Synthesis, crystal structure, and magnetic properties of the mixed-ligand complex [Gd(CF3CO2)3(phen)2 (H2O)]
The mononuclear gadolinium mixed-ligand complex [Gd(CF3CO2)3(phen)2 (H2O)] has been prepared and structurally characterized by X-ray crystallography. Two complex molecules are doubly bridged by H bonds between carboxylate and aqua ligands with a Gd-Gd separation of 7.16(1) Å. Magnetic susceptibility...
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2001
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024 | 7 | |2 scopus |a 2-s2.0-0035796160 | |
024 | 7 | |2 cas |a gadolinium, 7440-54-2 | |
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100 | 1 | |a Rizzi, A. | |
245 | 1 | 0 | |a Synthesis, crystal structure, and magnetic properties of the mixed-ligand complex [Gd(CF3CO2)3(phen)2 (H2O)] |
260 | |c 2001 | ||
270 | 1 | 0 | |m Rizzi, A.; Departamento de Física, Fac. Bioquimica Ciencias Biologicas, Universidad Nacional del Litoral, Güemes 3450, 3000 Santa Fe, Argentina |
504 | |a Lauffer, R.B., (1987) Chem. Rev., 87, p. 901 | ||
504 | |a Lauffer, R.B., (1990) Magn. Reson. Q., 6, p. 65 | ||
504 | |a Koening, S.H., Brown, R.D., (1990) Prog. Nucl. Magn. Reson Spectrosc., 22, p. 487 | ||
504 | |a Aime, S., Botta, M., Parker, D., Williams, J.A.G., (1995) J. Chem Soc., Dalton Trans., 2259 | ||
504 | |a Aime, S., Botta, M., Ermondi, G., Terreno, E., Anelli, P.L., Fedeli, F., Uggeri, F., (1996) Inorg. Chem., 35, p. 2726 | ||
504 | |a Wu, S.L., Franklin, S.J., Raymond, K.N., Horrocks W.DeW., Jr., (1996) Inorg. Chem., 35, p. 162 | ||
504 | |a Watson, A.D., (1994) J. Alloys Compd., 207-208, p. 14 | ||
504 | |a Kumar, K., Jin, T., Wang, X., Desreux, J.F., Tweedle, M.F., (1994) Inorg. Chem., 33, p. 3823 | ||
504 | |a Allen, F.H., Kennard, O., (1993) Chem. Des. Automat. News, 8 (1), p. 31 | ||
504 | |a Mao, L., Lu, W., Dong, N., Wu, G., Wang, B., (1989) Jiegou Huaxue (Structural Chemistry), 8, p. 75 | ||
504 | |a Panagiotopoulos, A., Zafiropoulos, T.F., Perlepes, S.P., Bakalbassis, E., Masson-Ramade, I., Kahn, O., Terzis, A., Raptopoulou, C.P., (1995) Inorg. Chem., 34, p. 4918 | ||
504 | |a Rybakov, V.B., Zakharov, V.N., Kamyshnyi, A.L., Aslanov, L.A., Suisalu, A.P., (1991) Koord. Khim., 17, p. 1061 | ||
504 | |a note; Sheldrick, G.M., (1997) SHELXS97: Program for Crystal Structure Resolution, , University of Göttingen: Göttingen, Germany | ||
504 | |a Sheldrick, G.M., (1997) SHELXL97: Program for Crystal Structure Refinement, , University of Göttingen: Göttingen, Germany | ||
504 | |a Sheldrick, G.M., (1991) SHELXTL-PC, version 4.2, , Siemens Analytical X-ray Instruments Inc.: Madison, WI | ||
504 | |a Nardelli, M., (1983) Comput. Chem., 7, p. 95 | ||
504 | |a Nakamoto, K., (1986) Infrared and Raman Spectra of Inorganic and Coordination Compounds, 4th ed., , Wiley-Interscience: New York | ||
