Hydrogenation of carbonylic compounds on Pt/SiO2 catalysts modified with SnBu4

Silica supported bimetallic and organobimetallic PtSn catalysts were prepared by Surface Organometallic Chemistry on Metals and tested in the hydrogenation of different carbonylic compounds (butanal, butanone, cyclohexanone, benzaldehyde, crotonaldehyde and cinnamaldehyde). It was studied the influe...

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Detalles Bibliográficos
Autor principal: Santori, G.F
Otros Autores: Casella, M.L, Siri, G.J, Ferretti, O.A, Moglioni, A., Iglesias, G.M
Formato: Capítulo de libro
Lenguaje:Inglés
Publicado: Elsevier Inc. 2000
Acceso en línea:Registro en Scopus
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Registro en la Biblioteca Digital
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024 7 |2 scopus  |a 2-s2.0-0034589985 
024 7 |2 cas  |a 2 butanone, 78-93-3; benzaldehyde, 100-52-7; butyraldehyde, 123-72-8; cinnamaldehyde, 104-55-2; crotonaldehyde, 4170-30-3; cyclohexanone, 108-94-1; platinum, 7440-06-4; silicon dioxide, 10279-57-9, 14464-46-1, 14808-60-7, 15468-32-3, 60676-86-0, 7631-86-9 
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100 1 |a Santori, G.F. 
245 1 0 |a Hydrogenation of carbonylic compounds on Pt/SiO2 catalysts modified with SnBu4 
260 |b Elsevier Inc.  |c 2000 
270 1 0 |m Santori, G.F.; CINDECA (UNLP-CONICET), 47 No 257, (1900) La Plata, Argentina 
506 |2 openaire  |e Política editorial 
504 |a Ponec, V., (1997) Appl. Catal. A: Gen., 149, p. 27 
504 |a Poltarzewski, Z., Galvagno, S., Pietropaolo, R., Staiti, P., (1986) J. Catal., 102, p. 190 
504 |a Margitfalvi, J., Hegedüs, M., Göbölös, S., Kern-Tálas, E., Szedlacsek, P., Szabó, S., Nagy, S., (1984) Proc.8th Int. Congr. on Catal., 4, p. 903. , Berlin, Verlag-Chemie 
504 |a Ferretti, O.A., Bettega De Pauli, L., Candy, J.P., Mabilon, G., Bournonville, J.P., (1987) Stud. Surf. Sci. Catal., 31, p. 713 
504 |a Didillon, B., Candy, J.P., Lepeltier, F., Ferretti, O.A., Basset, J.M., (1993) Stud. Surf. Sci. Catal., 78, p. 205 
504 |a Santori, G., Casella, M., Siri, G., Ferretti, O., (1998) Proc. XVI Simp. Iberoam. Catal., 2, p. 597. , A. Centeno et al. Eds 
504 |a Santori, G., Casella, M., Siri, G., Aduriz, H., Ferretti, O., Appl. Catal. A: Gen., , in press 
504 |a Gallezot, P., Giroir-Fendler, A., Richard, D., (1990) Catal. Lett., 5, p. 169 
520 3 |a Silica supported bimetallic and organobimetallic PtSn catalysts were prepared by Surface Organometallic Chemistry on Metals and tested in the hydrogenation of different carbonylic compounds (butanal, butanone, cyclohexanone, benzaldehyde, crotonaldehyde and cinnamaldehyde). It was studied the influence of the Sn/Pt atomic ratio on the hydrogenation of cinnamaldehyde, having been found an optimum of approximately 0.4. The selective hydrogenation of C=O group in polyfunctional molecules can be explained on the basis of the combination of geometric (specially in organobimetallic catalysts), and electronic effects due to the presence of ionic tin. © 2000 Elsevier Science B.V. All rights reserved.  |l eng 
593 |a CINDECA (UNLP-CONICET), 47 No 257, (1900) La Plata, Argentina 
593 |a Facultad de Ingeniería, UNLP, 47 No 257, (1900) La Plata, Argentina 
593 |a Departamento de Química Orgánica, UBA, Junín 954, (1113) Buenos Aires, Argentina 
690 1 0 |a 2 BUTANONE 
690 1 0 |a BENZALDEHYDE 
690 1 0 |a BUTYRALDEHYDE 
690 1 0 |a CARBONYL DERIVATIVE 
690 1 0 |a CINNAMALDEHYDE 
690 1 0 |a CROTONALDEHYDE 
690 1 0 |a CYCLOHEXANONE 
690 1 0 |a METAL 
690 1 0 |a ORGANOMETALLIC COMPOUND 
690 1 0 |a PLATINUM 
690 1 0 |a SILICON DIOXIDE 
690 1 0 |a TIN DERIVATIVE 
690 1 0 |a CATALYSIS 
690 1 0 |a CATALYST 
690 1 0 |a CHEMICAL REACTION 
690 1 0 |a CONFERENCE PAPER 
690 1 0 |a GAS CHROMATOGRAPHY 
690 1 0 |a HYDROGENATION 
690 1 0 |a REACTION ANALYSIS 
690 1 0 |a TEMPERATURE 
700 1 |a Casella, M.L. 
700 1 |a Siri, G.J. 
700 1 |a Ferretti, O.A. 
700 1 |a Moglioni, A. 
700 1 |a Iglesias, G.M. 
773 0 |d Elsevier Inc., 2000  |g v. 130 C  |h pp. 2063-2068  |p Stud. Surf. Sci. Catal.  |x 01672991  |t Studies in Surface Science and Catalysis 
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856 4 0 |u https://hdl.handle.net/20.500.12110/paper_01672991_v130C_n_p2063_Santori  |y Handle 
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