Layer-by-layer self-assembled redox polyelectrolytes on passive steel

Mostrar otras versiones (1)

Steel samples were passivated in 0.1 M NaOH solutions at 0.3 V vs. Ag/AgCl (3 M KC1) and then poly(allylamine) derivatized with osmium pyridine- bipyridine-chloride complex and poly-(vinylsulfonate) were sequentially self-assembled electrostatically layer-by-layer. The resulting electrodes were exam...

Descripción completa

Guardado en:
Detalles Bibliográficos
Autor principal: Völker, E.
Otros Autores: Calvo, E.J, Williams, F.J
Formato: Capítulo de libro
Lenguaje:Inglés
Publicado: 2008
Acceso en línea:Registro en Scopus
DOI
Handle
Registro en la Biblioteca Digital
Aporte de:Registro referencial: Solicitar el recurso aquí
Biblioteca Central Dr. Luis F. Leloir (FCEN) de Universidad de Buenos Aires
LEADER 08087caa a22008657a 4500
001 PAPER-22255
003 AR-BaUEN
005 20230518205348.0
008 190411s2008 xx ||||fo|||| 00| 0 eng|d
024 7 |2 scopus  |a 2-s2.0-59449106470 
040 |a Scopus  |b spa  |c AR-BaUEN  |d AR-BaUEN 
100 1 |a Völker, E. 
245 1 0 |a Layer-by-layer self-assembled redox polyelectrolytes on passive steel 
260 |c 2008 
270 1 0 |m Calvo, E. J.; Departamento de Química Inorgdnica, Analítica y Quimica Física, Universidad de Buenos Aires, C1428EHA Buenos Aires, Argentina; email: calvo@qi.fcen.uba.ar 
506 |2 openaire  |e Política editorial 
504 |a Faraday, M., Experimental Researches in Electricity, p. 1848. , Dover Publisher: London, Reprinted 1965 
504 |a Vetter, K.J., (1971) Electrochim. Acta, 16, pp. 1923-1937 
504 |a Ryan, M.P., Toney, M.F., Davenport, A.J., Oblonsky, L.J., (1999) Mater. Res. Bull, 24, pp. 29-35 
504 |a Oblonsky, L.J., Davenport, A.J., Ryan, M.P., Isaacs, H.S., Newman, R.C., (1997) J. Electrochem. Soc, 144, pp. 2398-2404 
504 |a Kuroda, K., Cahan, B.D., Nazri, G., Yeager, E., Mitchell, T.E., (1982) J. Electrochem. Soc, 129, pp. 2163-2169 
504 |a Kruger, J., (1989) Corros. Sci, 29, pp. 149-162 
504 |a Gabrielli, C., Keddam, M., (1982) J. Electrochem. Soc, 129, pp. 2872-2874 
504 |a Davenport, A.J., Oblonsky, L.J., Ryan, M.P., Toney, M.F., (2000) J. Electrochem. Soc, 747, pp. 2162-2173 
504 |a Chin, Y.T., Cahan, B.D., (1992) J. Electrochem. Soc, 139, pp. 2432-2442 
504 |a Chen, C.T., Cahan, B.D., (1981) J. Opt. Soc. Am, 11, pp. 932-934 
504 |a Chen, C.T., Cahan, B.D., (1982) J. Electrochem. Soc, 129, pp. 17-26 
504 |a Cahan, B.D., Chen, C.T., (1982) J. Electrochem. Soc, 129, pp. 474-480 
504 |a Cahan, B.D., Chen, C.T., (1982) J. Electrochem. Soc, 129, pp. 921-925 
504 |a Decher, G., (2003) Multilayer Thin Films, , Decher, G, Schlenoff, B.J, Eds, Wiley-VCH: Weinheim 
504 |a Tagliazucchi, M., Grumelli, D., Bonazzola, C., Calvo, E.J., (2006) J. Nanosci. Nanotechnol, 6, pp. 1731-1740 
504 |a Tagliazucchi, M., Grumelli, D., Calvo, E.J., (2006) Phys. Chem. Chem. Phys, 8, pp. 5086-5095 
