Conversion of benzaldehyde into benzyl benzoate from the reaction with lithium metal in hexane
The reaction of benzaldehyde with lithium metal was studied in two solvents and several temperatures as a model for more complex processes. Conditions were achieved to favor the adsorption of reactant on the metal surface, as wed as to slow down diffusion of the reactive species to solution: reactio...
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| Formato: | Capítulo de libro |
| Lenguaje: | Inglés |
| Publicado: |
1997
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| Acceso en línea: | Registro en Scopus DOI Handle Registro en la Biblioteca Digital |
| Aporte de: | Registro referencial: Solicitar el recurso aquí |
| LEADER | 04339caa a22006857a 4500 | ||
|---|---|---|---|
| 001 | PAPER-20077 | ||
| 003 | AR-BaUEN | ||
| 005 | 20230518205128.0 | ||
| 008 | 190411s1997 xx ||||fo|||| 00| 0 eng|d | ||
| 024 | 7 | |2 scopus |a 2-s2.0-0031592587 | |
| 024 | 7 | |2 cas |a benzaldehyde, 100-52-7; benzyl benzoate, 120-51-4, 8022-66-0 | |
| 040 | |a Scopus |b spa |c AR-BaUEN |d AR-BaUEN | ||
| 030 | |a TELEA | ||
| 100 | 1 | |a Nudelman, N.S. | |
| 245 | 1 | 0 | |a Conversion of benzaldehyde into benzyl benzoate from the reaction with lithium metal in hexane |
| 260 | |c 1997 | ||
| 270 | 1 | 0 | |m Nudelman, N.S.; Depto. Quimica Organica, Facultad Ciencias Exactas, Universidad de Buenos Aires, 1428 Buenos Aires, Argentina |
| 506 | |2 openaire |e Política editorial | ||
| 504 | |a Adamson, A.W., (1990) Physical Chemistry of Surfaces, , Wiley & Sons, New York | ||
| 504 | |a Sinfelt, J.H., (1987) Acc. Chem. Res., 20, p. 134 | ||
| 504 | |a Stockwell, D.M., Bennett, C.O., (1988) J. Catal., 110, p. 354 | ||
| 504 | |a Stockwell, D.M., Chung, J.S., Bennett, C.O., (1988) J. Catal., 122, p. 135 | ||
| 504 | |a Baetzold, R.C., Monnier, J.R., (1986) J. Phys. Chem., 90, p. 2944 | ||
| 504 | |a Nudelman, N.S., Carbonylation of main-group organometallic compounds (1989) The Chemistry of Double Bonded Functional Groups, , Patai, S. and Rappoport, Z. eds., ch. 13, Wiley, Chichester and references therein | ||
| 504 | |a Nudelman, N.S., Lewkowicz, E.S., Furlong, J.P.J., (1993) J. Org. Chem., 58, p. 1847 | ||
| 504 | |a Nudelman, N.S., Lewkowicz, E.S., Perez, D.R., (1990) Synthesis, p. 917 | ||
| 504 | |a Nudelman, N.S., Doctorovich, F., (1994) Tetrahedron, 50, p. 4651 | ||
| 504 | |a Baerns, M., Ross, J.R.H., Van Der Wiele, K., (1989) Methane Activation, Catalysis Today, p. 4 | ||
| 504 | |a Nudelman, N.S., Mendiara, S., (1996) J. Phys. Org. Chem., , in press | ||
| 504 | |a Stapp, P.R., (1973) J. Org. Chem., 38, p. 1433 | ||
| 504 | |a Larock, R.C., (1989) Comprehensive Organic Transformations, p. 840. , VCH, New York | ||
| 504 | |a Fox, M.A., (1992) Chem. Rev., 92, p. 365. , and refs. therein | ||
| 504 | |a Masnovi, J., Maticic, J., (1988) J. Am. Chem. Soc., 110, p. 5189 | ||
| 504 | |a Saito, Y., Ikehera, H., Kasatani, R., Watanabe, M., Matsuura, T., (1986) J. Am. Chem. Soc., 108, p. 5190 | ||
| 504 | |a Masnovi, J., Samsel, E.G., Bullok, R.M., (1989) J. Chem. Soc. Chem Comm, p. 1044 | ||
| 504 | |a Ashby, E.C., Coleman, D., Gamasa, M., (1987) J. Org. Chem., 52, p. 4079 | ||
| 504 | |a Shriver, D.F., (1989) The Manipulation of Air-Sensitive Compounds, , Wiley, N. Y | ||
| 520 | 3 | |a The reaction of benzaldehyde with lithium metal was studied in two solvents and several temperatures as a model for more complex processes. Conditions were achieved to favor the adsorption of reactant on the metal surface, as wed as to slow down diffusion of the reactive species to solution: reaction within adsorbed species produces benzyl benzoate in high yield. |l eng | |
| 593 | |a Depto. de Quimica Organica, Facultad de Ciencias Exactas, Universidad de Buenos Aires, 1428 Buenos Aires, Argentina | ||
| 593 | |a Depto. de Quimica, Facultad de Ciencias Exactas, Universidad de Mar del Plata, Mar del Plata, Argentina | ||
| 690 | 1 | 0 | |a BENZALDEHYDE |
| 690 | 1 | 0 | |a BENZYL BENZOATE |
| 690 | 1 | 0 | |a ADSORPTION |
| 690 | 1 | 0 | |a ARTICLE |
| 690 | 1 | 0 | |a CATALYSIS |
| 690 | 1 | 0 | |a DRUG SYNTHESIS |
| 690 | 1 | 0 | |a ELECTRON TRANSPORT |
| 690 | 1 | 0 | |a IN VITRO STUDY |
| 690 | 1 | 0 | |a METHODOLOGY |
| 690 | 1 | 0 | |a MODEL |
| 700 | 1 | |a Mendiara, S. | |
| 773 | 0 | |d 1997 |g v. 38 |h pp. 2245-2248 |k n. 13 |p TETRAHEDRON LETT. |x 00404039 |w (AR-BaUEN)CENRE-415 |t Tetrahedron Letters | |
| 856 | 4 | 1 | |u https://www.scopus.com/inward/record.uri?eid=2-s2.0-0031592587&doi=10.1016%2fS0040-4039%2897%2900334-1&partnerID=40&md5=d4beb8f2f0ba99273f774cf4b8198de9 |y Registro en Scopus |
| 856 | 4 | 0 | |u https://doi.org/10.1016/S0040-4039(97)00334-1 |y DOI |
| 856 | 4 | 0 | |u https://hdl.handle.net/20.500.12110/paper_00404039_v38_n13_p2245_Nudelman |y Handle |
| 856 | 4 | 0 | |u https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_00404039_v38_n13_p2245_Nudelman |y Registro en la Biblioteca Digital |
| 961 | |a paper_00404039_v38_n13_p2245_Nudelman |b paper |c PE | ||
| 962 | |a info:eu-repo/semantics/article |a info:ar-repo/semantics/artículo |b info:eu-repo/semantics/publishedVersion | ||
| 963 | |a VARI | ||
| 999 | |c 81030 | ||