Bioactive constituents of Conyza albida

The bioactivity-guided fractionation of an active chloroform extract of Conyza albida led to the isolation of three alkenynes, deca-4,6-diyn-2-(Z)-enoic methyl ester (1), deca-4,6-diyn-2-(Z)-enoic ethyl ester (2) and deca-2,4-diene-4-hydroxy-6-yn-l,4-olide (3), and the terpenoid spathulenol (4), as...

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Autor principal: Del Pacciaroni, A.V
Otros Autores: Mongelli, E., Espinar, L.A, Romano, A., Ciccia, G., Silva, G.L
Formato: Capítulo de libro
Lenguaje:Inglés
Publicado: 2000
Acceso en línea:Registro en Scopus
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Registro en la Biblioteca Digital
Aporte de:Registro referencial: Solicitar el recurso aquí
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024 7 |2 scopus  |a 2-s2.0-0034518963 
024 7 |2 pubmed  |a 11199128 
024 7 |2 cas  |a DNA, 9007-49-2; DNA topoisomerase, 80449-01-0; chloroform, 67-66-3; methyl green, 54327-10-5; spathulenol, 6750-60-3; Plant Extracts 
040 |a Scopus  |b spa  |c AR-BaUEN  |d AR-BaUEN 
030 |a PLMEA 
100 1 |a Del Pacciaroni, A.V. 
245 1 0 |a Bioactive constituents of Conyza albida 
260 |c 2000 
270 1 0 |m Silva, G.L.; Departamento de Química Org., Fac. de Ciencias Quím. U.N.C., IMBIV-CONICET, Ciudad Universitaria, 5000 Córdoba, Argentina; email: silvagl@dqo.fcq.unc.edu.ar 
506 |2 openaire  |e Política editorial 
504 |a Ariza Espinar, L., Conyza albida (Compositae) en Argentina (1982) Boletín de la Sociedad Argentina de Botánica, 21, pp. 269-271 
504 |a Marzocca, A., Conyza bonariensis (1997) Vademécum de Malezas Medicinales de la Argentina, Indígenas y Exóticas, p. 259. , Editorial Hemisferio Sur, Buenos Aires, Argentina: 
504 |a González, A., Ferreira, F., Vázquez, A., Moyna, P., Alonso Paz, E., Biological screening of Uruguayan medicinal plants (1993) Journal of Ethnopharmacology, 39, pp. 217-220 
504 |a Gutierrez-Lugo, M.T., Barrientos-Benitez, T., Luna, B., Ramirez-Gamma, R.M., Bye, R., Linares, E., Mata, R., Antimicrobial and cytotoxic activities of some crude drug extracts from Mexican medicinal plants (1996) Phytomedicine, 2, pp. 341-347 
504 |a Al-Yahya, M.A., Mossa, J.S., Al-Meshal, I.A., Antoun, M.D., Mc Cloud, T.G., Cassady, J.M., Jacobsen, L.B., McLaughlin, J.L., Phytochemical and biological studies on Saudi medicinal plants part 9. Antitumor testing (1985) International Journal of Crude Drug Research, 23, pp. 45-66 
504 |a Anderberg, A.A., Taxonomy and phylogeny of the tribe Plucheeae (Asteraceae) (1991) Plant Systematic Evolution, 176, pp. 145-177 
504 |a Bohlmann, F., Jakupovic, J., 8-Oxo-α-selinen und neue Scopoletin-derivative aus Conyza-arten (1979) Phytochemistry, 18, pp. 1367-1370 
504 |a Sanz, J.F., Marco, J.A., Ein neues Butenolid aus Conyza bonariensis (1991) Liebigs Annalen Chemie, pp. 399-400 
504 |a Krebs, H.C., Rakotoarimanga, J.V., Habermehl, G.C., Isolation of spathulenol and (-)-caryophyllene oxide from Vernonia mollissima Don and 1H and 13C reassignment by two-dimensional NMR spectroscopy (1990) Magnetic Resonance in Chemistry, 28, pp. 124-128 
504 |a Mongelli, E., Romano, A., Desmarchelier, C., Coussio, J., Ciccia, G., Cytotoxic 4-nerolidylcatechol from Pothomorphe peltata inhibits topoisomerase 1 activity (1999) Planta Medica, 65, pp. 376-378 
504 |a McLaughlin, J., Methods in Plant Biochemistry. Crown gall tumors on potato discs and brine shrimp lethality: Two bioassays for higher plant screening and fractionation (1991), pp. 1-32. , Harborne JB, editor. Academic Press, New York:Sugiyama, H., Ehrenfeld, G.N., Shipley, J.B., Kilkuskie, R.E., Chang, L.H., Hecht, S.M., DNA strand scission by bleomycin group antibiotics (1985) Journal of Natural Products, 48, pp. 869-877 
504 |a Carpita, A., Neri, D., Rossi, R., Stereocontrolled synthesis of naturally-occurring poliacetylenes characterized by (E)-1-en-3-yne, (E)-1-en-3,5-diyne, (1E,5E)-1,5-dien-3-yne, and (1E,7E)-1,7-dien-3,5-diyne moieties (1987) Gazzetta Chimica Italiana, 117, pp. 481-497 
