Understanding the Zr and Si interdispersion in Zr1-xSixO2 mesoporous thin films by using FTIR and XANES spectroscopy

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Zr-Si mixed mesoporous oxides were obtained in a wide range of proportions, from 0 to 30% and from 70 to 100% of Si, using Si(OEt)4 and ZrCl4 as precursors and Pluronic F127 as a template. The oxide mesostructure was characterized by transmission electron microscopy and 2D-small angle X-ray scatteri...

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Autor principal: Andrini, L.
Otros Autores: Angelomé, P.C, Soler-Illia, G.J.A.A, Requejo, Félix Gregorio
Formato: Capítulo de libro
Lenguaje:Inglés
Publicado: Royal Society of Chemistry 2016
Acceso en línea:Registro en Scopus
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100 1 |a Andrini, L. 
245 1 0 |a Understanding the Zr and Si interdispersion in Zr1-xSixO2 mesoporous thin films by using FTIR and XANES spectroscopy 
260 |b Royal Society of Chemistry  |c 2016 
270 1 0 |m Angelomé, P.C.; Gerencia Química, Centro Atómico Constituyentes, Comisión Nacional de Energía Atómica, Av. General Paz 1499, Argentina; email: angelome@cnea.gov.ar 
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506 |2 openaire  |e Política editorial 
520 3 |a Zr-Si mixed mesoporous oxides were obtained in a wide range of proportions, from 0 to 30% and from 70 to 100% of Si, using Si(OEt)4 and ZrCl4 as precursors and Pluronic F127 as a template. The oxide mesostructure was characterized by transmission electron microscopy and 2D-small angle X-ray scattering. Fourier transform infrared spectroscopy measurements suggested a local homogeneous interdispersion of both cations. Further selective studies using X-ray Absorption Near Edge Structure (XANES) spectroscopy for separately Zr and Si local environments, allowed for demonstrating that the Zr coordination varies from close to 7 to 6, when its concentration in the mixed oxide is reduced. In addition, it was possible to determine that in mixed oxides with low Zr concentrations, Zr can fit into the spaces occupied by Si in SiO2 pure oxide. An equivalent XANES result was obtained for Si, which is also compatible with the information obtained by FTIR. Furthermore, the Zr-O distance varied from close to 2.2 Å to 1.7 Å when the Zr concentration decreased. Finally, our study also demonstrates the usefulness of XANES to selectively assess the local structure (coordination, symmetry and chemical state) of specific atoms in nanostructured systems. © 2016 The Royal Society of Chemistry.  |l eng 
593 |a Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas, INIFTA, CONICET, La Plata, 1900, Argentina 
593 |a Gerencia Química, Centro Atómico Constituyentes, Comisión Nacional de Energía Atómica, Av. General Paz 1499, San Martín, Buenos Aires, B1650KNA, Argentina 
593 |a Departamento de Química Inorgánica, Analítica y Química Física, Facultad de Ciencias Exactas y Naturales, Universidad de Buenos Aires, Buenos Aires, Argentina 
593 |a Instituto de Nanosistemas, Universidad Nacional de General San Martín, Av. 25 de Mayo y Francia, San Martín Buenos Aires, 1650, Argentina 
593 |a Departamento de Física, Facultad de Ciencias Exactas, Universidad Nacional de la Plata, La Plata, Argentina 
690 1 0 |a FOURIER TRANSFORM INFRARED SPECTROSCOPY 
690 1 0 |a HIGH RESOLUTION TRANSMISSION ELECTRON MICROSCOPY 
690 1 0 |a SILICON 
690 1 0 |a TRANSMISSION ELECTRON MICROSCOPY 
690 1 0 |a X RAY ABSORPTION 
690 1 0 |a X RAY ABSORPTION NEAR EDGE STRUCTURE SPECTROSCOPY 
690 1 0 |a X RAY SCATTERING 
690 1 0 |a CHEMICAL STATE 
690 1 0 |a LOCAL ENVIRONMENTS 
690 1 0 |a LOCAL STRUCTURE 
690 1 0 |a MESOPOROUS OXIDES 
690 1 0 |a MESOPOROUS THIN FILMS 
690 1 0 |a MESOSTRUCTURES 
690 1 0 |a NANOSTRUCTURED SYSTEMS 
690 1 0 |a PLURONIC F-127 
690 1 0 |a CRYSTAL ATOMIC STRUCTURE 
700 1 |a Angelomé, P.C. 
700 1 |a Soler-Illia, G.J.A.A. 
700 1 |a Requejo, Félix Gregorio 
773 0 |d Royal Society of Chemistry, 2016  |g v. 45  |h pp. 9977-9987  |k n. 24  |p Dalton Trans.  |x 14779226  |t Dalton Transactions 
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