Toxic furanoeremophilanes from Senecio bonariensis
Four toxic 10αH-9-oxofuranoeremophilanes were isolated and identified from the petroleum ether extract of Senecio bonariensis. Their 13C NMR spectral data, J1,10 Altona calculation and a correlation for 1H NMR (C6D6/CDCl3) are discussed. © Swets & Zeitlinger.
Guardado en:
| Autor principal: | |
|---|---|
| Otros Autores: | |
| Formato: | Capítulo de libro |
| Lenguaje: | Inglés |
| Publicado: |
1997
|
| Acceso en línea: | Registro en Scopus Handle Registro en la Biblioteca Digital |
| Aporte de: | Registro referencial: Solicitar el recurso aquí |
| LEADER | 07304caa a22006617a 4500 | ||
|---|---|---|---|
| 001 | PAPER-19974 | ||
| 003 | AR-BaUEN | ||
| 005 | 20230518205122.0 | ||
| 008 | 190411s1997 xx ||||fo|||| 00| 0 eng|d | ||
| 024 | 7 | |2 scopus |a 2-s2.0-21544431596 | |
| 040 | |a Scopus |b spa |c AR-BaUEN |d AR-BaUEN | ||
| 030 | |a PHBIF | ||
| 100 | 1 | |a Pomilio, A.B. | |
| 245 | 1 | 0 | |a Toxic furanoeremophilanes from Senecio bonariensis |
| 260 | |c 1997 | ||
| 270 | 1 | 0 | |m Pomilio, A.B.; PROPLAME-CONICET, Departamento de Química Orgánica, Ciudad Universitaria, 1428 Buenos Aires, Argentina |
| 506 | |2 openaire |e Política editorial | ||
| 504 | |a Birnbaum, G.I., Stoessl, A., Grover, S.H., Stothers, J.B., The complete stereostructure of capsidiol. X-ray analysis and 13C Nuclear Magnetic Resonance of eremophilane derivatives having trans-vicinal methyl groups (1974) Can. J. Chem., 52, pp. 993-1005 | ||
| 504 | |a Bohlmann, F., Zdero, C., Natürlich vorkommende Terpen-Derivate XLI. Über neue Sesquiterpene der Gattung Senecio (1974) Chem. Ber., 107, pp. 2912-2922 | ||
| 504 | |a Bohlmann, F., Zdero, C., Neue C10-Säureamide, Furanoeremophilane und andere Inhaltsstoffe aus bolivianische Senecio-Arten (1979) Phytochemistry, 18, pp. 125-128 | ||
| 504 | |a Bohlmann, F., Zdero, C., Grenz, M., Natürlich vorkommende Terpen-Derivate XXXIX. Über die Inhaltsstoffe der Gattung (1974) Euryops. Chem. Ber., 107, pp. 2730-2736 | ||
| 504 | |a Burden, R.S., Loeffler, R.S.T., Rowell, P.M., Bailey, J.A., Kemp, M.S., Cyclodebneyol, a fungitoxic sesquiterpene from TNV infected Nicotiana debneyi (1986) Phytochemistry, 25, pp. 1607-1608 | ||
| 504 | |a Cabrera, A.L., Compuestas (1963) Flora de la Provincia de Buenos Aires, 4 (6 PART), pp. 306-308. , edited by Colección Científica del Instituto Nacional de Tecnología Agropecuaria (INTA), Buenos Aires, Argentina | ||
| 504 | |a Chalmers, A.A., Coleman, P.C., Rivett, D.E.A., Woolard, G.R., Carbon-13 Nuclear Magnetic Resonance spectroscopy of euryopronol and euryoprol (1980) S. Afr. J. Chem., 33, pp. 1-7 | ||
| 504 | |a Dalling, D.K., Grant, D.M., Carbon-13 Magnetic Resonance. XXI. Steric interactions in the methylcyclohexanes (1972) J. Am. Chem. Soc., 94, pp. 5318-5324 | ||
| 504 | |a Dalling, D.K., Grant, D.M., Paul, E.G., Carbon-13 Magnetic Resonance. XXIII. The methyldecalins (1973) J. Am. Chem. Soc., 95, pp. 3718-3724 | ||
| 504 | |a Flamm, B.L., Pettus Jr., J.A., Sims, J.J., Springer, J.P., Clardy, J., Isolation of epoxydecompostin from Lepidospartum squamatum Gray and its structure revision (1976) Tetrahedron Lett., (31), pp. 2671-2674 | ||
| 504 | |a Gough, J.L., Guthrie, J.P., Stothers, J.B., Stereochemical assignments in steroids by C-13 nuclear magnetic resonance spectroscopy. Configuration of the A/B ring junction (1972) J. Chem. Soc. Chem. Commun., pp. 979-980 | ||
| 504 | |a Guerriero, A., Pietra, F., Furanoeremophilanes from Petarites niveus: High solvolitic reactivity at the C-6β position bearing an α,β-unsaturated ester group (1982) Phytochemistry, 21, pp. 2887-2891 | ||
| 504 | |a Haasnoot, C.A.G., De Leeuw, F.A.A.M., De Leeuw, H.M.P., Altona, C., The relationship between proton-proton NMR coupling constants and substituents electronegativities. Part II. Conformational analysis of the sugar ring in nucleosides and nucleotides in solution using a generalized Karplus equation (1981) Org. Magn. Res., 15, pp. 43-52 | ||
