Effect of acid pretreatment and process temperature on characteristics and yields of pyrolysis products of peanut shells
Pyrolysis of acid pretreated peanut (Arachis hypogaea) shells was examined in order to improve the yield of liquids (bio-oils) and the characteristics of the three kinds of pyrolysis products. Also, pyrolysis of the pristine shells was comparatively investigated. The acid pretreatment was carried ou...
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Elsevier Ltd
2017
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| LEADER | 13611caa a22011777a 4500 | ||
|---|---|---|---|
| 001 | PAPER-17766 | ||
| 003 | AR-BaUEN | ||
| 005 | 20230518204908.0 | ||
| 008 | 190410s2017 xx ||||fo|||| 00| 0 eng|d | ||
| 024 | 7 | |2 scopus |a 2-s2.0-85025837088 | |
| 040 | |a Scopus |b spa |c AR-BaUEN |d AR-BaUEN | ||
| 100 | 1 | |a Gurevich Messina, L.I. | |
| 245 | 1 | 0 | |a Effect of acid pretreatment and process temperature on characteristics and yields of pyrolysis products of peanut shells |
| 260 | |b Elsevier Ltd |c 2017 | ||
| 270 | 1 | 0 | |m Cukierman, A.L.; Universidad de Buenos Aires, Facultad de Ciencias Exactas y Naturales, Depto. de Industrias, Programa de Investigación y Desarrollo de Fuentes Alternativas de Materias Primas y Energía (PINMATE), Int. Güiraldes 2620, Ciudad Universitaria, Argentina; email: analea@di.fcen.uba.ar |
| 506 | |2 openaire |e Política editorial | ||
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| 520 | 3 | |a Pyrolysis of acid pretreated peanut (Arachis hypogaea) shells was examined in order to improve the yield of liquids (bio-oils) and the characteristics of the three kinds of pyrolysis products. Also, pyrolysis of the pristine shells was comparatively investigated. The acid pretreatment was carried out employing a dilute HCl solution and it successfully diminished the ash content of the shells. Pyrolysis assays were performed in a fixed-bed reactor at different process temperatures (400 °C, 500 °C, and 600 °C). The maximum bio-oil yield was obtained at a temperature of 500 °C for both the pretreated and the pristine shells, but pyrolysis of the formers yielded more bio-oils than the untreated ones (42 wt% vs. 33 wt%). The increase of the process temperature resulted in a reduction of the solid (bio-char) generation for both samples. Demineralization also led to a further reduction of the bio-char yield. Regarding the products characteristics, neither the pretreatment nor the temperature had a noticeable influence on the elemental composition of the bio-oils. However, water content of the bio-oils was lower for the ones arising from pyrolysis of the demineralized shells although it increased with growing process temperature. Likewise, pyrolysis of the demineralized shells resulted in bio-chars with less ash, improving their potentialities as bio-fuels. Also, the bio-chars arising from the treated shells at the higher temperatures (500 °C and 600 °C) resulted in higher BET surface areas (up to 300 m2/g), pointing to their possible use as rough adsorbents or for further upgrading to activated carbons. © 2017 Elsevier Ltd |l eng | |
| 536 | |a Detalles de la financiación: PICT 2012-2188 | ||
| 536 | |a Detalles de la financiación: Consejo Nacional de Investigaciones Científicas y Técnicas, PIP 0183 | ||
| 536 | |a Detalles de la financiación: Universidad de Buenos Aires, 20020130100605BA | ||
| 536 | |a Detalles de la financiación: The authors gratefully acknowledge Agencia Nacional de Promoci?n Cient?fica y Tecnol?gica (ANPCYT), (Grant Nr. PICT 2012-2188) Consejo Nacional de Investigaciones Cient?ficas y T?cnicas (CONICET) (Grant Nr. PIP 0183), and Universidad de Buenos Aires (UBA) (Grant Nr. 20020130100605BA) from Argentina, for financial support. | ||
| 593 | |a Universidad de Buenos Aires, Facultad de Ciencias Exactas y Naturales, Depto. de Industrias, Programa de Investigación y Desarrollo de Fuentes Alternativas de Materias Primas y Energía (PINMATE), Int. Güiraldes 2620, Ciudad Universitaria, Buenos Aires, C1428BGA, Argentina | ||
| 593 | |a Consejo Nacional de Investigaciones Científicas y Técnicas (CONICET), Godoy Cruz 2290, Buenos Aires, C1425FQB, Argentina | ||
| 593 | |a Universidad de Buenos Aires, Facultad de Farmacia y Bioquímica, Depto. de Tecnología Farmacéutica, Cátedra de Tecnología Farmacéutica II, Junín 956, Buenos Aires, C1113AAD, Argentina | ||
| 690 | 1 | 0 | |a BIO-CHAR |
| 690 | 1 | 0 | |a BIO-OIL |
| 690 | 1 | 0 | |a DEMINERALIZATION |
| 690 | 1 | 0 | |a PEANUT SHELLS |
| 690 | 1 | 0 | |a PYROLYSIS |
| 690 | 1 | 0 | |a ACTIVATED CARBON |
| 690 | 1 | 0 | |a BIOFUELS |
| 690 | 1 | 0 | |a OILSEEDS |
| 690 | 1 | 0 | |a PYROLYSIS |
| 690 | 1 | 0 | |a BIO CHARS |
| 690 | 1 | 0 | |a BIO OIL |
| 690 | 1 | 0 | |a DEMINERALIZATION |
| 690 | 1 | 0 | |a ELEMENTAL COMPOSITIONS |
| 690 | 1 | 0 | |a FIXED BED REACTOR |
| 690 | 1 | 0 | |a PEANUT SHELLS |
| 690 | 1 | 0 | |a PROCESS TEMPERATURE |
| 690 | 1 | 0 | |a PYROLYSIS PRODUCTS |
| 690 | 1 | 0 | |a SHELLS (STRUCTURES) |
| 690 | 1 | 0 | |a ACTIVATED CARBON |
| 690 | 1 | 0 | |a BIOASSAY |
| 690 | 1 | 0 | |a BIOFUEL |
| 690 | 1 | 0 | |a BIOMINERALIZATION |
| 690 | 1 | 0 | |a CHARCOAL |
| 690 | 1 | 0 | |a COMPARATIVE STUDY |
| 690 | 1 | 0 | |a GROUNDNUT |
| 690 | 1 | 0 | |a HYDROCHLORIC ACID |
| 690 | 1 | 0 | |a PYROLYSIS |
| 690 | 1 | 0 | |a SHELL |
| 690 | 1 | 0 | |a ARACHIS HYPOGAEA |
| 700 | 1 | |a Bonelli, P.R. | |
| 700 | 1 | |a Cukierman, A.L. | |
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