Synthesis and characterization of some heterocyclic derivatives by cyclization of carbohydrate thiosemicarbazone - Part III

Synthesis of (3′R) 2-acetamido-4-N-acetyl-3′-spiro-[1′,2′:5′,6′- di-O-isopropylidene-α-D-glucofuranosyl]1,3,4-thiadiazoline diastereomerically pure is described. We report the physical and spectroscopic characterization of the new heterocyclic compound as well as its immediate precursors. We discuss...

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Detalles Bibliográficos
Autor principal: Martins Alho, M.A
Otros Autores: D' Accorso, N.B
Formato: Capítulo de libro
Lenguaje:Inglés
Publicado: 2002
Acceso en línea:Registro en Scopus
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Registro en la Biblioteca Digital
Aporte de:Registro referencial: Solicitar el recurso aquí
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100 1 |a Martins Alho, M.A. 
245 1 0 |a Synthesis and characterization of some heterocyclic derivatives by cyclization of carbohydrate thiosemicarbazone - Part III 
260 |c 2002 
270 1 0 |m Martins Alho, M.A.; Fac. de Ciencias Exactas/Naturales, Universidad de Buenos Aires, Ciudad Universitaria, C. P. 1428, Buenos Aires, Argentina 
506 |2 openaire  |e Política editorial 
504 |a Martins Alho, M.A., D'Accorso, N.B., (1997) J. Heterocyclic Chem., 34, p. 1415 
504 |a Martins Alho, M.A., D'Accorso, N.B., (2000) J. Heterocyclic Chem., 37, p. 811 
504 |a Onodera, K., Kashimura, N., (1972) Methods in Carbohydrate Chemistry, 6, p. 334. , R. L. Whistler and J. N. BeMiller, ed, Academic Press, New York and London 
504 |a Karabatsos, G.J., Taller, R.A., (1968) Tetrahedron, 24, p. 3347 
504 |a Tronchet, J.M.J., Gentile, B., (1976) Helvetica Chim. Acta., 54, p. 1380 
504 |a Rosenthal, A., Ong, K.S., Baker, D., (1970) Carbohydr. Res., 13, p. 113 
504 |a Tronchet, J.M.J., Neeser, J.R., Charollais, E.J., González, L., (1983) J. Carbohydrate Chem., 2, p. 19 
504 |a Martins Alho, M.A., D'Accorso, N.B., (2000) Carbohydr. Res., 328, p. 481 
520 3 |a Synthesis of (3′R) 2-acetamido-4-N-acetyl-3′-spiro-[1′,2′:5′,6′- di-O-isopropylidene-α-D-glucofuranosyl]1,3,4-thiadiazoline diastereomerically pure is described. We report the physical and spectroscopic characterization of the new heterocyclic compound as well as its immediate precursors. We discuss also the possibilities for cyclization and established the stereochemistry of the new stereogenic center.  |l eng 
593 |a Fac. de Ciencias Exactas/Naturales, Universidad de Buenos Aires, Ciudad Universitaria, C. P. 1428, Buenos Aires, Argentina 
690 1 0 |a 2 ACETAMIDO 4 N ACETYL 3' SPIRO[1',2':5',6' DI O ISOPROPYLIDENE ALPHA DEXTRO GLUCOFURANOSYL] 1,3,4 THIADIAZOLINE 
690 1 0 |a CARBOHYDRATE 
690 1 0 |a HETEROCYCLIC COMPOUND 
690 1 0 |a THIOSEMICARBAZONE DERIVATIVE 
690 1 0 |a UNCLASSIFIED DRUG 
690 1 0 |a ARTICLE 
690 1 0 |a CARBON NUCLEAR MAGNETIC RESONANCE 
690 1 0 |a CHEMICAL STRUCTURE 
690 1 0 |a CHIRALITY 
690 1 0 |a CYCLIZATION 
690 1 0 |a DIASTEREOISOMER 
690 1 0 |a ISOMERISM 
690 1 0 |a NUCLEAR OVERHAUSER EFFECT 
690 1 0 |a PROTON NUCLEAR MAGNETIC RESONANCE 
690 1 0 |a SPECTROSCOPY 
690 1 0 |a STEREOCHEMISTRY 
690 1 0 |a SYNTHESIS 
700 1 |a D' Accorso, N.B. 
773 0 |d 2002  |g v. 39  |h pp. 137-140  |k n. 1  |p J. Heterocycl. Chem.  |x 0022152X  |w (AR-BaUEN)CENRE-780  |t Journal of Heterocyclic Chemistry 
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