504 |a Tagliazucchi, M., Williams, F.J., Calvo, E.J., (2007) J. Phys. Chem. B, 111, pp. 8105-8113 
504 |a Tagliazucchi, M., Calvo, E.J., (2007) J. Electroanal. Chem, 599, pp. 249-259 
504 |a Grumelli, D.E., Garay, R., Barbero, C.A., Calvo, E.J., (2006) J. Phys. Chem. B, 110, pp. 15345-15352 
504 |a Grumelli, D., Bonazzola, C., Calvo, E.J., (2006) Electrochem. Commun, 8, pp. 1353-1357 
504 |a Harris, J.J., DeRose, P.M., Bruening, M.L., (1999) J. Am. Chem. Soc, 121, pp. 1978-1979 
504 |a Dai, J., Sullivan, D.M., Bruening, M.L., (2000) Ind. Eng. Chem. Res, 39, pp. 3528-3535 
504 |a Farhat, T.R., Schlenoff, J.B., (2002) Electrochem. Solid-State Lett, 5, pp. B13-B15 
504 |a Wang, L., Xiao, D., Wang, E., Xu, L., (2005) J. Colloid Interface Sci, 285, pp. 435-442 
504 |a Danilowicz, C., Cottón, E., Battaglini, F., (1998) J. Electroanal. Chem, 445, pp. 89-94 
504 |a Scofield, J.H., (1976) J. Electron Spectrosc. Relat. Phenom, 8, pp. 129-137 
504 |a Azzam, R.M.A., Bashara, N.M., (1977) Ellipsometry and Polarized Light, , North-Holland Publishing Company: Amsterdam 
504 |a Roosendaal, S.J., Giebels, I.A.M.E., Vrendenberg, A.M., Habraken, F.H.P.M., (1998) Surf. Interface Anal, 26, pp. 758-765 
504 |a Mclntyre, N.S., Zetaruk, D.G., (1977) Anal. Chem, 49, pp. 1521-1529 
504 |a Briggs, D., Beamson, G., (1992) High Resolution XPS of Organic Polymers: The Scienta ESCA300 Database, , John Wiley & Sons: New York 
504 |a Calvo, E.J., Schiffrin, D.J., (1988) J. Electroanal. Chem, 243, pp. 171-185 
504 |a Lindberg, B.J., Hamrin, K., Johansson, G., Gelius, U., Fahlman, A., Nordling, C., Siegbahn, K., (1970) Phys. Sci, 1, pp. 286-298 
504 |a Lourenco, J.M.C, Ribeiro, P.A, Botelho do Rego; A.M.; Braz Fernandes, F.M.; Moutinho, A.M.C.; Ra- poso, M. Langmuir. 2004, 20, 8103-8109; Cohen, M.R., Merrill, R.P., (1991) Surf. Sci, 245, pp. 1-11 
504 |a Chen, C.T., Cahan, B.D., Yeager, E., Passivation Studies of Iron (1979) Nickel and their Alloys by In Situ Ellipsom- etry and Ex Situ ESCA Techniques-Technical Report, pp. 112-113. , 48; Case Western Reserve University: Cleveland, OH 
504 |a Forzani, E.S., Otero, M., Perez, M.A., Lopez Teijelo, M., Calvo, E.J., (2002) Langmuir, 18, pp. 4020-4029 
504 |a Forzani, E.S., Perez, M.A., Lopez Teijelo, M., Calvo, E.J., (2002) Langmuir, 18, pp. 9867-9873 
504 |a Tognalli, N., Fainstein, A., (2006), Personal communication; Laviron, E., (1979) J. Electroanal. Chem, 100, pp. 263-270 
504 |a Laviron, E., (1980) J. Electroanal. Chem, 112, pp. 1-9 
504 |a Ricci, A., Rolli, C., Rothacher, S., Baraldo, L., Bonazzola, C., Calvo, E.J., Tognalli, N., Fainstein, A., (2007) J. Solid State Electrochem, 11, pp. 1511-1520 
504 |a Olmedo, A.M.T., Pereiro, R., Schiffrin, D.J., (1976) J. Electroanal. Chem, 74, pp. 19-36 
