Synthesis and characterization of dithiocarbonate derivatives of zinc and cadmium bis(dithiocarbamates)

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The mixed-ligand complexes [NBun4][Zn(S2CNMe2) 2(S2COEt)] 1, [NBun4][Cd(S2CNEt2) 2(S2COEt)] 2 and [PPh4][Cd(S2CNEt2)2(S 2COEt)] 3 have been prepared by direct addition of zinc and cadmium bis(dithiocarbamate) to the tetraalkylammonium or tetraphenylphosphonium dithiocarbonate salt in acetone at room...

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Detalles Bibliográficos
Autor principal: Baggio, R.
Otros Autores: Frigerio, Alicia Beatriz, Halac, E.B, Vega, D., Perec, M.
Formato: Capítulo de libro
Lenguaje:Inglés
Publicado: 1992
Acceso en línea:Registro en Scopus
DOI
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Registro en la Biblioteca Digital
Aporte de:Registro referencial: Solicitar el recurso aquí
Biblioteca Central Dr. Luis F. Leloir (FCEN) de Universidad de Buenos Aires
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100 1 |a Baggio, R. 
245 1 0 |a Synthesis and characterization of dithiocarbonate derivatives of zinc and cadmium bis(dithiocarbamates) 
260 |c 1992 
270 1 0 |m Perec, M.; Departamento de Quimica Inorganica, Analitica y Quimica Fisica, Universidad de Buenos Aires, Ciudad Universitaria, 1428 Buenos Aires, Argentina 
504 |a Gruff, E.S., Koch, S.A., (1989) J. Am. Chem. Soc., 11, p. 8762 
504 |a Santos, R.A., Gruff, E.S., Koch, S.A., Harbison, G.S., (1991) J. Am. Chem. Soc., 113, p. 469 
504 |a Li, H.Y., Amma, E.L., (1990) Inorg. Chim. Acta, 177, p. 5 
504 |a Hickman, J.J., Wrighton, M.S., (1991) J. Am. Chem. Soc., 113, p. 4440 
504 |a Dance, I.G., (1980) J. Am. Chem. Soc., 102, p. 3445 
504 |a Swenson, D., Baezinger, N.C., Coucouvanis, D., (1978) J. Am. Chem. Soc., 100, p. 1933 
504 |a Eklund, H., Nordstrom, B., Zeppezauer, E., Soderiund, G., Ohlsson, I., Boiwe, T., Sonderberg, B.O., Branden, C.I., (1976) J. Mol. Biol., 102, p. 27 
504 |a Rosenbusch, J.D., Weber, K., (1980) Proc. Natl. Acad. Sci. USA, 68, p. 1019 
504 |a Ueyama, N., Sugawara, T., Sasaki, K., Nakamura, A., Yamashita, S., Wakatsuki, Y., Yamazaki, H., Yasuoka, N., (1988) Inorg. Chem., 27, p. 741 
504 |a Salma, S., Shugar, H., Spiro, T.G., (1979) Inorg. Chem., 18, p. 104 
504 |a Blair, D.F., Campbell, G.W., Schoonover, J.R., Chan, S.I., Gray, H.B., Malmstrom, B.G., Pecht, I., Norton, K.A., (1985) J. Am. Chem. Soc., 107, p. 5755 
504 |a Cohen, B., Mastropaolo, D., Potenza, J.A., Schugar, H.J., (1978) Acta Crystallogr., Sect. B, 34, p. 2958 
504 |a Mastropaolo, D., Thich, J.A., Potenza, J.A., Schugar, H.J., (1977) J. Am. Chem. Soc., 99, p. 424 
504 |a Coucouvanis, D., (1970) Prog. Inorg. Chem., 11, p. 233 
504 |a Coucouvanis, D., (1979) Prog. Inorg. Chem., 26, p. 301 
504 |a Ashworth, C.C., Bailey, N.A., Johnson, M., McCleverty, J.A., Morrison, N., Tabbiner, B., (1976) J. Chem. Soc., Chem. Commun., p. 743 
504 |a McCleverty, J.A., Kowalski, R.S.Z., Bailey, N.A., Mulvaney, R., O’Cleirigh, D.A., (1983) J. Chem. Soc., Dalton Trans., p. 627 
504 |a McCleverty, J.A., Gill, S., Kowalsky, R.S.Z., Bailey, N.A., Adams, H., Lumbard, K.W., Murphy, M.A., (1982) J. Chem. Soc., Dalton Trans., p. 493 
504 |a Hoskins, B.F., Kelly, B.P., (1972) Inorg. Nucl. Chem. Lett., 8, p. 875 
504 |a Sola, M., Lledos, A., Duran, M., Bertran, J., (1991) Inorg. Chem., 30, p. 2523 
504 |a Alsfasser, R., Trofimenko, S., Looney, A., Parkin, G., Vahrenkamp, H., (1991) Inorg. Chem., 30, p. 4098 
504 |a Hoops, S.C., Anderson, W.K., Merz, K.M., Jr., (1991) J. Am. Chem. Soc., 113, p. 8262 
504 |a Zhang, C., Chadha, R., Reddy, H.K., Schrauzer, G.N., (1991) Inorg. Chem., 30, p. 3865 
504 |a Duhme, A.K., Siegfrid, P., Strasdeit, H., (1990) Inorg. Chim. Acta, 175, p. 5 
504 |a Orpen, A.G., Brammer, L., Allen, F.H., Kennard, O., Watson, D.G., Taylor, R., (1989) J. Chem. Soc., Dalton Trans., p. 1 
