 90, p. 1187 | ||
| 504 | |a Koelsch, C.F., Gumprecht, W.H., (1958) J. Org. Chem, 23, p. 1603 | ||
| 504 | |a Enraf-Nonius, B.V., (1997) COLLECT data collection software, , Nonius BV, Delft, The Netherlands; | ||
| 504 | |a Otwinowski, Z., Minor, W., (1997) Methods in Enzymology: Macromolecular Crystallography, 276, p. 307. , Carter, C. W, Sweet, R. M, Eds, Academic Press: San Diego | ||
| 504 | |a Spek, A.L., (2000) PLATON, A Multipurpose Crystallographic Tool, , Utrecht University: Utrecht, The Netherlands | ||
| 504 | |a Sheldrick, G.M., (1997) SHELXS-97. Program for Crystal Structure Resolution, , University of Göttingen: Göttingen, Germany | ||
| 504 | |a Sheldrick, G.M., (1997) SHELXL-97. Program for Crystal Structures Analysis, , University of Göttingen: Göttingen, Germany | ||
| 504 | |a Frisch, M. J, Trucks, G. W, Schlegel, H. B, Scuseria, G. E, Robb, M. A, Cheeseman, J. R, Montgomery, J. A, Vreven, T, Jr, Kudin, K. N, Burant, J. C, Millam, J. M, Iyengar, S. S, Tomasi, J, Barone, V, Mennucci, B, Cossi, M, Scalmani, G, Rega, N, Petersson, G. A, Nakatsuji, H, Hada, M, Ehara, M, Toyota, K, Fukuda, R, Hasegawa, J, Ishida, M, Nakajima, T, Honda, Y, Kitao, O, Nakai, H, Kiene, M, Li, X, Knox, J. E, Hratchian, H. P. Cross, J. B, Adamo, C, Jaramillo, J, Gomperts, R, Stratmann, R. E, Yazyev, O, Austin, A. J, Cammi, R, Pomelli, C, Ochterski, J. W, Ayala, P. Y, Morokuma, K, Voth, G. A, Salvador, P, Dannenberg, J. J, Zakrzewski, V. G, Dapprich, S, Daniels, A. D, Strain, M. C, Farkas, O, Malick, D. K, Rabuck, A. D, Raghavachari, K, Foresman, J. B, Ortiz, J. V, Cui, Q, Baboul, A. G, Clifford, S, Cioslowski, J, Stefanov, B. B, Liu, G, Liashenko, A, Piskorz, P, Komaromi, I, Martin, R. L, Fox, D. J, Keith, T, Al-Lah; Johnson, C.K., ORTEP-II. A Fortran Thermal-Ellipsoid Plot Program (1976), Report ORNL-5318, Oak Ridge National Laboratory: Tennessee; Bonnet, S., Collin, J.P., Gruber, N., Sauvage, J.P., Schofield, E.R., (2003) Dalton Trans, p. 4654 | ||
| 504 | |a Chen, J.L., Zhang, L.Y., Chen, Z.N., Gao, L.B., Abe, M., Sasaki, Y., (2004) Inorg. Chem, 43, p. 1481 | ||
| 504 | |a Liu, X.X., Wong, W.T., (2000) Polyhedron, 19, p. 7 | ||
| 504 | |a Zong, R.F., Thummel, R.P., (2004) J. Amer. Chem. Soc, 126, p. 10800 | ||
| 504 | |a Biradha, K., Edwards, R.E., Foulds, G.J., Robinson, W.T., Desiraju, G.R., (1995) J. Chem. Soc., Chem. Commun, p. 1705 | ||
| 504 | |a Ohms, U., Guth, H., (1984) Z. Kristallogr, 166, p. 213 | ||
| 504 | |a Creutz, C., Chou, M.H., (1987) Inorg. Chem, 26, p. 2995 | ||
| 504 | |a Albores, P., Rossi, M.B., Baraldo, L.M., Slep, L.D., (2006) Inorg. Chem, 45, p. 10595 | ||
| 504 | |a Stynes, H.C., Ibers, J.A., (1971) Inorg. Chem, 10, p. 2304 | ||
| 504 | |a Baumann, J.A., Meyer, T.J., (1980) Inorg. Chem, 19, p. 345 | ||
| 504 | |a Kuehn, C.G., Taube, H., (1976) J. Am. Chem. Soc, 98, p. 689 | ||
| 504 | |a Binstead, R.A., Meyer, T.J., (1987) J. Am. Chem. Soc, 109, p. 3287 | ||
| 504 | |a Aoyagi, K., Yukawa, Y., Shimizu, K., Mukaida, M., Takeuchi, T., Kakihana, H., (1986) Bull. Chem. Soc. J, 59, p. 1493 | ||
