Anionic halide and isothiocyanate adducts of zinc and cadmium dithiocarbamates

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The mixed-ligand complexes [NEt4][Zn(S2CNMe2)2X] (X = Cl, Br, or NCS) and [NR4][Cd(S2CNEt2)2X] (R = Et, X = Cl, Br, or NCS; R = Bun, X = I) have been prepared by reaction of zinc and cadmium bis(dithiocarbamate) with the tetraalkylammonium salt of the halide or thiocyanate in acetone at room tempera...

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Detalles Bibliográficos
Autor principal: Baggio, R.
Otros Autores: Frigerio, Alicia Beatriz, Halac, E.B, Vega, D., Perec, M.
Formato: Capítulo de libro
Lenguaje:Inglés
Publicado: 1992
Acceso en línea:Registro en Scopus
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Registro en la Biblioteca Digital
Aporte de:Registro referencial: Solicitar el recurso aquí
Biblioteca Central Dr. Luis F. Leloir (FCEN) de Universidad de Buenos Aires
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100 1 |a Baggio, R. 
245 1 0 |a Anionic halide and isothiocyanate adducts of zinc and cadmium dithiocarbamates 
260 |c 1992 
270 1 0 |m Perec, M.; Departamento de Quimica Inorganica, Analitica y Quimica Fisica, Universidad de Buenos Aires, Ciudad Universitaria, Pabellon II 1428, Buenos Aires, Argentina 
504 |a McCleverty, J.A., Morrison, N.J., Spencer, N., Ashworth, C.C., Bailey, N.A., Johnson, M.R., Smith, J.M.A., Taylor, C.R., (1980) J. Chem. Soc., Dalton Trans., p. 1945 
504 |a McCleverty, J.A., Gill, S., Kowalski, R.S.Z., Bailey, N.A., Adams, H., Lumbard, K.W., Murphy, M.A., (1982) J. Chem. Soc., Dalton Trans., p. 493 
504 |a McCleverty, J.A., Spencer, N., Bailey, N.A., Shackelton, S.L., (1980) J. Chem. Soc., Dalton Trans., p. 1939 
504 |a Coucouvanis, D., (1970) Prog. Inorg. Chem, 11, p. 234 
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504 |a McCleverty, J.A., Morrison, N.J., (1976) J. Chem. Soc., Dalton Trans., p. 2169 
504 |a Duhme, A.K., Pohl, S., Strasdeit, H., (1990) Inorg. Chim.Acta, 175, p. 5 
504 |a Fraser, K.A., Harding, M.M., (1967) Acta Crystallogr., 22, p. 75 
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504 |a Ueyama, N., Sugawara, T., Sasaki, K., Nakamura, A., Yamashita, S., Wakatsuki, Y., Yamazaki, H., Yasuoka, N., (1988) Inorg. Chem., 27, p. 741 
504 |a Gruff, E.S., Koch, S.A., (1989) J. Am. Chem. Soc., 111, p. 8762 
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504 |a Haanstra, W.G., Driessen, W.L., Reedijk, J., Turpeinen, U., Hamalainen, R., (1989) J. Chem. Soc., Dalton Trans., p. 2309 
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504 |a Goel, R.G., (1981) Spectrochim. Acta, Part A, 37, p. 557 
504 |a Nakamoto, K., (1986) Infrared and Raman Spectra of Inorganic and Coordination Compounds, , 4th edn., Wiley-Interscience, New York 
504 |a Bonati, F., Ugo, R., (1967) J. Organomet. Chem., 10, p. 257 
504 |a Brown, D., Glass, W.K., Burke, M.A., (1976) Spectrochim. Acta, Part A., 32, p. 137 
504 |a Kellner, R., Nikolov, G.S., Trendafilova, N., (1984) Inorg. Chim. Acta, 84, p. 233 
504 |a Frigerio, A., Halacand, B., Perec, M., (1989) Inorg. Chim. Acta, 164, p. 149 
504 |a Coates, G.E., Ridley, D., (1964) J. Chem. Soc., p. 166 
504 |a Goldstein, M., Unsworth, W.D., (1972) J. Mol. Struct., 14, p. 451 
504 |a Adams, D.M., Cornell, J.B., (1967) J. Chem. Soc. A, p. 428 
504 |a Adams, D.M., Hooper, M.A., (1972) J. Chem. Soc., Dalton Trans., p. 631 
504 |a Dance, G.I., Choy, A., Scudder, M.L., (1984) J. Am. Chem. Soc., 106, p. 62 
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504 |a Walker, N., Stuart, D., (1983) Acta Crystallogr., Sect. A, 39, p. 158 
504 |a Sheldrick, G.M., (1985) Crystallographic Computing 3, 175p. , SHELXS 86, eds. G. M. Sheldrick, C. Kruger and R. Goddard, Oxford University Press 
504 |a Sheldrick, G.M., (1976), SHELX 76, Program for Crystal Structure Determination, University of Cambridge; (1974) International Tables for X-Ray Crystallography, 4. , Kynoch Press, Birmingham 
506 |2 openaire  |e Política editorial 
520 3 |a The mixed-ligand complexes [NEt4][Zn(S2CNMe2)2X] (X = Cl, Br, or NCS) and [NR4][Cd(S2CNEt2)2X] (R = Et, X = Cl, Br, or NCS; R = Bun, X = I) have been prepared by reaction of zinc and cadmium bis(dithiocarbamate) with the tetraalkylammonium salt of the halide or thiocyanate in acetone at room temperature. The single-crystal X-ray structures of [NEt4][Zn(S2CNMe2)2(NCS)] 1 and [NEt4][Cd(S2CNEt2)2(NCS)] 2 were determined: 1, monoclinic, space group P21/n, a = 9.447(1), b = 16.661(2), c = 15.807(1) Å, β = 97.10(1)° and Z = 4; 2, orthorhombic, space group P212121, a = 16.213(1), b = 17.501(2), c = 10.243(1) Å and Z = 4. The central Zn and Cd atoms show distorted trigonal-bipyramidal co-ordination geometry with the thiocyanate N atom occupying an equatorial position and the dithiocarbamate ligands spanning one axial and one equatorial position each. The infrared and Raman spectra (2100-50 cm-1) of the complexes are discussed. The metal-sulfur stretching frequencies are assigned in the ranges 226-205 (Zn-S) and 203-145 cm-1 (Cd-S), respectively.  |l eng 
593 |a Division Fisica del Solido, Departamento de Fisica, Comision Nacional de Energia Atomica, Avda. del Libertador 8250 1429, Buenos Aires, Argentina 
593 |a Departamento de Quimica Inorganica, Analitica y Quimica Fisica, Universidad de Buenos Aires, Ciudad Universitaria, Pabellon II 1428, Buenos Aires, Argentina 
700 1 |a Frigerio, Alicia Beatriz 
700 1 |a Halac, E.B. 
700 1 |a Vega, D. 
700 1 |a Perec, M. 
773 0 |d 1992  |h pp. 549-554  |k n. 4  |x 14727773  |t Journal of the Chemical Society, Dalton Transactions 
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856 4 0 |u https://doi.org/10.1039/DT9920000549  |y DOI 
856 4 0 |u https://hdl.handle.net/20.500.12110/paper_14727773_v_n4_p549_Baggio  |y Handle 
856 4 0 |u https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_14727773_v_n4_p549_Baggio  |y Registro en la Biblioteca Digital 
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