504 |a Huheey, J.E., (1978) Principles of Structure and Reactivity, , 2nd edn., Harper & Row, New York 
504 |a Addison, A.W., Rao, T.N., Reedijk, J., Van Rijn, J., Verschoor, G.C.J., (1984) J. Chem. Soc., Dalton Trans., p. 1349 
504 |a Carmona, E., Contreras, L., Sanchez, L.J., Gutierrez-Puebla, E., Monge, A., (1989) J. Chem. Soc., Dalton Trans., p. 2003 
504 |a Raston, C.L., White, A.H., (1976) Aust. J. Chem., 29, p. 739 
504 |a Kepert, D.L., (1977) Prog. Inorg. Chem., 23, p. 1 
504 |a Bonati, F., Ugo, R., (1967) J. Organomet. Chem., 10, p. 257 
504 |a Brown, D., Glass, W.K., Burke, M.A., (1976) Spectrochim. Acta, Part A, 32, p. 137 
504 |a Kellner, R., Nikolov, G.S., Trendafilova, N., (1984) Inorg. Chim. Acta, 84, p. 233 
504 |a Watt, G.W., McCormick, B.J., (1965) Spectrochim. Acta, 21, p. 753 
504 |a Drake, J.E., Sarkar, A.B., Wong, M.L.Y., (1990) Inorg. Chem., 29, p. 785 
504 |a Baggio, R., Frigerio, A., Halac, E.B., Vega, D., Perec, M., (1992) J. Chem. Soc. Dalton Trans., p. 549 
504 |a Osakada, K., Yamamoto, T., (1991) Inorg. Chem., 30, p. 2328 
504 |a Walker, N., Stuart, D., (1983) Acta Crystallogr., Sect. A, 39, p. 158 
504 |a Sheldrick, G.M., (1985) Crystallographic Computing 3, 175p. , SHELXS 86, eds. G. M. Sheldrick, C. Kruger and R. Goddard, Oxford University Press, Oxford 
504 |a Sheldrick, G.M., (1976), SHELX 76, Program for Crystal Structure Determination, University of Cambridge; (1974) International Tables for X-Ray Crystallography, 4. , Kynoch Press, Birmingham 
506 |2 openaire  |e Política editorial 
520 3 |a The mixed-ligand complexes [NBun4][Zn(S2CNMe2) 2(S2COEt)] 1, [NBun4][Cd(S2CNEt2) 2(S2COEt)] 2 and [PPh4][Cd(S2CNEt2)2(S 2COEt)] 3 have been prepared by direct addition of zinc and cadmium bis(dithiocarbamate) to the tetraalkylammonium or tetraphenylphosphonium dithiocarbonate salt in acetone at room temperature. The compounds were characterized by elemental analysis and infrared, Raman, and 1H NMR spectroscopy. The crystal structures of 1 and 3 were determined: 1, orthorhombic, space group Pbca (no. 61), a = 20.140(5), b = 16.570(4), c = 21.453(5) Å and Z = 8; 3, orthorhombic, space group Pna21 (no. 33), a = 19.027(5), b = 13.829(3), c = 15.938(4) Å and Z = 4. The environment about zinc is a distorted trigonal bipyramid with a monodentate dithiocarbonate ligand in an equatorial position and the dithiocarbamate ligands spanning one axial and one equatorial position each. The cadmium environment is a distorted six-co-ordinate trigonal prism. The metal-sulfur modes are assigned empirically at 218 (Zn-S) and at 165 cm-1 (Cd-S). The thermal degradation of solids 1 and 2 affords ZnS and CdS, respectively.  |l eng 
593 |a Division Fisica del Solido, Departamento de Fisica, Comision Nacional de Energia Atomica, Avda del Libertador 8250, 1429 Buenos Aires, Argentina 
593 |a Departamento de Quimica Inorganica, Analitica y Quimica Fisica, Universidad de Buenos Aires, Ciudad Universitaria, 1428 Buenos Aires, Argentina 
700 1 |a Frigerio, Alicia Beatriz 
700 1 |a Halac, E.B. 
700 1 |a Vega, D. 
700 1 |a Perec, M. 
773 0 |d 1992  |h pp. 1887-1892  |k n. 12  |x 14727773  |t Journal of the Chemical Society, Dalton Transactions 
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856 4 0 |u https://doi.org/10.1039/DT9920001887  |y DOI 
856 4 0 |u https://hdl.handle.net/20.500.12110/paper_14727773_v_n12_p1887_Baggio  |y Handle 
856 4 0 |u https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_14727773_v_n12_p1887_Baggio  |y Registro en la Biblioteca Digital 
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962 |a info:eu-repo/semantics/article  |a info:ar-repo/semantics/artículo  |b info:eu-repo/semantics/publishedVersion 
999 |c 80171 

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