Solubility of i2 and formation of f2-arene charge-transfer complexes in supercritical SF6
The solubility of I2(s) has been measured spectrophotometrically in supercritical SF6 with and without the addition of benzene and mesitylene at temperatures, T = 323.95. 330.00 and 340.55 K over the pressure range 2-10 MPa. It was possible to obtain the solubility of iodine and the concentration of...
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1998
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| LEADER | 05184caa a22006257a 4500 | ||
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| 001 | PAPER-19746 | ||
| 003 | AR-BaUEN | ||
| 005 | 20230518205107.0 | ||
| 008 | 190411s1998 xx ||||fo|||| 00| 0 eng|d | ||
| 024 | 7 | |2 scopus |a 2-s2.0-33751138641 | |
| 040 | |a Scopus |b spa |c AR-BaUEN |d AR-BaUEN | ||
| 100 | 1 | |a Destsillats, H. | |
| 245 | 1 | 0 | |a Solubility of i2 and formation of f2-arene charge-transfer complexes in supercritical SF6 |
| 260 | |c 1998 | ||
| 270 | 1 | 0 | |m Destsillats, H.; Institute de Quimica Fisica de Materielles, Ambiente y Energia, Facuhad de Ciencias Exactas y Naturales, Ciudad Universitaria Pabellón II, 1428-Capital Federal, Argentina |
| 506 | |2 openaire |e Política editorial | ||
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| 520 | 3 | |a The solubility of I2(s) has been measured spectrophotometrically in supercritical SF6 with and without the addition of benzene and mesitylene at temperatures, T = 323.95. 330.00 and 340.55 K over the pressure range 2-10 MPa. It was possible to obtain the solubility of iodine and the concentration of the charge-transfer complex from the visible and UV bands of the spectra over The fluid density range 1.0-9.1 mol dm-3. The results support the view that interactions between iodine and the arene molecules are restricted to Leonard-Jones plus multipcle interactions. The observed variation with fluid density of the equilibrium concentration quotient for charge-transfer complex formation may be correlated with the density dependence of the excess number of I2-arene collisions. No evidence for the existence of critical clustering has been found. |l eng | |
| 593 | |a Institute de Quimica Fisica de Materielles, Ambiente y Energia, Facuhad de Ciencias Exactas y Naturales, Ciudad Universitaria Pabellón II, 1428-Capital Federal, Argentina | ||
| 593 | |a Unidad de Actividad Quimica, Comision National de Energia Atómica, Av. Libertador 8250, 1429-Capital Federal, Argentina | ||
| 700 | 1 | |a Fernandez-Prini, R. | |
| 773 | 0 | |d 1998 |g v. 94 |h pp. 871-878 |k n. 7 |x 09565000 |t Journal of the Chemical Society - Faraday Transactions | |
| 856 | 4 | 1 | |u https://www.scopus.com/inward/record.uri?eid=2-s2.0-33751138641&partnerID=40&md5=64c9401a78668d20c63c2129f54fd9b0 |y Registro en Scopus |
| 856 | 4 | 0 | |u https://hdl.handle.net/20.500.12110/paper_09565000_v94_n7_p871_Destsillats |y Handle |
| 856 | 4 | 0 | |u https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_09565000_v94_n7_p871_Destsillats |y Registro en la Biblioteca Digital |
| 961 | |a paper_09565000_v94_n7_p871_Destsillats |b paper |c PE | ||
| 962 | |a info:eu-repo/semantics/article |a info:ar-repo/semantics/artículo |b info:eu-repo/semantics/publishedVersion | ||
| 999 | |c 80699 | ||