| 504 | |a Thompson, M.S., Meyer, T.J., (1982) J. Am. Chem. Soc, 104, p. 4106 | ||
| 504 | |a Dengel, A.C., Elhendawy, A.M., Griffith, W.P., Omahoney, C.A., Williams, D.J., (1990) J. Chem. Soc., Dalton Trans, p. 737 | ||
| 504 | |a Griffith, W.P., (1992) Chem. Soc. Rev, 21, p. 179 | ||
| 504 | |a Roecker, L., Meyer, J., (1987) J. Am. Chem. Soc, 109, p. 746 | ||
| 504 | |a Lever, A.B.P., (1990) Inorg. Chem, 29, p. 1271 | ||
| 504 | |a Endicott, J.F., Taube, H., (1965) Inorg. Chem, 4, p. 437 | ||
| 504 | |a Llobet, A., Doppelt, P., Meyer, T.J., (1988) Inorg. Chem, 27, p. 514 | ||
| 504 | |a Shepherd, R.E., Hoq, M.F., Hoblack, N., Johnson, C.R., (1984) Inorg. Chem, 23, p. 3249 | ||
| 504 | |a Coe, B.J., McDonald, C.I., Couchman, S.M., Jeffery, J.C., Rees, L.H., Coles, S.J., Gelbrich, T., Hursthouse, M.B., (2000) Polyhedron, 19, p. 1193 | ||
| 504 | |a Creutz, C., Newton, M.D., Sutin, N., (1994) J. Photochem. Photobiol. A: Chem, 82, p. 47 | ||
| 504 | |a Slep, L.D., Olabe, J.A., (2001) J. Am. Chem. Soc, 123, p. 7186 | ||
| 504 | |a Applying the mathematical procedure described in ref 34 with a fixed ζ Ru = 1200 cm-1, we obtained an R = 43 with the following values: ML = 5.6 × 103 cm -1, HML = 6.2 × 103 cm -1, and CM2 = 0.84 | ||
| 506 | |2 openaire |e Política editorial | ||
| 520 | 3 | |a Reaction of trans-Ru(DMSO)4Cl2 with DMAP (DMAP = 4-dimethylaminopyridine) yields the yellow [Ru(DMAP)6]2+ cation in good yield. The crystal and molecular structure of [Ru(DMAP) 6]Cl2·6CH3CH2OH was determined by X-ray diffraction methods. The complex crystallizes in the trigonal R3 space group with a = b = 16.373(1), c = 20.311(1) Å, γ = 120°, and Z = 3 molecules per unit cell. The reaction of [Ru(DMAP) 6]2+ in aerobic water gives the red [Ru III(DMAP)5(OH)]2+ cation. This complex shows a chemical behavior similar to [RuIII(NH3) 5Cl]2+ and allows the preparation of a family of [Ru(DMAP)5L]n+ complexes. Their electronic properties indicate that the {RuIII(DMAP)5} fragment is a weaker π-donor than {RuIII(NH3)5}. Our density functional theory (DFT) calculations show that in {RuII(DMAP) 5} the DMAP ligands can compete for the π electron density of the ruthenium making the fragment a weaker π-donor. © 2008 American Chemical Society. |l eng | |
| 593 | |a Departamento de Química Inorgánica, Analítica Y Química Física, INQUIMAE, Ciudad Universitaria, C1428EHA Buenos Aires, Argentina | ||
| 593 | |a Departamento de Física, Facultad Ciencias Exactas, Universidad Nacional de la Plata and IFLP (CONICET), CC 67, 1900 La Plata, Argentina | ||
| 593 | |a Instituto de Física de São Carlos, Universidade de São Pablo, CP. 369, 13560 São Carlos (SP), Brazil | ||
| 700 | 1 | |a Piro, O.E. | |
| 700 | 1 | |a Castellano, Eduardo Ernesto | |
| 700 | 1 | |a Alborés, P. | |
| 700 | 1 | |a Baraldo, L.M. | |
| 773 | 0 | |d 2008 |g v. 47 |h pp. 2416-2427 |k n. 7 |p Inorg. Chem. |x 00201669 |w (AR-BaUEN)CENRE-60 |t Inorganic Chemistry | |
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