The high-resolution 1h nmr spectra and conformations of n-acetyl-α-d-galactopyranosylamine peracetate and 1, 1-bis(acetamido)-l-deoxy-d-glucitol peracetate in aqueous medium

In contrast with the spectra previously measured with lower resolution equipment, the 500-MHz 1H NMR spectra of l, l-bis(acetam1do)-1-deoxy-D-gl ucitol peracetate and N-acetyl-α-D-galactopyranosylamine peracetate in aqueous solution were amenable to full resolution. The former compound shows a “sick...

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Autor principal: Matulewicz, M.C
Otros Autores: Stortz, C.A, Jarret, R.M, Cerezo, A.S
Formato: Capítulo de libro
Lenguaje:Inglés
Publicado: 1987
Acceso en línea:Registro en Scopus
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Registro en la Biblioteca Digital
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100 1 |a Matulewicz, M.C. 
245 1 4 |a The high-resolution 1h nmr spectra and conformations of n-acetyl-α-d-galactopyranosylamine peracetate and 1, 1-bis(acetamido)-l-deoxy-d-glucitol peracetate in aqueous medium 
260 |c 1987 
506 |2 openaire  |e Política editorial 
504 |a Coxon, B., Tipson, R.S., Alexander, M., Deferrari, J.O., (1974) Carbohydr. Res., 35 (15) 
504 |a Wang, L., Lin, T.-S., Sartorelli, A.C., (1983) J. Org. Chem., 48 (2891) 
504 |a Cerezo, A.S., (1971) Chem. Ind., 96 
504 |a Cerezo, A.S., (1978) An. Asoc. Quim. Argent., 66 (41) 
504 |a Seldes, A.M., Gros, E.G., Thiel, I.M.E., Deferrari, J.O., (1975) Carbohydr. Res., 39 (11) 
504 |a El Khadem, H., Horton, D., Wander, J.D., (1972) J. Org. Chem., 37 (1630) 
504 |a Richardson, A.C., Mclauchlan, K.A., (1962) J. Chem. Soc., 2499. , (in part) 
504 |a Cerezo, A.S., Sproviero, J.F., Deulofeu, V., Delpy, S., (1968) Carbohydr. Res., 7 (395) 
504 |a Frush, H.L., Isbell, H.S., (1951) J. Res. Nat. Bur. Stand., 47 (239) 
520 3 |a In contrast with the spectra previously measured with lower resolution equipment, the 500-MHz 1H NMR spectra of l, l-bis(acetam1do)-1-deoxy-D-gl ucitol peracetate and N-acetyl-α-D-galactopyranosylamine peracetate in aqueous solution were amenable to full resolution. The former compound shows a “sickle” conformation produced by rotation of the C2–C3 bond out of the planar, zigzag arrangement, while the latter has a 4C1conformation. © 1987, Taylor & Francis Group, LLC. All rights reserved.  |l eng 
593 |a Departamento De Quimica Orgánica, Facultad De Ciencias Exactas y Naturales, Ciudad Universitaria, Pabellon 2, 1428, Buenos, A1res, Argentina 
593 |a College of the Holy Cross, Department of Chemistry, Worcester, MA, 01610, United States 
700 1 |a Stortz, C.A. 
700 1 |a Jarret, R.M. 
700 1 |a Cerezo, A.S. 
773 0 |d 1987  |g v. 6  |h pp. 515-521  |k n. 3  |p J. Carbohydr. Chem.  |x 07328303  |w (AR-BaUEN)CENRE-573  |t Journal of Carbohydrate Chemistry 
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856 4 0 |u https://doi.org/10.1080/07328308708057939  |y DOI 
856 4 0 |u https://hdl.handle.net/20.500.12110/paper_07328303_v6_n3_p515_Matulewicz  |y Handle 
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