Theoretical and experimental studies of diruthenium tetracarboxylates structure, spectroscopy, and electrochemistry
Quantum mechanical calculations at the density functional theory (DFT) level have been performed on diruthenium tetracarboxylates of different levels of molecular complexity: from unsolvated monomers to oligomers. The agreement between the calculated and experimental molecular structures and vibrati...
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American Chemical Society
2008
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| LEADER | 15129caa a22014657a 4500 | ||
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| 001 | PAPER-22388 | ||
| 003 | AR-BaUEN | ||
| 005 | 20230518205356.0 | ||
| 008 | 190411s2008 xx ||||fo|||| 00| 0 eng|d | ||
| 024 | 7 | |2 scopus |a 2-s2.0-84962467084 | |
| 040 | |a Scopus |b spa |c AR-BaUEN |d AR-BaUEN | ||
| 030 | |a INOCA | ||
| 100 | 1 | |a Castro, M.A. | |
| 245 | 1 | 0 | |a Theoretical and experimental studies of diruthenium tetracarboxylates structure, spectroscopy, and electrochemistry |
| 260 | |b American Chemical Society |c 2008 | ||
| 270 | 1 | 0 | |m Roitberg, A. E.; Quantum Theory Project, University of Florida, Gainesville, FL 32611, United States; email: roitberg@ufl.edu |
| 506 | |2 openaire |e Política editorial | ||
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| 520 | 3 | |a Quantum mechanical calculations at the density functional theory (DFT) level have been performed on diruthenium tetracarboxylates of different levels of molecular complexity: from unsolvated monomers to oligomers. The agreement between the calculated and experimental molecular structures and vibrational modes of the simple [Ru 2 (μ-O 2 CCH 3 ) 4 ] 0/ +and [Ru 2 (μ-O 2 CCH 3 ) 4 (H 2 O) 2 ] 10/+ systems made us confident in our calculation methodology. Therefore, it has been applied to the analysis of two different kinds of properties of these compounds: the trends in the UV/vis spectroscopy and electrochemistry along the [Ru 2 (μ-O 2 CCH 3 ) 4 X 2 ] - (X = Cl - , Br - , I) series, and the crystalline polymorphism related to the polymeric strand conformation in extended Ru 2 (μ-O 2 CR) 4 Cl compounds. For the [Ru 2 (μ-O 2 CCH 3 ) 4 X 2 ] - series, we report new spectroscopic and electrochemical results and interpret the trends on the basis of time dependent DFT-polarized continuum model calculations, local charge and spin analysis, and X donor properties. As far as the polymeric conformation is concerned, it has been previously suggested that the Ru-Cl-Ru angle results from a compromise between packing, orbital overlap, and microsegregation. Our calculations on [RU 2 (μ-O 2 CCH 3 ) 4 Cl] 2 Cl - and [Ru 2 (μ-O 2 CCH 3 ) 4 Cl] 3 Cl - oligomers provide insights on the influence of the first two factors on the strand conformation and allows a suggestion on what is the equatorial aliphatic chain's influence on this issue. © 2008 American Chemical Society. |l eng | |
| 593 | |a INQUIMAE, Departamento de Química Inorgánica, Analítica Y Química Física, Ciudad Universitaria, C1428EHA Buenos Aires, Argentina | ||
| 593 | |a Quantum Theory Project, University of Florida, Gainesville, FL 32611, United States | ||
| 593 | |a Instituto de Ciencias, Universidad Nacional de General Sarmiento, J. M. Gutierrez 1150, B1613GSX, Los Polvorines, Prov. Buenos Aires, Argentina | ||
| 700 | 1 | |a Roitberg, A.E. | |
| 700 | 1 | |a Cukiernik, F.D. | |
| 773 | 0 | |d American Chemical Society, 2008 |g v. 47 |h pp. 4682-4690 |k n. 11 |p Inorg. Chem. |x 00201669 |w (AR-BaUEN)CENRE-60 |t Inorganic Chemistry | |
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