| 504 | |a Hegnauer, R., Compositae (1989) Chemotaxonomie der Pflanzen, 8, pp. 260-319. , Ed. Birkhäuser, Basel, Boston and Berlin | ||
| 504 | |a Heywood, V.H., Harborne, J.B., Turner, B.L., (1977) The Biology and Chemistry of the Compositae, Vol. 2, Senecioneae, 2, pp. 831-850. , Robins, D.J., Academic Press, London | ||
| 504 | |a Jares, E.A., (1989) Estudio Químico de Senecio Crassiflorus (Poir.) D.C., Senecio Bonariensis H. et A. y Senecio Viravira Hieron, 243p. , Ph.D. Thesis, No. 2266, Director: Prof. Dr. A.B. Pomilio, Facultad de Ciencias Exactas y Naturales, Universidad de Buenos Aires, Buenos Aires, Argentina | ||
| 504 | |a Jares, E.A., Tettamanzi, M.C., Pomilio, A.B., Sitosterol 3-O-β-D-glucuropyranoside from Senecio bonariensis (1990) Phytochemistry, 29, pp. 340-341 | ||
| 504 | |a Jennings, P.W., Reeder, S.K., Hurley, J.C., Caughlan, C.N., Smith, G.D., Isolation and structure elucidation of one of the toxic constituents from Tetradymia glabrata (1974) J. Org. Chem., 39, pp. 3392-3398 | ||
| 504 | |a Jennings, P.W., Hurley, J.C., Reeder, S.K., Holian, A., Lee, P., Caughlan, C.N., Larsen, R.D., Isolation and structure elucidation of the second toxic constituent from Tetradymia glabrata (1976) J. Org. Chem., 41, pp. 4078-4081 | ||
| 504 | |a Nachman, R.J., Tetrahydroligularenolide and related eremophilanes from Senecio aureus (1983) Phytochemistry, 22, pp. 780-782 | ||
| 504 | |a Page Jr., T.F., Alger, T., Grant, D.M., The Carbon-13 Nuclear Magnetic Resonance of furan, pyrrole, thiophene, and some of their methyl derivatives (1965) J. Am. Chem. Soc., 87, pp. 5333-5339 | ||
| 504 | |a Samek, Z., Harmatha, J., Novotny, L., Sorm, F., Terpenes. CCII. Absolute configuration of adenostylone, neoadenostylone, and isoadenostylone from Adenostyles attiariae and decompostine from Cacalia decomposita (1969) Collect. Czech. Chem. Commun., 34, pp. 2792-2808 | ||
| 504 | |a Tada, M., Sato, T., Takahashi, T., Tori, K., Horibe, I., Kuriyama, K., Conformational equilibria of eremophilanes, naturally occurring cis-decalin derivatives, studied by NMR and CD spectroscopy (1981) J. Chem. Soc., Perkin I, pp. 2695-2701 | ||
| 504 | |a Villarroel, L., Torres, R., Gavin, J., Reina, M., De La Fuente, G., 9-oxo-10αH-furanoeremophilanes from Senecio chilensis and Senecio patagonicus (1991) J. Nat. Prod., 54, pp. 588-590 | ||
| 504 | |a Wehrly, F.W., Nishida, T., The use of C-13 Nuclear Magnetic Resonance Spectroscopy in Natural Products Chemistry (1979) Fortschr. Chem. Org. Naturst., 36, pp. 1-229. , founded by Zechmeister. Herzw. Grisebach, H. and Kirby, G.W | ||
| 520 | 3 | |a Four toxic 10αH-9-oxofuranoeremophilanes were isolated and identified from the petroleum ether extract of Senecio bonariensis. Their 13C NMR spectral data, J1,10 Altona calculation and a correlation for 1H NMR (C6D6/CDCl3) are discussed. © Swets & Zeitlinger. |l eng | |
| 593 | |a PROPLAME-CONICET, Departamento de Química Orgánica, Ciudad Universitaria, 1428 Buenos Aires, Argentina | ||
| 690 | 1 | 0 | |a 13C NMR DATA |
| 690 | 1 | 0 | |a 1H NMR (C6D6/CDCL3) |
| 690 | 1 | 0 | |a FURANOEREMOPHILANES |
| 690 | 1 | 0 | |a J1,10 ALTONA CALCULATION |
| 690 | 1 | 0 | |a SENECIO BONARIENSIS |
| 690 | 1 | 0 | |a TOXIC |
| 700 | 1 | |a Jares, E.A. | |
| 773 | 0 | |d 1997 |g v. 35 |h pp. 207-211 |k n. 3 |p Pharm. Biol. |x 13880209 |w (AR-BaUEN)CENRE-6435 |t Pharmaceutical Biology | |
| 856 | 4 | 1 | |u https://www.scopus.com/inward/record.uri?eid=2-s2.0-21544431596&partnerID=40&md5=e67b70d3439e046160b4b2f7e4e2ba92 |y Registro en Scopus |
| 856 | 4 | 0 | |u https://hdl.handle.net/20.500.12110/paper_13880209_v35_n3_p207_Pomilio |y Handle |
| 856 | 4 | 0 | |u https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_13880209_v35_n3_p207_Pomilio |y Registro en la Biblioteca Digital |
| 961 | |a paper_13880209_v35_n3_p207_Pomilio |b paper |c PE | ||
| 962 | |a info:eu-repo/semantics/article |a info:ar-repo/semantics/artículo |b info:eu-repo/semantics/publishedVersion | ||
| 999 | |c 80927 | ||