Polar Effects of Substitutents on the Reaction Rates of 4-R- and 5-R-2-Nitrochlorobenzenes with Piperidine in Benzene

The rate constants for the reaction of fourteen 4-R- and of twelve 5-R-2-nitroehlorobenzcncs with piperidine in benzene have been determined. The reaction follows the Hammett relationship log kR/kH = σ*ρ with a ρ-value of +3.80. Differences in rates are mainly determined by differences in activation...

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Detalles Bibliográficos
Autor principal: Greizerstein, W.
Otros Autores: Bonelli, R.A, Brieux, J.A
Formato: Capítulo de libro
Lenguaje:Inglés
Publicado: 1962
Acceso en línea:Registro en Scopus
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Registro en la Biblioteca Digital
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100 1 |a Greizerstein, W. 
245 1 0 |a Polar Effects of Substitutents on the Reaction Rates of 4-R- and 5-R-2-Nitrochlorobenzenes with Piperidine in Benzene 
260 |c 1962 
506 |2 openaire  |e Política editorial 
520 3 |a The rate constants for the reaction of fourteen 4-R- and of twelve 5-R-2-nitroehlorobenzcncs with piperidine in benzene have been determined. The reaction follows the Hammett relationship log kR/kH = σ*ρ with a ρ-value of +3.80. Differences in rates are mainly determined by differences in activation energies. © 1962, American Chemical Society. All rights reserved.  |l eng 
593 |a Laboratorio de Quimica Organica, Facultad de Ciencias Exactas y Naturales, Universidad Nacional de Buenos Aires, Buenos Aires, Argentina 
700 1 |a Bonelli, R.A. 
700 1 |a Brieux, J.A. 
773 0 |d 1962  |g v. 84  |h pp. 1026-1032  |k n. 6  |p J. Am. Chem. Soc.  |x 00027863  |w (AR-BaUEN)CENRE-19  |t Journal of the American Chemical Society 
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