Fluorescence quenching kinetic model for a bound and partitioned quencher in micelles

A kinetic model for quenching of a fluorescent probe in micelles is analysed. The probe is totally incorporated into the micelles. The quencher distributes between water and the micellar pseudophase in two different ways; i.e. by binding and by partition. The model is analytically solved under the a...

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Detalles Bibliográficos
Autor principal: Daraio, Marta Edit
Otros Autores: Aramendía, P.F, San Román, E.
Formato: Capítulo de libro
Lenguaje:Inglés
Publicado: Elsevier 1996
Acceso en línea:Registro en Scopus
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Registro en la Biblioteca Digital
Aporte de:Registro referencial: Solicitar el recurso aquí
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100 1 |a Daraio, Marta Edit 
245 1 0 |a Fluorescence quenching kinetic model for a bound and partitioned quencher in micelles 
260 |b Elsevier  |c 1996 
270 1 0 |m Daraio, M.E.; INQUIMAE, Depto. de Quimica Inorgánica, Universidad de Buenos Aires, Pabellón 2, 1428 Buenos Aires, Argentina 
504 |a Kalyanasundaram, K., (1987) Photochemistry in Microheterogeneous Systems, , Academic Press, New York 
504 |a Grätzel, M., (1989) Heterogeneous Photochemical Electron Transfer, , CRC Press, Boca Raton 
504 |a Gehlen, M.H., De Schryver, F.C., (1993) Chem. Rev., 93, p. 199 
504 |a (1993) J. Phys. Chem., 97, p. 11242 
504 |a Bohne, C., Barra, M., Boch, R., Abuin, E.B., Scaiano, J.C., (1992) J. Photochem. Photobiol. A, 65, p. 249 
504 |a Daraio, M.E., Aramendía, P.F., San Román, E., (1993) Chem. Phys. Letters, 204, p. 415 
504 |a (1994) J. Photochem. Photobiol. A, 77, p. 41 
504 |a Blatt, E., Chatelier, R.C., Sawyer, W.H., (1986) Biophys. J., 50, p. 349 
504 |a Haigh, E.A., Thulborn, K.R., Nichol, L.W., Sawyer, W.H., (1978) Aust. J. Biol. Sci., 31, p. 447 
504 |a Encinas, M.V., Lissi, E.A., (1982) Chem. Phys. Letters, 91, p. 55 
504 |a Blatt, E., Chatelier, R.C., Sawyer, W.H., (1984) Chem. Phys. Letters, 108, p. 397 
504 |a Ziemiecki, H.W., Holland, R., Cherry, W.R., (1980) Chem. Phys. Letters, 73, p. 145 
504 |a Infelta, P.P., Grätzel, M., Thomas, J.K., (1974) J. Phys. Chem., 78, p. 190 
504 |a Tachiya, M., (1975) Chem. Phys. Letters, 33, p. 289 
504 |a Yekta, A., Aikawa, M., Turro, N.J., (1979) Chem. Phys. Letters, 63, p. 543 
504 |a Turro, N.J., Aikawa, M., Yekta, A., (1979) Chern. Phys. Letters, 64, p. 473 
504 |a Tachiya, M., (1982) J. Chem. Phys., 76, p. 340 
504 |a Daraio, M.E., Aramendía, P.F., San Román, E., Braslavsky, S.E., (1991) Photochem. Photobiol., 54, p. 367 
504 |a Hunter, T.F., (1980) Chem. Phys. Letters, 75, p. 152 
504 |a Daraio, M.E., Völker, A., Aramendía, P.F., San Román, E., to be published; Katusin-Razem, B., Wong, M., Thomas, J.K., (1978) J. Am. Chem. Soc., 100, p. 1679 
506 |2 openaire  |e Política editorial 
520 3 |a A kinetic model for quenching of a fluorescent probe in micelles is analysed. The probe is totally incorporated into the micelles. The quencher distributes between water and the micellar pseudophase in two different ways; i.e. by binding and by partition. The model is analytically solved under the assumption that quenching of the probe is much faster than the quencher exchange either between the two phases or between partition and binding sites within the same micelle. Equations for the time-resolved and steady-state fluorescence intensities are derived. The model is applied to the quenching of a carboxylated zinc phthalocyanine fluorescence by diethyl-aniline in CTAC micelles.  |l eng 
536 |a Detalles de la financiación: Consejo Nacional de Investigaciones Científicas y Técnicas 
536 |a Detalles de la financiación: Universidad de Buenos Aires 
536 |a Detalles de la financiación: Institute of Environmental Science and Research, ESR, Tecnol6gico 
536 |a Detalles de la financiación: PFA and ESR are members of Carrera del Investi-gador Cientffico y Tecnol6gico from CONICET (Consejo Nacional de Investigaciones Cientfficas y T~cnicas, Argentina). The work was supported by grants from Universidad de Buenos Aires, Fundacidn Antorchas (Argentina), and Volkswagen Stiftung and GTZ (Germany). We are indebted to Professor Dr. Silvia Braslavsky (Max-Planck-Institut fiir Strahlen-chemie, Miilheim-Ruhr, Germany) for constant encouragement, support, and valuable discussions. 
593 |a INQUIMAE, Depto. de Quimica Inorgánica, Universidad de Buenos Aires, Pabellón 2, 1428 Buenos Aires, Argentina 
700 1 |a Aramendía, P.F. 
700 1 |a San Román, E. 
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