504 |a Díez-Pérez, I., Sanz, E., Gorostiza, P., (2006) Electrochem. Commun, 8, pp. 1595-1602 
504 |a Díez-Pérez, I., Giiell, A., Sanz, E., Gorostiza, P., (2006) Anal. Chem, 78, pp. 7325-7329 
504 |a Stimming, U., Schultze, J.W., (1976) Ber. Bunsenges. Phys. Chem, 80, pp. 1297-1302 
504 |a Stimming, U., Schultze, J.W., (1977) Ber. Bunsenges. Phys. Chem, 81, pp. 1116-1117 
504 |a Stimming, U., Schultze, J.W., (1979) Electrochim. Acta, 24, pp. 859-869 
504 |a Schultze, J.W., Stimming, U., (1975) Zeit. Phys. Chem. Frankfurt, 98, pp. 285-302 
520 3 |a Steel samples were passivated in 0.1 M NaOH solutions at 0.3 V vs. Ag/AgCl (3 M KC1) and then poly(allylamine) derivatized with osmium pyridine- bipyridine-chloride complex and poly-(vinylsulfonate) were sequentially self-assembled electrostatically layer-by-layer. The resulting electrodes were examined by cyclic voltammetry, ellipsometry, and X-ray Photoelectron Spectroscopy (XPS). These studies demonstrate the formation of a redox polyelectrolyte multilayer onto the passive film protecting the ferrous metal. As the number of deposited polyelectrolyte layers increases there is an increase in the measured thickness of the self-assembled film. The rate of thickness growth in osmium polymer film with the number of deposition cycles is slower for films thinner than ~30 nm. Cyclic voltammetry shows that the electron transfer rate to the outer sphere osmium complex tethered to the polymer backbone is much slower for the multilayer on passive iron than on gold surfaces. This is in agreement with the well-known behavior of soluble redox couples on passive metals and with electrochemical tunelling spectroscopy.  |l eng 
593 |a Departamento de Química Inorgdnica, Analítica y Quimica Física, Universidad de Buenos Aires, C1428EHA Buenos Aires, Argentina 
593 |a Departmento de Quimica de Superficies y Recubirmientos, Tenaris Siderca, Simini 250, Campana, Buenos Aires B2804MHA, Argentina 
700 1 |a Calvo, E.J. 
700 1 |a Williams, F.J. 
773 0 |d 2008  |g v. 48  |h pp. 305-312  |k n. 3-4  |p Isr. J. Chem.  |x 00212148  |w (AR-BaUEN)CENRE-985  |t Israel Journal of Chemistry 
856 4 1 |u https://www.scopus.com/inward/record.uri?eid=2-s2.0-59449106470&doi=10.1560%2fIJC.48.3-4.305&partnerID=40&md5=b0f11d1cb0ef5237024bd2dff1282291  |y Registro en Scopus 
856 4 0 |u https://doi.org/10.1560/IJC.48.3-4.305  |y DOI 
856 4 0 |u https://hdl.handle.net/20.500.12110/paper_00212148_v48_n3-4_p305_Volker  |y Handle 
856 4 0 |u https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_00212148_v48_n3-4_p305_Volker  |y Registro en la Biblioteca Digital 
961 |a paper_00212148_v48_n3-4_p305_Volker  |b paper  |c PE 
962 |a info:eu-repo/semantics/article  |a info:ar-repo/semantics/artículo  |b info:eu-repo/semantics/publishedVersion 
999 |c 83208 

Ejemplares similares