Characterization of two new copper(II) complexes with saccharinate and benzimidazole as ligands

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The crystal structure of the complexes [Cu(sac)2-(bzim)2(H2O)] (1) and [Cu(sac)2(bzim)(H2O)(EtOH)] · 2 EtOH (2) (sac = saccharinate anion; bzim = benzimidazole; EtOH = ethanol) was determined by single crystal X-ray diffractometry. Complex 1 crystallizes in the monoclinic C2/c space group with Z = 8...

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Autor principal: Williams, P.A.M
Otros Autores: Ferrer, E.G, Pasquevich, K.A, Baran, Enrique José, Chaia, Z., Castellano, Eduardo Ernesto, Piro, Oscar Enrique
Formato: Capítulo de libro
Lenguaje:Alemán
Publicado: Wiley-VCH Verlag 2000
Acceso en línea:Registro en Scopus
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100 1 |a Williams, P.A.M. 
245 1 0 |a Characterization of two new copper(II) complexes with saccharinate and benzimidazole as ligands 
246 3 1 |a Charakterisierung von zwei neuen kupfer(II)-Komplexen mit saccharinat und benzimidazol als liganden 
260 |b Wiley-VCH Verlag  |c 2000 
270 1 0 |m Baran, E.J.; CEQUINOR, Facultad de Ciencias Exactas, UNLP, C. Correo 962, 1900-La Plata, Argentina; email: baran@quimica.unlp.edu.ar 
504 |a Haider, S.Z., Malik, K.M.A., Ahmed, K.J., Hess, H., Riffel, H., Hursthouse, M.B., (1983) Inorg. Chim. Acta, 72, p. 21 
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504 |a Jovansovski, G., Kamenar, B., (1982) Cryst. Struct. Comm., 11, p. 247 
504 |a Malik, K.M.A., Haider, S.Z., Hossain, M.A., (1984) Acta. Crystallogr., C 40, p. 1696 
504 |a Cotton, F.A., Falvello, L.R., Schwotzer, W., Murillo, C.A., Valle-Bourret, G., (1991) Inorg. Chim. Acta, 790, p. 89 
504 |a Jovanovski, G., Hergold-Brundic, A., Kamenar, B., (1988) Acta Crystallogr., C 44, p. 63 
504 |a Weber, R., Gilles, M., Bergerhoff, G., (1993) Z. Kristallogr., 206, p. 273 
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504 |a Baran, E.J., Wagner, C.C., Rossi, M., Caruso, F., (2000) Z. Anorg. Allg. Chem., 626, p. 701 
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504 |a Hergold-Brundic, A., Grupce, O., Jovanovski, G., (1991) Acta Crystallogr., C 47, p. 2659 
504 |a Liu, S.X., Huang, J.L., Li, J.M., Lin, W.B., (1991) Acta Crystallogr., C 47, p. 41 
504 |a Johnson, C.K., (1965) ORTEP, Report ORNL-3794, , Oak Ridge Natl. Laboratory, TN., USA 
504 |a Baran, E.J., Williams, P.A.M., Sáez-Puche, R., Soria, J., (1990) Polyhedron, 9, p. 1383 
504 |a Lever, A.B.P., (1984) Inorganic Electronic Spectroscopy, 2nd Edit., , Elsevier, Amsterdam 
504 |a Kahn, O., (1993) Molecular Magnetism, , VCH Publishers Inc., New York 
504 |a Suwaiyan, A., Zwarich, R., Baig, N., (1990) J. Roman Spectr., 27, p. 243 
504 |a Lin-Vien, D., Colthup, N.B., Fately, W.G., Grasselli, J.G., (1991) The Handbook of Infrared and Raman Characteristic Frequencies of Organic Molecules, , Academic Press, New York 
504 |a Nakamoto, K., (1997) Infrared and Raman Spectra of Inorganic and Coordination Compounds, Part B, 5th Edit, , J. Wiley, New York 
504 |a Adams, D.M., (1966) Metal-Ligand and Related Vibrations, , Edward Arnold, London 
504 |a Içbudak, H., Yilmaz, V.T., Ölmez, H., (1998) J. Thermal Anal., 55, p. 843 
504 |a Haider, S.Z., Malik, K.M.A., Ahmed, K.J., (1951) J. Bangladesh Acad. Sci., 5, p. 81 
504 |a Haider, S.Z., Malik, K.M.A., Ahmed, K.J., (1985) Inorg. Synth., 23, p. 47 
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504 |a Walker, N., Stuart, D., (1983) Acta Crystallogr., A 39, p. 158 
504 |a Harm, K., Wocadlo, S., (1995) XCAD-4, Program for Processing CAD-4 Diffractometer Data, , University of Marburg, Germany 
504 |a Sheldrick, G.M., (1997) SHELX-97. Program for Crystal Structure Resolution, , University of Göttingen, Germany 
506 |2 openaire  |e Política editorial 
520 3 |a The crystal structure of the complexes [Cu(sac)2-(bzim)2(H2O)] (1) and [Cu(sac)2(bzim)(H2O)(EtOH)] · 2 EtOH (2) (sac = saccharinate anion; bzim = benzimidazole; EtOH = ethanol) was determined by single crystal X-ray diffractometry. Complex 1 crystallizes in the monoclinic C2/c space group with Z = 8 whereas complex 2 belongs to the triclinic P1̄ space group with Z = 2. Room temperature magnetic susceptibilities as well as electronic and IR spectra of both complexes were discussed. Their thermal behaviour was investigated by means of TG and DTA methods.  |l eng 
593 |a CEQUINOR, Facultad de Ciencias Exactas, UNLP, C. Correo 962, 1900-La Plata, Argentina 
593 |a CEQUINOR (CONICET, UNLP), Facultad de Ciencias Exactas, Universidad Nacional de La Plata, La Plata, Argentina 
593 |a Fac. de Ciencias Exactas y Naturales, Universidad de Buenos Aires, Buenos Aires, Argentina 
593 |a Inst. de Fisica de Säo Carlos, Universidade de Säo Paulo, Säo Carlos, Brazil 
593 |a Depto. de Fisica and IFLP (CONICET), Faculdad de Ciencias Exactas, Universidad Nacional de La Plata, La Plata, Argentina 
690 1 0 |a BENZIMIDAZOLE 
690 1 0 |a COPPER(II) 
690 1 0 |a CRYSTAL STRUCTURES 
690 1 0 |a ELECTRONIC SPECTRA 
690 1 0 |a IR-SPECTRA 
690 1 0 |a SACCHARINATE 
690 1 0 |a THERMAL BEHAVIOUR 
700 1 |a Ferrer, E.G. 
700 1 |a Pasquevich, K.A. 
700 1 |a Baran, Enrique José 
700 1 |a Chaia, Z. 
700 1 |a Castellano, Eduardo Ernesto 
700 1 |a Piro, Oscar Enrique 
773 0 |d Wiley-VCH Verlag, 2000  |g v. 626  |h pp. 2509-2514  |k n. 12  |p Z. Anorg. Allg. Chem.  |x 00442313  |w (AR-BaUEN)CENRE-9793  |t Zeitschrift fur Anorganische und Allgemeine Chemie 
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