504 | |a Deacon, G.B., Phillips, R.G., (1980) Coord. Chem. Rev., 33, p. 227 | ||
504 | |a Kepert, D.L., (1978) Prog. Inorg. Chem., 24, p. 179 | ||
504 | |a Orpen, A.G., Brammer, L., Allen, F.H., Kennard, O., Watson, D.G., Taylor, R., (1989) J. Chem. Soc., Dalton Trans., pp. S1 | ||
504 | |a Uggeri, F., Aime, S., Anelli, P.C., Botta, M., Brocchetta, M., De Haen, C., Ermondi, G., Paoli, P., (1995) Inorg. Chem., 34, p. 633 | ||
504 | |a Shanon, R.D., (1976) Acta Crystallogr., A32, p. 751 | ||
504 | |a Bencini, A., Gatteschi, D., (1990) Electron Paramagnetic Resonance of Exchange-Coupled Systems, , Springer: Berlin | ||
506 | |2 openaire |e Política editorial | ||
520 | 3 | |a The mononuclear gadolinium mixed-ligand complex [Gd(CF3CO2)3(phen)2 (H2O)] has been prepared and structurally characterized by X-ray crystallography. Two complex molecules are doubly bridged by H bonds between carboxylate and aqua ligands with a Gd-Gd separation of 7.16(1) Å. Magnetic susceptibility and EPR measurements showed weak magnetic exchange coupling of the 3D type. |l eng | |
593 | |a Departamento de Física, Facultad de Bioquímica y Ciencias Biológicas, Universidad Nacional del Litoral and INTEC(CONICET-UNL), Güemes 3450, 3000 Santa Fe, Argentina | ||
593 | |a Departamento de Física, Comisión Nacional de Energía Atómica, Avda. del Libertador 8250, 1429 Buenos Aires, Argentina | ||
593 | |a Departamento de Física, Facultad de Ciencias Físicas y Matemáticas, Universidad de Chile, Avda. Blanco Encalada 2008, Casilla 487-3, Santiago, Chile | ||
593 | |a U.M.R. 6511, L.C.S.I.M. CNRS, Institut de Chimie de Rennes, Universite de Rennes I, 35042 Rennes, France | ||
593 | |a Departamento de Química Inorgánica Analítica y Química Física, Facultad de Ciencias Exactas y Naturales, INQUIMAE, Universidad de Buenos Aires, Ciudad Universitaria, Pabellón II, 1428, Buenos Aires, Argentina | ||
690 | 1 | 0 | |a GADOLINIUM |
690 | 1 | 0 | |a LIGAND |
690 | 1 | 0 | |a ARTICLE |
690 | 1 | 0 | |a COMPLEX FORMATION |
690 | 1 | 0 | |a CRYSTAL STRUCTURE |
690 | 1 | 0 | |a MAGNETISM |
690 | 1 | 0 | |a MOLECULAR DYNAMICS |
690 | 1 | 0 | |a STEREOCHEMISTRY |
690 | 1 | 0 | |a SYNTHESIS |
690 | 1 | 0 | |a X RAY CRYSTALLOGRAPHY |
700 | 1 | |a Baggio, R. | |
700 | 1 | |a Calvo, Rafael A. | |
700 | 1 | |a Garland, M.T. | |
700 | 1 | |a Peña, O. | |
700 | 1 | |a Perec, M. | |
773 | 0 | |d 2001 |g v. 40 |h pp. 3623-3625 |k n. 14 |p Inorg. Chem. |x 00201669 |w (AR-BaUEN)CENRE-60 |t Inorganic Chemistry | |
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856 | 4 | 0 | |u https://doi.org/10.1021/ic001243v |x doi |y DOI |
856 | 4 | 0 | |u https://hdl.handle.net/20.500.12110/paper_00201669_v40_n14_p3623_Rizzi |x handle |y Handle |
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963 | |a VARI |