504 |a Miyazawa, M., Yamamoto, K., Kameoka, H., The essential oil of Erigeron canadensis (1992) Journal of Essential Oil Research, 4, pp. 227-230 
504 |a Köning, G., Wright, A., Sticher, O., Angerhofer, C., Pezzuto, J., Biological activities of selected marine natural products (1994) Planta Medica, 60, pp. 532-537 
504 |a Fullas, F., Hussain, R.A., Chai, H.B., Pezzuto, J.M., Soejarto, D.D., Kinghorn, A.D., Cytotoic constituents of Baccharis gaudichaudiana (1994) Journal of Natural Products, 57, pp. 801-807 
504 |a Bonjean, K., De Pauw-Gillet, M., Bassleer, R., Quentin-Leclercq, J., Angenot, L., Wright, A., Cytotoxic activities of Colombian plant extracts on Chinense hamster lung fibroblasts (1996) Phytotherapy Research, 10, pp. 159-160 
504 |a Suffness, M., Pezzuto, J., Methods in Plant Biochemistry. Assays related to cancer drug discovery (1991), pp. 71-133. , Harborne JB, editor. Academic Press, New York:Liu, L.F., DNA Topoisomerase poisons as antitumor drugs (1989) Annual Review of Biochemistry, 58, pp. 351-375 
504 |a Jung, J.H., Kim, Y., Lee, C.O., Kang, S.S., Park, J.H., Im, K.S., Cytotoxic constituents of Saussurea lappa (1998) Archives of Pharmaceutical Research, 21, pp. 153-156 
504 |a Takaishi, Y., Okuyama, T., Masuda, A., Nakano, K., Murakami, K., Tomimatsu, T., Acetylenes from Cirsium japonicum (1990) Phytochemistry, 29, pp. 3849-3852 
520 3 |a The bioactivity-guided fractionation of an active chloroform extract of Conyza albida led to the isolation of three alkenynes, deca-4,6-diyn-2-(Z)-enoic methyl ester (1), deca-4,6-diyn-2-(Z)-enoic ethyl ester (2) and deca-2,4-diene-4-hydroxy-6-yn-l,4-olide (3), and the terpenoid spathulenol (4), as the active toxic metabolites in the Artemia sp. lethality test. When tested in the KB cell cytotoxicity assay, compounds 1-4 demonstrated 1C 50 values of 52.2, 38.4, 117.9, and 83.8 μM, respectively. All compounds studied were inactive in the DNA methyl green and DNA strand scission assays, while compounds 3 and 4 showed moderate activity as inhibitors of human topoisomerase I. Compound 2 is reported here for the first time.  |l eng 
593 |a Departamento de Química Orgánica, Facultad de Ciencias Quím. U.N.C., IMBIV-CONICET, Pabellón de Ciencias II, Ciudad Universitaria, 5000 Córdoba, Argentina 
593 |a Cátedra de Microbiología Industrial y Biotecnología, IQUIMEFA-CONICET, Facultad de Farmacia y Bioquímica, Universidad de Buenos Aires, Argentina 
593 |a Cátedra de Farmacognosia, IQUIMEFA-CONICET, Facultad de Farmacia y Bioquímica, Universidad de Buenos Aires, Argentina 
690 1 0 |a ALKENYNES 
690 1 0 |a COMPOSITAE 
690 1 0 |a CONYZA ALBIDA 
690 1 0 |a CYTOTOXIC ACTIVITY 
690 1 0 |a DNA INTERACTION 
690 1 0 |a DNA STRAND SCISSION 
690 1 0 |a TOPOISOMERASE 1 
690 1 0 |a CHLOROFORM 
690 1 0 |a DECA 2,4 DIENE 4 HYDROXY 6 YN 1,4 OLIDE 
690 1 0 |a DECA 4,6 DIYN 2 ENOIC ETHYL ESTER 
690 1 0 |a DECA 4,6 DIYN 2 ENOIC METHYL ESTER 
690 1 0 |a DNA 
690 1 0 |a DNA TOPOISOMERASE 
690 1 0 |a METHYL GREEN 
690 1 0 |a PLANT EXTRACT 
690 1 0 |a SPATHULENOL 
690 1 0 |a UNCLASSIFIED DRUG 
690 1 0 |a ANIMAL EXPERIMENT 
690 1 0 |a ARTICLE 
690 1 0 |a CONTROLLED STUDY 
690 1 0 |a CYTOTOXICITY 
690 1 0 |a DRUG ACTIVITY 
690 1 0 |a FRACTIONATION 
690 1 0 |a HUMAN 
690 1 0 |a HUMAN CELL 
690 1 0 |a MEDICINAL PLANT 
690 1 0 |a NONHUMAN 
690 1 0 |a PLANT LEAF 
690 1 0 |a SHRIMP 
690 1 0 |a ASTERACEAE 
690 1 0 |a HUMANS 
690 1 0 |a MOLECULAR STRUCTURE 
690 1 0 |a PLANT EXTRACTS 
690 1 0 |a SPECTRUM ANALYSIS 
700 1 |a Mongelli, E. 
700 1 |a Espinar, L.A. 
700 1 |a Romano, A. 
700 1 |a Ciccia, G. 
700 1 |a Silva, G.L. 
773 0 |d 2000  |g v. 66  |h pp. 720-723  |k n. 8  |p Planta Med.  |x 00320943  |t Planta Medica 
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856 4 0 |u https://doi.org/10.1055/s-2000-9600  |y DOI 
856 4 0 |u https://hdl.handle.net/20.500.12110/paper_00320943_v66_n8_p720_DelPacciaroni  |y Handle 
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