Solubility of I2(S) and equilibrium concentration of the (I2 + C6H6) charge transfer complex in supercritical xenon with added C6H6

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The solubility of I2(S) in supercritical xenon with and without added C6H6 has been measured at the temperatures T = (300.79 ± 0.04) K and (318.70 ± 0.02) K over the pressure range from 5MPa to 10MPa. The u.v. absorbance due to the charge transfer interaction between I2 (acceptor) and C6H6 (donor) w...

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Autor principal: Destaillats, H.
Otros Autores: Fernández-Prini, R.
Formato: Capítulo de libro
Lenguaje:Inglés
Publicado: Academic Press 1997
Acceso en línea:Registro en Scopus
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100 1 |a Destaillats, H. 
245 1 0 |a Solubility of I2(S) and equilibrium concentration of the (I2 + C6H6) charge transfer complex in supercritical xenon with added C6H6 
260 |b Academic Press  |c 1997 
270 1 0 |m Fernández-Prini, R.; Inst. de Quim. Fis. de Materiales, Ambiente y Energía, Ciudad Universitaria Pabelleon II, 1428-Capital Federal, Argentina; email: rfprini@cnea.edu.ar 
506 |2 openaire  |e Política editorial 
504 |a Carlier, C., Randolph, T.W., (1993) AIChE J., 39, pp. 876-884 
504 |a Fernández-Prini, R., Japas, M.L., (1994) Chem. Soc. Rev., 23, pp. 155-163 
504 |a Bennet, G.E., Rossky, P.J., Johnston, K.P., (1995) J. Phys. Chem., 99, pp. 16136-16143 
504 |a Fernández-Prini, R., (1995) Pure Appl. Chem., 67, pp. 519-526 
504 |a Fernández-Prini, R., (1996) The Role of Chemistry in the Preservation of the Environment, p. 26. , Workshop NSF-CONICET: Buenos Aires 
504 |a Fernádez, D.P., Fernández-Prini, R., (1992) J. Chem. Thermodynamics, 24, pp. 377-386 
504 |a Marceca, E., Fernández-Prini, R., (1993) J. Chem. Thermodynamics, 25, pp. 237-247 
504 |a Marceca, E., Fernández-Prini, R., (1994) J. Chem. Thermodynamics, 26, pp. 651-661 
504 |a Gutkowski, K., Japas, M.L., Fernández-Prini, R., (1997) J. Chem. Thermodynamics, 29, pp. 1077-1086 
504 |a Stewart, R.B., Jacobsen, R.T., (1989) J. Phys. Chem. Ref. Data, 18, pp. 639-656 
504 |a Habgood, H.W., Schneider, W.G., (1954) Can. J. Chem., 32, pp. 98-111 
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504 |a Lide, D.R., (1995) Handbook of Chemistry and Physics (75th Edition), pp. 3-208. , CRC Press 
504 |a Tamres, M., Duerksen, W.K., Goodenow, J.M., (1968) J. Phys. Chem., 72, pp. 966-970 
504 |a Passchier, A.A., Gregory, N.W., (1968) J. Phys. Chem., 72, pp. 2697-2702 
504 |a Fernández, D.P., (1991), Thesis, Universidad de Buenos Aires; Lang, F.T., Strong, R.L., (1965) J. Am. Chem. Soc., 87, pp. 2345-2349 
504 |a Benesi, H.A., Hildebrand, J.H., (1949) J. Am. Chem. Soc., 71, pp. 2703-2708 
504 |a Tamres, M., Virzi, D., Searles, S., (1953) J. Am. Chem. Soc., 75, pp. 4358-4363 
504 |a Denten, Y., Guillot, B., Guissani, Y., (1992) J. Chem. Phys., 96, pp. 3782-3794 
504 |a Orgel, L.E., Mulliken, R.S., (1957) J. Am. Chem. Soc., 79, pp. 4839-4846 
504 |a Tamres, M., (1973) Molecular Complexes, 1, pp. 49-116 
504 |a Guggenheim, E.A., (1960) Trans. Faraday Soc., 56, pp. 1159-1164 
504 |a Prue, J.E., (1965) J. Chem. Soc., pp. 7534-7535 
504 |a Fernández-Prini, R., Japas, M.L., (1992) J. Phys. Chem., 96, pp. 5115-5121 
520 3 |a The solubility of I2(S) in supercritical xenon with and without added C6H6 has been measured at the temperatures T = (300.79 ± 0.04) K and (318.70 ± 0.02) K over the pressure range from 5MPa to 10MPa. The u.v. absorbance due to the charge transfer interaction between I2 (acceptor) and C6H6 (donor) was also measured when the fluid was saturated, and also when unsaturated, with I2. The enhancement of the solubility of I2(s) due to added C6H6 was moderate, supporting the view that the charge transfer process does not contribute significantly to the thermodynamic properties of donor and acceptor. The effect of density on the equilibrium concentration quotient for the formation of the donor-acceptor complex is discussed. © 1997 Academic Press Limited.  |l eng 
536 |a Detalles de la financiación: Secretaría de Ciencia y Técnica, Universidad de Buenos Aires 
536 |a Detalles de la financiación: Thanks are given to the Universidad de Buenos Aires UBACyT) and CONICET for partial economic support. H.D. is grateful to UBACyT for a research fellowship. 
593 |a Inst. de Quim. Fis. de Materiales, Ambiente y Energía, Universidad de Buenos Aires, 1428-Capital Federal, Argentina 
593 |a Inst. de Quim. Fis. de Materiales, Ambiente y Energía, Ciudad Universitaria Pabelleon II, 1428-Capital Federal, Argentina 
593 |a Unidad de Activadad Química, Comn. Nac. de Ener. Atómica, Av. Liberador 8350, 1429-Capital Federal, Argentina 
690 1 0 |a CHARGE TRANSFER 
690 1 0 |a IODINE 
690 1 0 |a SOLUBILITY 
690 1 0 |a SUPERCRITICAL FLUID 
700 1 |a Fernández-Prini, R. 
773 0 |d Academic Press, 1997  |g v. 29  |h pp. 1209-1221  |k n. 11  |p J Chem Thermodyn  |x 00219614  |w (AR-BaUEN)CENRE-575  |t Journal of Chemical Thermodynamics 
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