The Constitution of a Galactomannan from the Seed of Gleditsia amorphoides

A galactomannan composed of 28.6% D-galactose and 71.4% D-mannose was isolated in 30% yield from the seeds of Gleditsia amorphoides. Periodate oxidation showed that all the mannose and galactose units were attacked since hydrolysis of the reduced oxopolysaccharide gave only glycerol (1 mole) and ery...

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Autor principal: Cerezo, A.S
Formato: Capítulo de libro
Lenguaje:Inglés
Publicado: 1965
Acceso en línea:Registro en Scopus
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Registro en la Biblioteca Digital
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100 1 |a Cerezo, A.S. 
245 1 4 |a The Constitution of a Galactomannan from the Seed of Gleditsia amorphoides 
260 |c 1965 
270 1 0 |m Cerezo, A.S.; Departamento de Química Orgánica, Facultad de Ciencias Exactas, Universidad de Buenos Aires, Buenos Aires, Argentina 
506 |2 openaire  |e Política editorial 
520 3 |a A galactomannan composed of 28.6% D-galactose and 71.4% D-mannose was isolated in 30% yield from the seeds of Gleditsia amorphoides. Periodate oxidation showed that all the mannose and galactose units were attacked since hydrolysis of the reduced oxopolysaccharide gave only glycerol (1 mole) and erythritol (2.7 moles). The periodate consumption was 4.8 moles for every four hexose residues and at the same time 1 mole of formic acid was produced. Hydrolysis of the methylated polysaccharide yielded 2,3,4,6-tetra-O-methyl-D-galactose (1 mole), 2,3,6-tri-O-methyl-D-mannose (2.1 moles), and 2,3-di-O-methyl-D-mannose (1.1 moles). © 1965, American Chemical Society. All rights reserved.  |l eng 
593 |a Departamento de Química Orgánica, Facultad de Ciencias Exactas, Universidad de Buenos Aires, Buenos Aires, Argentina 
773 0 |d 1965  |g v. 30  |h pp. 924-927  |k n. 3  |p J. Org. Chem.  |x 00223263  |w (AR-BaUEN)CENRE-337  |t Journal of Organic Chemistry 
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