Synthesis of atomic metal clusters on nanoporous alumina
The synthesis of atomic metal (gold and nickel) clusters by pulsed galvanostatic electrodeposition on nanoporous alumina is presented. The method allows the production of clusters with an average diameter of 0.7 nm for gold and 1.1 nm for nickel, while the size can be controlled through the current...
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Lenguaje: | Inglés |
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2013
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Acceso en línea: | Registro en Scopus DOI Handle Registro en la Biblioteca Digital |
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LEADER | 06281caa a22008537a 4500 | ||
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001 | PAPER-16751 | ||
003 | AR-BaUEN | ||
005 | 20241007093323.0 | ||
008 | 190411s2013 xx ||||fo|||| 00| 0 eng|d | ||
024 | 7 | |2 scopus |a 2-s2.0-84887465880 | |
024 | 7 | |2 cas |a 4 nitrophenol, 100-02-7; aluminum oxide, 1302-74-5, 1318-23-6, 1344-28-1, 14762-49-3; ferrocyanide, 13408-63-4, 13601-19-9; gold, 7440-57-5; nickel, 7440-02-0 | |
040 | |a Scopus |b spa |c AR-BaUEN |d AR-BaUEN | ||
100 | 1 | |a Peinetti, A.S. | |
245 | 1 | 0 | |a Synthesis of atomic metal clusters on nanoporous alumina |
260 | |c 2013 | ||
270 | 1 | 0 | |m González, G.A.; INQUIMAE, Departamento de Química Inorgánica, Analítica y Química Física, Facultad de Ciencias Exactas y Naturales, Universidad de Buenos Aires, Ciudad Universitaria, Pabellón 2, Gangwon, Buenos Aires, C1428EHA, Argentina; email: graciela@qi.fcen.uba.ar |
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506 | |2 openaire |e Política editorial | ||
520 | 3 | |a The synthesis of atomic metal (gold and nickel) clusters by pulsed galvanostatic electrodeposition on nanoporous alumina is presented. The method allows the production of clusters with an average diameter of 0.7 nm for gold and 1.1 nm for nickel, while the size can be controlled through the current density applied. This strategy represents a simple and efficient method for the construction of heterogeneous catalysts and sub-nanometre electrode arrays exemplified here by the reduction of 4-nitrophenol and the electrochemical response to ferrocyanide. © 2013 The Royal Society of Chemistry. |l eng | |
593 | |a INQUIMAE, Departamento de Química Inorgánica, Analítica y Química Física, Facultad de Ciencias Exactas y Naturales, Universidad de Buenos Aires, Ciudad Universitaria, Pabellón 2, Gangwon, Buenos Aires, C1428EHA, Argentina | ||
690 | 1 | 0 | |a 4 NITROPHENOL |
690 | 1 | 0 | |a ALUMINUM OXIDE |
690 | 1 | 0 | |a FERROCYANIDE |
690 | 1 | 0 | |a GOLD |
690 | 1 | 0 | |a NICKEL |
690 | 1 | 0 | |a ARTICLE |
690 | 1 | 0 | |a ATOMIC FORCE MICROSCOPY |
690 | 1 | 0 | |a CATALYST |
690 | 1 | 0 | |a CYCLIC POTENTIOMETRY |
690 | 1 | 0 | |a DIFFUSION |
690 | 1 | 0 | |a ELECTROCHEMICAL ANALYSIS |
690 | 1 | 0 | |a ELECTRODE |
690 | 1 | 0 | |a NANOPORE |
690 | 1 | 0 | |a PARTICLE SIZE |
690 | 1 | 0 | |a SYNTHESIS |
700 | 1 | |a Herrera, S. | |
700 | 1 | |a González, G.A. | |
700 | 1 | |a Battaglini, Fernando | |
773 | 0 | |d 2013 |g v. 49 |h pp. 11317-11319 |k n. 96 |p Chem. Commun. |x 13597345 |w (AR-BaUEN)CENRE-1038 |t Chemical Communications | |
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