ortho Effects on Nucleophilic Aromatic Substitution. The Reactions of 6-R-2-Nitrochlorobenzenes with Piperidine in Benzene
The rate constants and thermodynamic parameters for the reaction of nine 6-R-2-nitrochlorobenzenes with piperidine in benzene have been determined. The reactions follow the Hammett relationship log (kR/kH) = σρ if the "bulky" substituents, bromine and methyl, are excluded. An approximate v...
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| Formato: | Capítulo de libro |
| Lenguaje: | Inglés |
| Publicado: |
1965
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| Acceso en línea: | Registro en Scopus DOI Handle Registro en la Biblioteca Digital |
| Aporte de: | Registro referencial: Solicitar el recurso aquí |
| LEADER | 02230caa a22002897a 4500 | ||
|---|---|---|---|
| 001 | PAPER-17861 | ||
| 003 | AR-BaUEN | ||
| 005 | 20230518204914.0 | ||
| 008 | 190411s1965 xx ||||fo|||| 00| 0 eng|d | ||
| 024 | 7 | |2 scopus |a 2-s2.0-28144461211 | |
| 040 | |a Scopus |b spa |c AR-BaUEN |d AR-BaUEN | ||
| 100 | 1 | |a Sbarbati, N.E. | |
| 245 | 1 | 0 | |a ortho Effects on Nucleophilic Aromatic Substitution. The Reactions of 6-R-2-Nitrochlorobenzenes with Piperidine in Benzene |
| 260 | |c 1965 | ||
| 270 | 1 | 0 | |m Sbarbati, N.E.; Laboratorio de Química Orgánica, Facultad de Ciencias Exactas, Universidad de Buenos Aires, Buenos Aires, Argentina |
| 506 | |2 openaire |e Política editorial | ||
| 520 | 3 | |a The rate constants and thermodynamic parameters for the reaction of nine 6-R-2-nitrochlorobenzenes with piperidine in benzene have been determined. The reactions follow the Hammett relationship log (kR/kH) = σρ if the "bulky" substituents, bromine and methyl, are excluded. An approximate van der Waals radius of 1.9 Å. is proposed as the lower limit below which steric effects are negligible, and differences in rate are mainly determined by polar effects. The substituent influence on both enthalpy and entropy of activation is discussed. © 1965, American Chemical Society. All rights reserved. |l eng | |
| 593 | |a Laboratorio de Química Orgánica, Facultad de Ciencias Exactas, Universidad de Buenos Aires, Buenos Aires, Argentina | ||
| 773 | 0 | |d 1965 |g v. 30 |h pp. 3365-3369 |k n. 10 |p J. Org. Chem. |x 00223263 |w (AR-BaUEN)CENRE-337 |t Journal of Organic Chemistry | |
| 856 | 4 | 1 | |u https://www.scopus.com/inward/record.uri?eid=2-s2.0-28144461211&doi=10.1021%2fjo01021a024&partnerID=40&md5=3d660e83550e517a9267813d915d6648 |y Registro en Scopus |
| 856 | 4 | 0 | |u https://doi.org/10.1021/jo01021a024 |y DOI |
| 856 | 4 | 0 | |u https://hdl.handle.net/20.500.12110/paper_00223263_v30_n10_p3365_Sbarbati |y Handle |
| 856 | 4 | 0 | |u https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_00223263_v30_n10_p3365_Sbarbati |y Registro en la Biblioteca Digital |
| 961 | |a paper_00223263_v30_n10_p3365_Sbarbati |b paper |c PE | ||
| 962 | |a info:eu-repo/semantics/article |a info:ar-repo/semantics/artículo |b info:eu-repo/semantics/publishedVersion | ||
| 963 | |a VARI | ||
| 999 | |c 78814 | ||